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Adv."],"published-print":{"date-parts":[[2026,7,3]]},"abstract":"<jats:p>\n                    Inverted perovskite solar cells (PSCs) remain constrained by nickel ion (Ni\n                    <jats:sup>3+<\/jats:sup>\n                    )\u2013triggered interfacial redox chemistry and buried-interface defect landscapes that drive nonradiative loss and undermine operational stability. We report an interface-locked dual-molecule contact by coassembling [4-(3,6-dimethyl-9\n                    <jats:italic toggle=\"yes\">H<\/jats:italic>\n                    -carbazol-9-yl)butyl]phosphonic acid (Me-4PACz) with 9\n                    <jats:italic toggle=\"yes\">H<\/jats:italic>\n                    -carbazol-2-yl trifluoromethanesulfonate (CzOTf), in which \u03c0-\u03c0\u2013stabilized cofacial packing rigidifies molecular orientation and strengthens interfacial electronic coupling for efficient hole extraction, whereas the sulfonate terminus offers broader lead (Pb)\u2013related defect coordination and relieves interfacial tensile stress, collectively promoting higher-quality crystallization and a chemically stabilized buried interface. Enabled by this synergistic regulation, vacuum-flash-evaporated 1.53\u2013electron volt PSCs deliver certified efficiencies up to 27.31%. The strategy also translates to perovskite\/HJT-Si (silicon heterojunction) tandems with an efficiency of 32.84%. Furthermore, the corresponding 766\u2013square centimeter large-area module achieved a power conversion efficiency of 21.54%. The CzOTf-modulated PSCs retain 92% of their initial efficiency after 2000 hours of continuous light soaking (ISOS-L-1). The CzOTf-modulated large-area module operated stably outdoors for 35 days without degradation.\n                  <\/jats:p>","DOI":"10.1126\/sciadv.aeg1456","type":"journal-article","created":{"date-parts":[[2026,7,1]],"date-time":"2026-07-01T17:59:22Z","timestamp":1782928762000},"update-policy":"https:\/\/doi.org\/10.34133\/aaas_crossmark","source":"Crossref","is-referenced-by-count":9,"title":["Unlocking 27.3% perovskite photovoltaics by interface-locked dual-molecule contact"],"prefix":"10.1126","volume":"12","author":[{"ORCID":"https:\/\/orcid.org\/0009-0004-7730-4480","authenticated-orcid":true,"given":"Zuolin","family":"Zhang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Smart Power Distribution Equipment and System, School of Materials Science and Engineering, Hebei University of Technology, Tianjin 300401, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mengjia","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Smart Power Distribution Equipment and System, School of Materials Science and Engineering, Hebei University of Technology, Tianjin 300401, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jike","family":"Ding","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Smart Power Distribution Equipment and System, School of Materials Science and Engineering, Hebei University of Technology, Tianjin 300401, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yunxiao","family":"Liao","sequence":"additional","affiliation":[{"name":"School of Renewable Energy, Hohai University, Nanjing, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hao","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Smart Power Distribution Equipment and System, School of Materials Science and Engineering, Hebei University of Technology, Tianjin 300401, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4921-0979","authenticated-orcid":true,"given":"Yong","family":"Ding","sequence":"additional","affiliation":[{"name":"School of Renewable Energy, Hohai University, Nanjing, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0261-2169","authenticated-orcid":true,"given":"Boxin","family":"Jiao","sequence":"additional","affiliation":[{"name":"Center of Materials Science and Optoelectronics Engineering, College of Materials Science and Opto-Electronic Technology, University of Chinese Academy of Sciences, Beijing 100049, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8617-0945","authenticated-orcid":true,"given":"Jiang","family":"Sheng","sequence":"additional","affiliation":[{"name":"ChangZhou S.C Exact Equipment Co. 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