{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,3]],"date-time":"2026-10-03T03:13:38Z","timestamp":1790997218539,"version":"4.1.0"},"reference-count":74,"publisher":"American Association for the Advancement of Science (AAAS)","issue":"29","funder":[{"name":"the General Program of National Natural Science Foundation of China","award":["22478008"],"award-info":[{"award-number":["22478008"]}]},{"name":"The Key Program of National Natural Science of China","award":["22438001"],"award-info":[{"award-number":["22438001"]}]},{"name":"The Peking University - BHP Carbon and Climate Wei-Ming PhD Scholars Program","award":["WM202511"],"award-info":[{"award-number":["WM202511"]}]}],"content-domain":{"domain":["www.science.org"],"crossmark-restriction":true},"short-container-title":["Sci. Adv."],"published-print":{"date-parts":[[2026,7,17]]},"abstract":"<jats:p>\n                    Conventional carbon dioxide (CO\n                    <jats:sub>2<\/jats:sub>\n                    ) capture systems are constrained by limited uptake capacity and energy-intensive regeneration. Here, we formulate a microporous carbon capture solution (MCCS) by dispersing a permanent-porosity framework (ZIF-67) in a liquid absorbent, coupling solvent-excluded physisorption with chemical uptake and boosting the CO\n                    <jats:sub>2<\/jats:sub>\n                    capture capacity by \u223c45%. Instead of bulk thermal stripping, we implement interfacial, microbubble-activated regeneration (MAR) with a decreased monoethanolamine (MEA) loss rate by \u223c38%. Microbubble activation refreshes gas-liquid-solid contact to liberate 100% physiosorbed CO\n                    <jats:sub>2<\/jats:sub>\n                    , whereas microbubble-collapse events that mechanically trigger contact electrocatalysis (CEC), enabling interfacial hydroxyl radicals (\u2022OH) that cleave carbamates under mild conditions and regenerates a substantial additional 37 to 55% of chemically absorbed CO\n                    <jats:sub>2<\/jats:sub>\n                    . Theoretical analyses reveal that \u2022OH is the key species governing CO\n                    <jats:sub>2<\/jats:sub>\n                    regeneration in the CEC-MAR process through oxidative carbon-nitrogen bond cleavage, followed by \u2022H-assisted intermediate reduction to regenerate the amine. To approach engineering relevance, we realize kilogram-scale zeolitic imidazolate framework (ZIF) synthesis under ambient conditions using simple mechanical stirring, providing scalable MCCS inventory to enable (i) continuous delivery of high-purity CO\n                    <jats:sub>2<\/jats:sub>\n                    (1437 millimoles over 200 minutes) from a laboratory-scale integrated system and (ii) direct electroreduction to carbon monoxide (CO) with a faradaic efficiency (FE\n                    <jats:sub>CO<\/jats:sub>\n                    ) of 51% without CO\n                    <jats:sub>2<\/jats:sub>\n                    supply. More broadly, it establishes a porous-liquid, interfacial-regeneration paradigm that decouples capacity from stoichiometry and enables electrified, continuous CO\n                    <jats:sub>2<\/jats:sub>\n                    capture, regeneration, and utilization under scalable, low-temperature conditions.\n                  <\/jats:p>","DOI":"10.1126\/sciadv.aef9017","type":"journal-article","created":{"date-parts":[[2026,7,17]],"date-time":"2026-07-17T17:58:48Z","timestamp":1784311128000},"update-policy":"https:\/\/doi.org\/10.34133\/aaas_crossmark","source":"Crossref","is-referenced-by-count":1,"title":["Microbubble-activated CO\n                    <sub>2<\/sub>\n                    regeneration in scalable microporous liquids enabled by contact electrocatalysis"],"prefix":"10.1126","volume":"12","author":[{"ORCID":"https:\/\/orcid.org\/0009-0008-4721-1653","authenticated-orcid":true,"given":"Pan","family":"Zhu","sequence":"first","affiliation":[{"name":"The Key Laboratory of Water and Sediment Sciences, Ministry of Education, College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0008-6525-4649","authenticated-orcid":true,"given":"Lixuan","family":"Ma","sequence":"additional","affiliation":[{"name":"Shanxi Laboratory for Yellow River, Institute of Resources and Environmental Engineering, Shanxi University, Taiyuan 030006, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xudong","family":"Yang","sequence":"additional","affiliation":[{"name":"The Key Laboratory of Water and Sediment Sciences, Ministry of Education, College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0007-0551-3824","authenticated-orcid":true,"given":"Xiao-Hong","family":"Yi","sequence":"additional","affiliation":[{"name":"Beijing Key Laboratory of Functional Materials for Building Structure and Environment Remediation, Key Laboratory of Urban Stormwater System and Water Environment (Ministry of Education), Beijing University of Civil Engineering and Architecture, Beijing 