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The homogeneous solution polymerization of highly fluorinated acrylic monomers can be achieved in supercritical carbon dioxide by using free radical methods. In addition, detailed decomposition rates and efficiency factors were measured for azobisisobutyronitrile in supercritical carbon dioxide and were compared to those obtained with conventional liquid solvents.<\/jats:p>","DOI":"10.1126\/science.257.5072.945","type":"journal-article","created":{"date-parts":[[2006,10,5]],"date-time":"2006-10-05T19:03:06Z","timestamp":1160074986000},"page":"945-947","source":"Crossref","is-referenced-by-count":783,"title":["Synthesis of Fluoropolymers in Supercritical Carbon Dioxide"],"prefix":"10.1126","volume":"257","author":[{"given":"J. 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