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Adv."],"published-print":{"date-parts":[[2026,10,16]]},"abstract":"<jats:p>\n                    The slow kinetics of sulfur cathodes caused by the high energy barriers of Li\n                    <jats:sup>+<\/jats:sup>\n                    desolvation stem primarily from the structure of the inner Helmholtz plane (IHP). Herein, a synergistic strategy combining electrochemical tandem catalysis with spatial nanoconfinement is proposed to regulate the Li(solvent)\n                    <jats:italic toggle=\"yes\">\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    <jats:sup>+<\/jats:sup>\n                    dynamics. As a proof-of-concept, the porous covalent organic framework (denoted as TPBD) decorated MXene is in situ constructed, acting as a tandem kinetic promoter. The theoretical simulations and in situ Raman reveal that the porous TPBD layer confines the bulky Li(solvent)\n                    <jats:italic toggle=\"yes\">\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    <jats:sup>+<\/jats:sup>\n                    species and sieves the spatial structure with accelerated Li\n                    <jats:sup>+<\/jats:sup>\n                    diffusion kinetics. Meanwhile, MXene serves as a negatively charged substrate that helps disrupt anion-solvent interactions and reconstruct the solvation structure at the IHP, thereby enhancing Li\n                    <jats:sup>+<\/jats:sup>\n                    kinetics and sulfur redox reversibility. Encouragingly, the assembled cells demonstrate a superior Li\n                    <jats:sup>+<\/jats:sup>\n                    transference number (0.77), long-term cycling lifespan up to 1000 cycles, as well as excellent areal capacity (&gt;6 mAh cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    ) at 0\u00b0C and superior rate capability at 50\u00b0C under a high sulfur loading of 7.51 mg cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . The as-prepared pouch cell remains stable for over 100 cycles, validating this novel integration of catalysis and nanoconfinement for tandem kinetics in Li-S batteries.\n                  <\/jats:p>","DOI":"10.1126\/sciadv.aej0353","type":"journal-article","created":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T17:59:24Z","timestamp":1792000764000},"update-policy":"https:\/\/doi.org\/10.34133\/aaas_crossmark","source":"Crossref","is-referenced-by-count":0,"title":["Nanoconfinement-cooperated catalysis enables rapid tandem redox kinetics for wide-temperature lithium-sulfur batteries"],"prefix":"10.1126","volume":"12","author":[{"ORCID":"https:\/\/orcid.org\/0009-0009-2705-7377","authenticated-orcid":true,"given":"Tianli","family":"Li","sequence":"first","affiliation":[{"name":"State Key Laboratory of Green and Efficient Development of Phosphorus Resources, Hubei Key Laboratory of Plasma Chemistry and Advanced Materials, School of Materials Science and Engineering, Wuhan Institute of Technology, Wuhan, 430205, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tao","family":"Chen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, School of Material Science and Engineering, International School of Material Science and Engineering, Wuhan University of Technology, Wuhan 430070, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3449-7767","authenticated-orcid":true,"given":"Pu","family":"Hu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green and Efficient Development of Phosphorus Resources, Hubei Key Laboratory of Plasma Chemistry and Advanced Materials, School of Materials Science and Engineering, Wuhan Institute of Technology, Wuhan, 430205, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Congcong","family":"Cai","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green and Efficient Development of Phosphorus Resources, Hubei Key Laboratory of Plasma Chemistry and Advanced Materials, School of Materials Science and Engineering, Wuhan Institute of Technology, Wuhan, 430205, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Juntao","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green and Efficient Development of Phosphorus Resources, Hubei Key Laboratory of Plasma Chemistry and Advanced Materials, School of Materials Science and Engineering, Wuhan Institute of Technology, Wuhan, 430205, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4653-3788","authenticated-orcid":true,"given":"Chaoqun","family":"Shang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green and Efficient Development of Phosphorus Resources, Hubei Key Laboratory of Plasma Chemistry and Advanced Materials, School of Materials Science and Engineering, Wuhan Institute of Technology, Wuhan, 430205, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Liwei","family":"Xiong","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green and Efficient Development of Phosphorus Resources, Hubei Key Laboratory of Plasma Chemistry and Advanced Materials, School of Materials Science and Engineering, Wuhan Institute of Technology, Wuhan, 430205, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yajie","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Materials for Advanced Nuclear Energy &amp; School of Materials Science and Engineering, Shanghai University, Shanghai, 200444, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8625-4866","authenticated-orcid":true,"given":"Hanxing","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, School of Material Science and Engineering, International School of Material Science and Engineering, Wuhan University of Technology, Wuhan 430070, China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7945-0826","authenticated-orcid":true,"given":"Jian","family":"Wang","sequence":"additional","affiliation":[{"name":"Helmholtz Institute Ulm (HIU) D89081 Ulm, Germany Karlsruhe Institute of Technology (KIT) D76021 Karlsruhe, Germany."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6354-058X","authenticated-orcid":true,"given":"Yaobing","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, Fujian, P. 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