100044, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jundong","family":"Wang","sequence":"additional","affiliation":[{"name":"The Key Laboratory of Water and Sediment Sciences, Ministry of Education, College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chunlu","family":"Ding","sequence":"additional","affiliation":[{"name":"The Key Laboratory of Water and Sediment Sciences, Ministry of Education, College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xin","family":"Li","sequence":"additional","affiliation":[{"name":"The Key Laboratory of Water and Sediment Sciences, Ministry of Education, College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7785-749X","authenticated-orcid":true,"given":"Meng","family":"Lin","sequence":"additional","affiliation":[{"name":"SUSTech Energy Institute for Carbon Neutrality, Department of Mechanical and Energy Engineering, Southern University of Science and Technology, Shenzhen 518055, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6787-2431","authenticated-orcid":true,"given":"Wen","family":"Liu","sequence":"additional","affiliation":[{"name":"The Key Laboratory of Water and Sediment Sciences, Ministry of Education, College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6033-7076","authenticated-orcid":true,"given":"Chong-Chen","family":"Wang","sequence":"additional","affiliation":[{"name":"Beijing Key Laboratory of Functional Materials for Building Structure and Environment Remediation, Key Laboratory of Urban Stormwater System and Water Environment (Ministry of Education), Beijing University of Civil Engineering and Architecture, Beijing 100044, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2393-5012","authenticated-orcid":true,"given":"Huazhang","family":"Zhao","sequence":"additional","affiliation":[{"name":"The Key Laboratory of Water and Sediment Sciences, Ministry of Education, College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China."},{"name":"Shanxi Laboratory for Yellow River, Institute of Resources and Environmental Engineering, Shanxi University, Taiyuan 030006, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9268-4889","authenticated-orcid":true,"given":"Zishuai","family":"Zhang","sequence":"additional","affiliation":[{"name":"The Key Laboratory of Water and Sediment Sciences, Ministry of Education, College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China."},{"name":"Institute of Carbon Neutrality, Peking University, Beijing 100871, China."}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"221","reference":[{"key":"e_1_3_2_2_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1176731"},{"key":"e_1_3_2_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.1737498"},{"key":"e_1_3_2_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202515007"},{"key":"e_1_3_2_5_2","unstructured":"G. Rochelle Absorption-Based Post-Combustion Capture of Carbon Dioxide (Woodhead Publishing 2016)."},{"key":"e_1_3_2_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cherd.2011.01.007"},{"key":"e_1_3_2_7_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-025-01307-8"},{"key":"e_1_3_2_8_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jclepro.2015.08.116"},{"key":"e_1_3_2_9_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-022-05029-w"},{"key":"e_1_3_2_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202424104"},{"key":"e_1_3_2_11_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2024.127564"},{"key":"e_1_3_2_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2021.119305"},{"key":"e_1_3_2_13_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-023-00958-9"},{"key":"e_1_3_2_14_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-28869-6"},{"key":"e_1_3_2_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c04912"},{"key":"e_1_3_2_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c03921"},{"key":"e_1_3_2_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c17760"},{"key":"e_1_3_2_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c02431"},{"key":"e_1_3_2_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202300604"},{"key":"e_1_3_2_20_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-025-01901-0"},{"key":"e_1_3_2_21_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-021-27789-1"},{"key":"e_1_3_2_22_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-025-63337-x"},{"key":"e_1_3_2_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c11489"},{"key":"e_1_3_2_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscentsci.2c00329"},{"key":"e_1_3_2_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.0c01606"},{"key":"e_1_3_2_26_2","doi-asserted-by":"publisher","DOI":"10.1039\/D1EE02608A"},{"key":"e_1_3_2_27_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.abi7281"},{"key":"e_1_3_2_28_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-44027-y"},{"key":"e_1_3_2_29_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-025-56949-w"},{"key":"e_1_3_2_30_2","