{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,21]],"date-time":"2026-08-21T00:41:01Z","timestamp":1787272861546,"version":"build-2736575974"},"reference-count":64,"publisher":"American Association for the Advancement of Science (AAAS)","issue":"17","funder":[{"DOI":"10.13039\/501100001809","name":"National Science Foundation of China","doi-asserted-by":"crossref","award":["U24A20540"],"award-info":[{"award-number":["U24A20540"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100001809","name":"National Science Foundation of China","doi-asserted-by":"crossref","award":["22136002"],"award-info":[{"award-number":["22136002"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100001809","name":"National Science Foundation of China","doi-asserted-by":"crossref","award":["22309093"],"award-info":[{"award-number":["22309093"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]},{"name":"National key research and development project of China","award":["2020YFA0710304"],"award-info":[{"award-number":["2020YFA0710304"]}]},{"name":"Special Fund Project of Jiangsu Province for Scientific and Technological Innovation in Carbon Peaking and Carbon Neutrality","award":["BK20220023"],"award-info":[{"award-number":["BK20220023"]}]}],"content-domain":{"domain":["www.science.org"],"crossmark-restriction":true},"short-container-title":["Sci. Adv."],"published-print":{"date-parts":[[2026,4,24]]},"abstract":"<jats:p>\n                    The photocatalytic conversion of carbon dioxide into formate offers substantial economic value; however, it suffers from the inherent efficiency-selectivity trade-offs. Here, we introduce phthalocyanine polymer dots coexposed with defined phthalocyanine nitrogen (N\n                    <jats:sub>pc<\/jats:sub>\n                    ) and phthalocyanine nitrogen\u2013hydrogen (N\n                    <jats:sub>pc<\/jats:sub>\n                    \u2500H) sites as promising photocatalysts, achieving synergistic enhancement in efficiency and selectivity. N\n                    <jats:sub>pc<\/jats:sub>\n                    sites act as electron nodes, directing photogenerated electrons from photosensitizers toward carbon dioxide\u2013adsorbed phthalocyanine, boosting the reactive charge density by 6.5-fold. Concurrently, the N\n                    <jats:sub>pc<\/jats:sub>\n                    \u2500H sites capture carbon dioxide via bidentate adsorption, triggering a carbon-selective protonation pathway for selective formate photosynthesis. Owing to the synergistic advantages, the photocatalyst achieves a record formate production rate of 15.89 millimoles per gram per hour with 98.8% selectivity under natural sunlight and quantum efficiencies exceeding 5% across a broad visible-light spectrum. By clarifying electron migration and proposing a unique carbon-selective protonation reaction mechanism, this work offers transformable guidelines for sustainable solar energy conversion and controllable photocatalytic carbon dioxide reduction.\n                  <\/jats:p>","DOI":"10.1126\/sciadv.aed7557","type":"journal-article","created":{"date-parts":[[2026,4,24]],"date-time":"2026-04-24T17:58:32Z","timestamp":1777053512000},"update-policy":"https:\/\/doi.org\/10.34133\/aaas_crossmark","source":"Crossref","is-referenced-by-count":2,"title":["Transferring strongly reducing electrons to bidentate-adsorbed CO\n                    <sub>2<\/sub>\n                    for efficient and selective formate photosynthesis"],"prefix":"10.1126","volume":"12","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6969-3341","authenticated-orcid":true,"given":"Jingyi","family":"Xu","sequence":"first","affiliation":[{"name":"Department of Chemistry, Tsinghua University, Beijing, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4130-787X","authenticated-orcid":true,"given":"Keda","family":"Chen","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Tsinghua University, Beijing, China."},{"name":"School of Energy and Environment, City University of Hong Kong, Hong Kong, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4778-5429","authenticated-orcid":true,"given":"Meichi","family":"Chong","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Tsinghua University, Beijing, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0006-1357-8567","authenticated-orcid":true,"given":"Jianfang","family":"Jing","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5023-8899","authenticated-orcid":true,"given":"Michael K. H.","family":"Leung","sequence":"additional","affiliation":[{"name":"School of Energy and Environment, City University of Hong Kong, Hong Kong, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junshan","family":"Li","sequence":"additional","affiliation":[{"name":"Institute for Advanced Study, Chengdu University, Chengdu, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8528-509X","authenticated-orcid":true,"given":"Yongfa","family":"Zhu","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Tsinghua University, Beijing, China."}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"221","reference":[{"key":"e_1_3_2_2_2","doi-asserted-by":"publisher","DOI":"10.1038\/d41586-022-00807-y"},{"key":"e_1_3_2_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/D2CS00849A"},{"key":"e_1_3_2_4_2","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.adr8651"},{"key":"e_1_3_2_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c04364"},{"key":"e_1_3_2_6_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-020-2738-2"},{"key":"e_1_3_2_7_2","first-page":"1037","article-title":"Photochemical H2 dissociation for nearly quantitative CO2 reduction to ethylene","volume":"389","author":"Jin P.","year":"2025","unstructured":"P. Jin, P. Guo, N. Luo, H. Zhang, C. Ni, R. Chen, W. Liu, R. Li, J. Xiao, G. Wang, F. Zhang, P. Fornasiero, F. Wang, Photochemical H2 dissociation for nearly quantitative CO2 reduction to ethylene. Sci. Adv. 389, 1037\u20131042 (2025).","journal-title":"Sci. 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