{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,29]],"date-time":"2026-07-29T18:58:07Z","timestamp":1785351487458,"version":"3.55.0"},"reference-count":35,"publisher":"American Association for the Advancement of Science (AAAS)","issue":"31","funder":[{"DOI":"10.13039\/501100002949","name":"Government of Jiangsu Province","doi-asserted-by":"publisher","award":["BK20241213"],"award-info":[{"award-number":["BK20241213"]}],"id":[{"id":"10.13039\/501100002949","id-type":"DOI","asserted-by":"publisher"}]},{"name":"New Cornerstone Science Foundation","award":["XPLORER PRIZE"],"award-info":[{"award-number":["XPLORER PRIZE"]}]},{"name":"Open State Key Laboratory of New Textile Materials and Advanced Processing Technologies","award":["FZ2024020"],"award-info":[{"award-number":["FZ2024020"]}]},{"name":"Technological Innovation Project Plan of Jiangsu Guoxin Investment Group Limited Project Name Applications and Study of Aging Mechanisms of New Perovskite Tandem Photovoltaic Modules Number","award":["JSNE2025005"],"award-info":[{"award-number":["JSNE2025005"]}]}],"content-domain":{"domain":["www.science.org"],"crossmark-restriction":true},"short-container-title":["Sci. Adv."],"published-print":{"date-parts":[[2026,7,31]]},"abstract":"<jats:p>\n                    The buried interface between the self-assembled monolayers (SAMs) and the perovskite plays a critical role in device performance and stability in inverted perovskite solar cells (PSCs). However, severe desorption and agglomeration of self-assembled molecules lead to interfacial losses and shorten device longevity. Herein, we design a molecule, 5,5\u2032,5\u2033-(nitrilotri-4,1-phenylene)tris[2-thiophenecarboxylic acid] (TTA) with a noncoplanar molecular configuration and multiple functional groups. The noncoplanar molecular configuration could effectively suppress \u03c0-\u03c0 stacking-induced aggregation and enable more regulated molecular packing. Its thiophene functional unit and tridentate carboxylic anchoring groups enhance interactions with substrates and the upper perovskites, assisted by the noncoplanar configuration, which is confirmed by density functional theory (DFT) calculations. When combined with the commonly used 4-(3,6-dimethyl-9\n                    <jats:italic toggle=\"yes\">H<\/jats:italic>\n                    -carbazol-9-yl)butane-1-phosphonic acid (Me-4PACz), this strategy enables a more homogeneous self-assembled molecular film, improved perovskite crystallinity, and reduced trap density. Consequently, the wide-bandgap (WBG) PSC (\u223c1.67 electron volts) demonstrates a champion power conversion efficiency (PCE) of 23.7%, with enhanced thermal-cycling and light-soaking stability. In addition, the perovskite\/silicon tandem devices based on this strategy achieve a PCE of 33.3% (certified at 33.1%) and demonstrate real-world operational stability of no observed PCE loss after 30 days of outdoor operation.\n                  <\/jats:p>","DOI":"10.1126\/sciadv.aei2945","type":"journal-article","created":{"date-parts":[[2026,7,29]],"date-time":"2026-07-29T17:59:11Z","timestamp":1785347951000},"update-policy":"https:\/\/doi.org\/10.34133\/aaas_crossmark","source":"Crossref","is-referenced-by-count":0,"title":["Noncoplanar multidentate contacts reinforce buried interface for perovskite\/silicon tandem solar cells"],"prefix":"10.1126","volume":"12","author":[{"ORCID":"https:\/\/orcid.org\/0009-0004-1445-4967","authenticated-orcid":true,"given":"Xinran","family":"Xu","sequence":"first","affiliation":[{"name":"School of Sustainable Energy and Resources, Jiangsu Key Laboratory of Artificial Functional Materials, Frontiers Science Center for Critical Earth Material Cycling, Nanjing University, Nanjing 210023, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0002-1084-8200","authenticated-orcid":true,"given":"Luokang","family":"Sun","sequence":"additional","affiliation":[{"name":"School of Sustainable Energy and Resources, Jiangsu Key Laboratory of Artificial Functional Materials, Frontiers Science Center for Critical Earth Material Cycling, Nanjing University, Nanjing 210023, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0004-4362-2317","authenticated-orcid":true,"given":"Chuanlu","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Sustainable Energy and Resources, Jiangsu Key Laboratory of Artificial Functional Materials, Frontiers Science Center for Critical Earth Material Cycling, Nanjing University, Nanjing 210023, China."},{"name":"College of Engineering and Applied Sciences, Nanjing University, Nanjing 210023, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0002-2930-8853","authenticated-orcid":true,"given":"Kun","family":"Chen","sequence":"additional","affiliation":[{"name":"Research and Development Center, JA Solar, Yangzhou 225131, China."