{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,16]],"date-time":"2026-10-16T00:18:48Z","timestamp":1792109928153,"version":"4.4.0"},"reference-count":35,"publisher":"American Association for the Advancement of Science (AAAS)","issue":"6112","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Science"],"published-print":{"date-parts":[[2012,12,7]]},"abstract":"<jats:title>Robust Reduction<\/jats:title>\n                  <jats:p>\n                    A major challenge in the design of artificial photosynthesis catalysts has been their instability under the reaction conditions\u2014a problem that plants and other autotrophs address by perpetually reproducing their biochemical machinery.\n                    <jats:bold>\n                      Han\n                      <jats:italic>et al.<\/jats:italic>\n                    <\/jats:bold>\n                    (p.\n                    <jats:related-article xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" ext-link-type=\"doi\" page=\"1321\" related-article-type=\"in-this-issue\" vol=\"338\" xlink:href=\"10.1126\/science.1227775\">1321<\/jats:related-article>\n                    , published online 8 November) now demonstrate a system for photoreductive hydrogen generation in water that manifests undiminished activity for weeks at a time. Semiconductor nanoparticles for light absorption were combined with a soluble nickel complex for the catalytic chemistry. The system currently requires a sacrificial electron donor, but its robustness shows promise for future pairing with an integrated oxidation catalyst.\n                  <\/jats:p>","DOI":"10.1126\/science.1227775","type":"journal-article","created":{"date-parts":[[2012,11,8]],"date-time":"2012-11-08T23:50:54Z","timestamp":1352418654000},"page":"1321-1324","source":"Crossref","is-referenced-by-count":764,"title":["Robust Photogeneration of H\n                    <sub>2<\/sub>\n                    in Water Using Semiconductor Nanocrystals and a Nickel Catalyst"],"prefix":"10.1126","volume":"338","author":[{"given":"Zhiji","family":"Han","sequence":"first","affiliation":[{"name":"Department of Chemistry, University of Rochester, Rochester, NY 14627, USA."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fen","family":"Qiu","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Rochester, Rochester, NY 14627, USA."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Richard","family":"Eisenberg","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Rochester, Rochester, NY 14627, USA."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Patrick L.","family":"Holland","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Rochester, Rochester, NY 14627, USA."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Todd D.","family":"Krauss","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Rochester, Rochester, NY 14627, USA."}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"221","reference":[{"key":"e_1_3_2_2_2","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.0603395103"},{"key":"e_1_3_2_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic050904r"},{"key":"e_1_3_2_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar00051a007"},{"key":"e_1_3_2_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr050193e"},{"key":"e_1_3_2_6_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2dt30823a"},{"key":"e_1_3_2_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/jz100075c"},{"key":"e_1_3_2_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja101031r"},{"key":"e_1_3_2_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201006407"},{"key":"e_1_3_2_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja2116348"},{"key":"e_1_3_2_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja303698e"},{"key":"e_1_3_2_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201006352"},{"key":"e_1_3_2_13_2","doi-asserted-by":"publisher","DOI":"10.1039\/c1cc16082f"},{"key":"e_1_3_2_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp046481g"},{"key":"e_1_3_2_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00499a051"},{"key":"e_1_3_2_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic102317u"},{"key":"e_1_3_2_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja201514e"},{"key":"e_1_3_2_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja1057357"},{"key":"e_1_3_2_20_2","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.1120757109"},{"key":"e_1_3_2_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200702953"},{"key":"e_1_3_2_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200902489"},{"key":"e_1_3_2_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja206782k"},{"key":"e_1_3_2_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/nn201681s"},{"key":"e_1_3_2_25_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(00)80765-3"},{"key":"e_1_3_2_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201107329"},{"key":"e_1_3_2_27_2","doi-asserted-by":"publisher","DOI":"10.1016\/S1387-7003(00)00027-7"},{"key":"e_1_3_2_28_2","doi-asserted-by":"publisher","DOI":"10.3891\/acta.chem.scand.48-0929"},{"key":"e_1_3_2_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00295a004"},{"key":"e_1_3_2_30_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm991167y"},{"key":"e_1_3_2_31_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja01589a079"},{"key":"e_1_3_2_32_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja047000+"},{"key":"e_1_3_2_33_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja103448u"},{"key":"e_1_3_2_34_2","unstructured":"K. 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