{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T02:59:27Z","timestamp":1791946767158,"version":"4.3.4"},"reference-count":26,"publisher":"American Association for the Advancement of Science (AAAS)","issue":"5743","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Science"],"published-print":{"date-parts":[[2005,9,23]]},"abstract":"<jats:p>\n                    We combined targeted chemistry and computational design to create a crystal structure for porous chromium terephthalate, MIL-101, withverylargeporesizes and surface area. Its zeotype cubic structure has a giant cell volume (\u223c702,000 cubic angstroms), a hierarchy of extra-large pore sizes (\u223c30 to 34 angstroms), and a Langmuir surface area for N\n                    <jats:sub>2<\/jats:sub>\n                    of \u223c5900 \u00b1 300 square meters per gram. Beside the usual properties of porous compounds, this solid has potential as a nanomold for monodisperse nanomaterials, as illustrated here by the incorporation of Keggin polyanions within the cages.\n                  <\/jats:p>","DOI":"10.1126\/science.1116275","type":"journal-article","created":{"date-parts":[[2005,9,22]],"date-time":"2005-09-22T16:58:23Z","timestamp":1127408303000},"page":"2040-2042","source":"Crossref","is-referenced-by-count":5337,"title":["A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area"],"prefix":"10.1126","volume":"309","author":[{"given":"G.","family":"Fe\u0301rey","sequence":"first","affiliation":[{"name":"Institut Lavoisier, CNRS Unite\u0301 Mixte de Recherche 8637, Universite\u0301 de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France."},{"name":"Institut universitaire de France, 103, Boulevard Saint-Michel, 75005 Paris, France."},{"name":"Royal Institution, 21 Albemarle Street, London W1S 4BS, UK."},{"name":"European Radiation Synchotron Facility, 38042 Grenoble, France."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"C.","family":"Mellot-Draznieks","sequence":"additional","affiliation":[{"name":"Institut Lavoisier, CNRS Unite\u0301 Mixte de Recherche 8637, Universite\u0301 de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France."},{"name":"Institut universitaire de France, 103, Boulevard Saint-Michel, 75005 Paris, France."},{"name":"Royal Institution, 21 Albemarle Street, London W1S 4BS, UK."},{"name":"European Radiation Synchotron Facility, 38042 Grenoble, France."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"C.","family":"Serre","sequence":"additional","affiliation":[{"name":"Institut Lavoisier, CNRS Unite\u0301 Mixte de Recherche 8637, Universite\u0301 de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France."},{"name":"Institut universitaire de France, 103, Boulevard Saint-Michel, 75005 Paris, France."},{"name":"Royal Institution, 21 Albemarle Street, London W1S 4BS, UK."},{"name":"European Radiation Synchotron Facility, 38042 Grenoble, France."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"F.","family":"Millange","sequence":"additional","affiliation":[{"name":"Institut Lavoisier, CNRS Unite\u0301 Mixte de Recherche 8637, Universite\u0301 de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France."},{"name":"Institut universitaire de France, 103, Boulevard Saint-Michel, 75005 Paris, France."},{"name":"Royal Institution, 21 Albemarle Street, London W1S 4BS, UK."},{"name":"European Radiation Synchotron Facility, 38042 Grenoble, France."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"J.","family":"Dutour","sequence":"additional","affiliation":[{"name":"Institut Lavoisier, CNRS Unite\u0301 Mixte de Recherche 8637, Universite\u0301 de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France."},{"name":"Institut universitaire de France, 103, Boulevard Saint-Michel, 75005 Paris, France."},{"name":"Royal Institution, 21 Albemarle Street, London W1S 4BS, UK."},{"name":"European Radiation Synchotron Facility, 38042 Grenoble, France."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"S.","family":"Surble\u0301","sequence":"additional","affiliation":[{"name":"Institut Lavoisier, CNRS Unite\u0301 Mixte de Recherche 8637, Universite\u0301 de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France."},{"name":"Institut universitaire de France, 103, Boulevard Saint-Michel, 75005 Paris, France."},{"name":"Royal Institution, 21 Albemarle Street, London W1S 4BS, UK."},{"name":"European Radiation Synchotron Facility, 38042 Grenoble, France."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"I.","family":"Margiolaki","sequence":"additional","affiliation":[{"name":"Institut Lavoisier, CNRS Unite\u0301 Mixte de Recherche 8637, Universite\u0301 de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France."},{"name":"Institut universitaire de France, 103, Boulevard Saint-Michel, 75005 Paris, France."},{"name":"Royal Institution, 21 Albemarle Street, London W1S 4BS, UK."},{"name":"European Radiation Synchotron Facility, 38042 Grenoble, France."}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"221","reference":[{"key":"e_1_3_1_2_2","doi-asserted-by":"publisher","DOI":"10.1038\/35010088"},{"key":"e_1_3_1_3_2","first-page":"563","volume":"3","year":"2002","unstructured":"F. 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Engl.39, 3414 (2000).","journal-title":"Angew. Chem. Int. Ed. Engl."},{"key":"e_1_3_1_24_2","unstructured":"Initial hydrogen storage measurements were \u223c0.45 and 3.75 weight percent at 293 K and 77 K respectively at 2 MPa. The values at 77 K seem to be the highest for MOFs after the contestation of previous results ( 3 )."},{"key":"e_1_3_1_25_2","unstructured":"Initial introduction of semiconducting ZnS nanoparticles in the pores of MIL-101 was successfully achieved with a ZnS\/Cr ratio close to 0.5."},{"key":"e_1_3_1_26_2","unstructured":"Incorporation of ibuprofen within MIL-101 has been achieved in large amounts (\u223c1 g of drug per gram of MIL-101) with a total release of the drug within a few days."},{"key":"e_1_3_1_27_2","unstructured":"We thank F. Taulelle and M. Haouas for collecting solid state NMR M. Latroche for hydrogen sorption measurements P. Mialane for providing the Keggin salt and for helpful discussions S. Floquet and E. Cadot for helpful discussion about the introduction of ZnS nanoparticles and P. Horcajada and M. Vallet-Regi for the drug incorporation study."}],"container-title":["Science"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.science.org\/doi\/pdf\/10.1126\/science.1116275","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,1,9]],"date-time":"2024-01-09T21:50:48Z","timestamp":1704837048000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.science.org\/doi\/10.1126\/science.1116275"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2005,9,23]]},"references-count":26,"journal-issue":{"issue":"5743","published-print":{"date-parts":[[2005,9,23]]}},"alternative-id":["10.1126\/science.1116275"],"URL":"https:\/\/doi.org\/10.1126\/science.1116275","relation":{},"ISSN":["0036-8075","1095-9203"],"issn-type":[{"value":"0036-8075","type":"print"},{"value":"1095-9203","type":"electronic"}],"subject":[],"published":{"date-parts":[[2005,9,23]]}}}