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.0602439103"},{"key":"e_1_3_2_31_2","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202512498"},{"key":"e_1_3_2_32_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0301-4622(99)00082-4"},{"key":"e_1_3_2_33_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-39089-x"},{"key":"e_1_3_2_34_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c13381"},{"key":"e_1_3_2_35_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.4c14726"},{"key":"e_1_3_2_36_2","doi-asserted-by":"publisher","DOI":"10.1039\/D5EE01448D"},{"key":"e_1_3_2_37_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-48407-w"},{"key":"e_1_3_2_38_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c02072"},{"key":"e_1_3_2_39_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41565-025-02033-9"},{"key":"e_1_3_2_40_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-023-01348-y"},{"key":"e_1_3_2_41_2","doi-asserted-by":"publisher","DOI":"10.1002\/adma.71187"},{"key":"e_1_3_2_42_2","doi-asserted-by":"publisher","DOI":"10.1038\/s44221-025-00531-7"},{"key":"e_1_3_2_43_2","doi-asserted-by":"crossref","unstructured":"D. Chen S. K. Sharma A. Mudhoo Handbook on Applications of Ultrasound Sonochemistry for Sustainability (CRC Press 2011).","DOI":"10.1201\/b11012"},{"key":"e_1_3_2_44_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c15514"},{"key":"e_1_3_2_45_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-45041-4"},{"key":"e_1_3_2_46_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-020-00735-z"},{"key":"e_1_3_2_47_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-025-01869-8"},{"key":"e_1_3_2_48_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41893-025-01654-1"},{"key":"e_1_3_2_49_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c01410"},{"key":"e_1_3_2_50_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-022-01130-6"},{"key":"e_1_3_2_51_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2024.10.010"},{"key":"e_1_3_2_52_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.0c00898"},{"key":"e_1_3_2_53_2","doi-asserted-by":"publisher","DOI":"10.1039\/D4CS00834K"},{"key":"e_1_3_2_54_2","doi-asserted-by":"publisher","DOI":"10.1039\/D4EE00048J"},{"key":"e_1_3_2_55_2","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202502344"},{"key":"e_1_3_2_56_2","doi-asserted-by":"publisher","DOI":"10.1021\/ct700301q"},{"key":"e_1_3_2_57_2","doi-asserted-by":"publisher","DOI":"10.1093\/bioinformatics\/btt055"},{"key":"e_1_3_2_58_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.2408420"},{"key":"e_1_3_2_59_2","doi-asserted-by":"publisher","DOI":"10.1016\/0263-7855(96)00018-5"},{"key":"e_1_3_2_60_2","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.21224"},{"key":"e_1_3_2_61_2","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.22885"},{"key":"e_1_3_2_62_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2018.05.006"},{"key":"e_1_3_2_63_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2015.08.086"},{"key":"e_1_3_2_64_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2020.117776"},{"key":"e_1_3_2_65_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7EE02342A"},{"key":"e_1_3_2_66_2","doi-asserted-by":"publisher","DOI":"10.4236\/opj.2018.86019"},{"key":"e_1_3_2_67_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.50.17953"},{"key":"e_1_3_2_68_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.cpc.2021.108033"},{"key":"e_1_3_2_69_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jmgm.2012.07.004"},{"key":"e_1_3_2_70_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00326a036"},{"key":"e_1_3_2_71_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.marchem.2005.11.001"},{"key":"e_1_3_2_72_2","doi-asserted-by":"publisher","DOI":"10.1021\/bp970133x"},{"key":"e_1_3_2_73_2","doi-asserted-by":"publisher","DOI":"10.1021\/bp970133x"},{"key":"e_1_3_2_74_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsaem.9b00986"},{"key":"e_1_3_2_75_2","doi-asserted-by":"publisher","DOI":"10.5194\/acp-23-10901-2023"}],"container-title":["Science Advances"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.science.org\/doi\/pdf\/10.1126\/sciadv.aef9017","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,17]],"date-time":"2026-07-17T18:00:05Z","timestamp":1784311205000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.science.org\/doi\/10.1126\/sciadv.aef9017"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7,17]]},"references-count":74,"journal-issue":{"issue":"29","published-print":{"date-parts":[[2026,7,17]]}},"alternative-id":["10.1126\/sciadv.aef9017"],"URL":"https:\/\/doi.org\/10.1126\/sciadv.aef9017","relation":{},"ISSN":["2375-2548"],"issn-type":[{"value":"2375-2548","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7,17]]},"assertion":[{"value":"2026-01-28","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-06-03","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-07-17","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"eaef9017"}}