{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,11]],"date-time":"2026-10-11T17:45:22Z","timestamp":1791740722686,"version":"4.3.4"},"reference-count":56,"publisher":"American Association for the Advancement of Science (AAAS)","issue":"25","funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22506042"],"award-info":[{"award-number":["22506042"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100006407","name":"Natural Science Foundation of Henan Province","doi-asserted-by":"publisher","award":["252300421710"],"award-info":[{"award-number":["252300421710"]}],"id":[{"id":"10.13039\/501100006407","id-type":"DOI","asserted-by":"publisher"}]},{"name":"The High level Talent Research Launch Fund of Henan University of Technology","award":["2024BS061"],"award-info":[{"award-number":["2024BS061"]}]},{"name":"Youth Science and Technology Talent Training Project of Science and Technology Innovation Talent Plan of Hubei Province","award":["2025DJA109"],"award-info":[{"award-number":["2025DJA109"]}]}],"content-domain":{"domain":["www.science.org"],"crossmark-restriction":true},"short-container-title":["Sci. Adv."],"published-print":{"date-parts":[[2026,6,19]]},"abstract":"<jats:p>\n                    Capturing gaseous mercury (Hg\n                    <jats:sup>0<\/jats:sup>\n                    ) from complex flue gases remains a common yet persistent issue. Here, the one-step hydrothermal method is adopted to synthesize zinc sulfide\/graphdiyne (ZnS\/GDY) nano adsorbents for efficient Hg vapor capture via a rational design of sp C\u2500S\u2500Zn hybridization on the interface. The research results indicate that GDY can gain electrons from ZnS though sp C\u2500S\u2500Zn bonds, which facilitates charge transfer and induces the generation of highly active Hg adsorption sites near sulfur defects (S\n                    <jats:sub>v<\/jats:sub>\n                    ). The fabricated ZnS\/GDY adsorbent can achieve a Hg\n                    <jats:sup>0<\/jats:sup>\n                    removal efficiency of 98% and exhibits excellent resistance to 1500\u00a0parts per million high-concentration sulfur dioxide (SO\n                    <jats:sub>2<\/jats:sub>\n                    ) constraints (maintaining a removal efficiency of 90.9%). Moreover, the commercial glass compound fiber filter (FMS) media coated with ZnS\/GDY shows potential for application in bag filter systems. About 80% of Hg\n                    <jats:sup>0<\/jats:sup>\n                    can be removed by ZnS\/GDY@FMS, even under conditions of high SO\n                    <jats:sub>2<\/jats:sub>\n                    concentration and in the presence of dust. Our work demonstrates that efficient Hg\n                    <jats:sup>0<\/jats:sup>\n                    removal efficiency under high-concentration SO\n                    <jats:sub>2<\/jats:sub>\n                    can be achieved by interfacial chemical bond engineering and provides guidance for functional carbon-based material design.\n                  <\/jats:p>","DOI":"10.1126\/sciadv.aef9068","type":"journal-article","created":{"date-parts":[[2026,6,19]],"date-time":"2026-06-19T18:00:33Z","timestamp":1781892033000},"update-policy":"https:\/\/doi.org\/10.34133\/aaas_crossmark","source":"Crossref","is-referenced-by-count":5,"title":["Rational design of interfacial sp C\u2500S\u2500Zn hybridization in ZnS\/graphdiyne for mercury vapor capture"],"prefix":"10.1126","volume":"12","author":[{"ORCID":"https:\/\/orcid.org\/0009-0000-4134-3630","authenticated-orcid":true,"given":"Chuanqi","family":"Pan","sequence":"first","affiliation":[{"name":"College of Environmental Engineering, Henan University of Technology, Zhengzhou 450001, P. R. China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cui","family":"Jie","sequence":"additional","affiliation":[{"name":"Research Center for Environment and Health, School of Information Engineering, Zhongnan University of Economics and Law, Wuhan, Hubei 430073, P. R. China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0007-0653-7887","authenticated-orcid":true,"given":"Ziheng","family":"Xia","sequence":"additional","affiliation":[{"name":"College of Environmental Engineering, Henan University of Technology, Zhengzhou 450001, P. R. China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kaiyue","family":"Xu","sequence":"additional","affiliation":[{"name":"College of Environmental Engineering, Henan University of Technology, Zhengzhou 450001, P. R. 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