},{"name":"MOE Key Laboratory of Low-grade Energy Utilization Technologies and Systems, School of Energy &amp; Power Engineering, Chongqing University, Chongqing 400044, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ye","family":"Yuan","sequence":"additional","affiliation":[{"name":"Jiangsu New Energy Development Co. Ltd., Nanjing 210005, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0006-7422-2281","authenticated-orcid":true,"given":"Zhe","family":"Li","sequence":"additional","affiliation":[{"name":"School of Sustainable Energy and Resources, Jiangsu Key Laboratory of Artificial Functional Materials, Frontiers Science Center for Critical Earth Material Cycling, Nanjing University, Nanjing 210023, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Li","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Sustainable Energy and Resources, Jiangsu Key Laboratory of Artificial Functional Materials, Frontiers Science Center for Critical Earth Material Cycling, Nanjing University, Nanjing 210023, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zijuan","family":"He","sequence":"additional","affiliation":[{"name":"Research and Development Center, JA Solar, Yangzhou 225131, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0008-9845-1729","authenticated-orcid":true,"given":"Yushuai","family":"Xu","sequence":"additional","affiliation":[{"name":"Research and Development Center, JA Solar, Yangzhou 225131, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xingpei","family":"Ye","sequence":"additional","affiliation":[{"name":"Jiangsu Guoxin Research Institute Co. Ltd., Nanjing 210005, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0000-7519-6915","authenticated-orcid":true,"given":"Zhou","family":"Liu","sequence":"additional","affiliation":[{"name":"Jiangsu Guoxin Research Institute Co. Ltd., Nanjing 210005, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1747-3360","authenticated-orcid":true,"given":"Yang","family":"Sun","sequence":"additional","affiliation":[{"name":"Research and Development Center, JA Solar, Yangzhou 225131, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4602-4852","authenticated-orcid":true,"given":"Haipeng","family":"Yin","sequence":"additional","affiliation":[{"name":"Research and Development Center, JA Solar, Yangzhou 225131, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5585-8413","authenticated-orcid":true,"given":"Zi","family":"Ouyang","sequence":"additional","affiliation":[{"name":"Research and Development Center, JA Solar, Yangzhou 225131, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6391-5270","authenticated-orcid":true,"given":"Kuan","family":"Sun","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of Low-grade Energy Utilization Technologies and Systems, School of Energy &amp; Power Engineering, Chongqing University, Chongqing 400044, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1635-1211","authenticated-orcid":true,"given":"Pengchen","family":"Zhu","sequence":"additional","affiliation":[{"name":"School of Sustainable Energy and Resources, Jiangsu Key Laboratory of Artificial Functional Materials, Frontiers Science Center for Critical Earth Material Cycling, Nanjing University, Nanjing 210023, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2871-4369","authenticated-orcid":true,"given":"Jia","family":"Zhu","sequence":"additional","affiliation":[{"name":"School of Sustainable Energy and Resources, Jiangsu Key Laboratory of Artificial Functional Materials, Frontiers Science Center for Critical Earth Material Cycling, Nanjing University, Nanjing 210023, China."},{"name":"College of Engineering and Applied Sciences, Nanjing University, Nanjing 210023, China."}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"221","reference":[{"key":"e_1_3_2_2_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.adg0091"},{"key":"e_1_3_2_3_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.ado9104"},{"key":"e_1_3_2_4_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.adf0194"},{"key":"e_1_3_2_5_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-54925-4"},{"key":"e_1_3_2_6_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-024-02073-x"},{"key":"e_1_3_2_7_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.adm9474"},{"key":"e_1_3_2_8_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.adj9602"},{"key":"e_1_3_2_9_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-51760-5"},{"key":"e_1_3_2_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202425145"},{"key":"e_1_3_2_11_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-023-06745-7"},{"key":"e_1_3_2_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.3c01385"},{"key":"e_1_3_2_13_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-50962-1"},{"key":"e_1_3_2_14_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-36141-8"},{"key":"e_1_3_2_15_2","doi-asserted-by":"publisher","DOI":"10.1039\/D4EE02492C"},{"key":"e_1_3_2_16_2","doi-asserted-by":"publisher","DOI":"10.3390\/en18102577"},{"key":"e_1_3_2_17_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-025-59891-z"},{"key":"e_1_3_2_18_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2024.05.005"},{"key":"e_1_3_2_19_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-025-59896-8"},{"key":"e_1_3_2_20_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-024-07723-3"},{"key":"e_1_3_2_21_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-024-08103-7"},{"key":"e_1_3_2_22_2","doi-asserted-by":"publisher","DOI":"10.1039\/D3TA02055J"},{"key":"e_1_3_2_23_2","first-page":"107","article-title":"Tuning isomerism effect in organic bulk additives enables efficient and stable perovskite solar cells","volume":"17","author":"Zhang Q.","year":"2025","unstructured":"Q. Zhang, Q. Zhao, H. Wang, Y. Yao, L. Li, Y. Wei, R. Xu, C. Zhang, E. O. Shalenov, Y. Tu, K. Wang, M. Xiao, Tuning isomerism effect in organic bulk additives enables efficient and stable perovskite solar cells. 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