{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T17:00:12Z","timestamp":1791306012514,"version":"4.3.1"},"reference-count":27,"publisher":"American Association for the Advancement of Science (AAAS)","issue":"5139","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Science"],"published-print":{"date-parts":[[1993,12,3]]},"abstract":"<jats:p>\n            Molecular-based magnets with high magnetic-ordering temperatures,\n            <jats:italic>T<\/jats:italic>\n            <jats:sub>c<\/jats:sub>\n            , can be obtained by mild chemistry methods by focusing on the bimetallic and mixed-valence transition metal \u03bc-cyanide of the Prussian blue family. A simple orbital model was used to predict the electronic structure of the metal ions required to achieve a high ordering temperature. The synthesis and magnetic properties of two compounds, [Cr\n            <jats:sub>5<\/jats:sub>\n            (CN)\n            <jats:sub>12<\/jats:sub>\n            ]\u22c510H\n            <jats:sub>2<\/jats:sub>\n            O and Cs\n            <jats:sub>0.75<\/jats:sub>\n            [Cr\n            <jats:sub>2.125<\/jats:sub>\n            (CN)\n            <jats:sub>6<\/jats:sub>\n            ]\u22c55H\n            <jats:sub>2<\/jats:sub>\n            O, which exhibited magnetic-ordering temperatures of 240 and 190 kelvin, respectively, are reported, together with the strategy for further work.\n          <\/jats:p>","DOI":"10.1126\/science.262.5139.1554","type":"journal-article","created":{"date-parts":[[2006,10,5]],"date-time":"2006-10-05T23:05:09Z","timestamp":1160089509000},"page":"1554-1557","source":"Crossref","is-referenced-by-count":790,"title":["High-\n            <i>T<\/i>\n            <sub>c<\/sub>\n            Molecular-Based Magnets: Ferrimagnetic Mixed-Valence Chromium(III)-Chromium(II) Cyanides with\n            <i>T<\/i>\n            <sub>c<\/sub>\n            at 240 and 190 Kelvin"],"prefix":"10.1126","volume":"262","author":[{"given":"T.","family":"Mallah","sequence":"first","affiliation":[{"name":"Laboratoire de Chimie des M\u00e9taux de Transition, U.A. Centre National de la Recherche Scientifique 419, Universit\u00e9 Pierre et Marie Curie, 4 Place Jussieu, 75252 Paris, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"S.","family":"Thi\u00e9baut","sequence":"additional","affiliation":[{"name":"Laboratoire de Chimie des M\u00e9taux de Transition, U.A. Centre National de la Recherche Scientifique 419, Universit\u00e9 Pierre et Marie Curie, 4 Place Jussieu, 75252 Paris, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"M.","family":"Verdaguer","sequence":"additional","affiliation":[{"name":"Laboratoire de Chimie des M\u00e9taux de Transition, U.A. Centre National de la Recherche Scientifique 419, Universit\u00e9 Pierre et Marie Curie, 4 Place Jussieu, 75252 Paris, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"P.","family":"Veillet","sequence":"additional","affiliation":[{"name":"Institut d'Electronique Fondamentale, U.A. Centre National de la Recherche Scientifique 22, Universit\u00e9 de Paris Sud, 91405 Orsay, France"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"221","reference":[{"key":"e_1_2_1_1_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.253.5017.301"},{"key":"e_1_2_1_2_1","first-page":"25","volume":"1","year":"1963","unstructured":"Anderson, P. W., Magnetism 1: 25 (1963).","journal-title":"Magnetism"},{"key":"e_1_2_1_3_1","doi-asserted-by":"crossref","first-page":"572","DOI":"10.1103\/PhysRev.103.572","volume":"103","year":"1956","unstructured":"BOZORTH, R.M., MAGNETIC PROPERTIES OF SOME ORTHOFERRITES AND CYANIDES AT LOW TEMPERATURES, PHYSICAL REVIEW 103: 572 (1956).","journal-title":"PHYSICAL REVIEW"},{"key":"e_1_2_1_4_1","first-page":"215","year":"1991","unstructured":"Caneschi, A., Molecular Magnetic Materials: 215 (1991).","journal-title":"Molecular Magnetic Materials"},{"key":"e_1_2_1_5_1","doi-asserted-by":"crossref","first-page":"203","DOI":"10.1007\/BF00618223","volume":"6","year":"1981","unstructured":"EATON, J.P., THE COMPLEX CYANIDES OF CHROMIUM (II) AND CHROMIUM (0), TRANSITION METAL CHEMISTRY 6: 203 (1981).","journal-title":"TRANSITION METAL CHEMISTRY"},{"key":"e_1_2_1_6_1","doi-asserted-by":"crossref","first-page":"101","DOI":"10.1021\/ic00248a021","volume":"26","year":"1987","unstructured":"FIGGIS, B.N., SPIN-DENSITY OF THE HEXACYANOCHROMATE(III) ION MEASURED BY POLARIZED NEUTRON-DIFFRACTION, INORGANIC CHEMISTRY 26: 101 (1987).","journal-title":"INORGANIC CHEMISTRY"},{"key":"e_1_2_1_7_1","first-page":"188","volume":"6","year":"1964","unstructured":"Figgis, B. N., Progress in Inorganic Chemistry 6: 188 (1964).","journal-title":"Progress in Inorganic Chemistry"},{"key":"e_1_2_1_8_1","doi-asserted-by":"crossref","first-page":"9213","DOI":"10.1021\/ja00049a078","volume":"114","year":"1992","unstructured":"GADET, V, HIGH-TC MOLECULAR-BASED MAGNETS - A FERROMAGNETIC BIMETALLIC CHROMIUM(III) NICKEL(II) CYANIDE WITH TC = 90-K, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 114: 9213 (1992).","journal-title":"JOURNAL OF THE AMERICAN CHEMICAL SOCIETY"},{"key":"e_1_2_1_9_1","first-page":"281","year":"1991","unstructured":"Gadet, V., Molecular Magnetic Materials: 281 (1991).","journal-title":"Molecular Magnetic Materials"},{"key":"e_1_2_1_10_1","unstructured":"GADET V THESIS U P M CURIE P (1992)."},{"key":"e_1_2_1_11_1","unstructured":"Goodenough J. B. Magnetism and the Chemical Bond (1963)."},{"key":"e_1_2_1_12_1","first-page":"832","volume":"87","year":"1982","unstructured":"GRIEBLER, W. D., ZEITSCHRIFT FUR NATURFORSCHUNG B 87: 832 (1982).","journal-title":"ZEITSCHRIFT FUR NATURFORSCHUNG B"},{"key":"e_1_2_1_13_1","doi-asserted-by":"crossref","first-page":"121","DOI":"10.1016\/S0020-1693(00)94793-5","volume":"7","year":"1973","unstructured":"GUDEL, H.U., INORG CHIM ACTA 7: 121 (1973).","journal-title":"INORG CHIM ACTA"},{"key":"e_1_2_1_14_1","doi-asserted-by":"crossref","first-page":"4884","DOI":"10.1021\/ja00850a018","volume":"97","year":"1975","unstructured":"HAY, P.J., ORBITAL INTERACTIONS IN METAL DIMER COMPLEXES, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 97: 4884 (1975).","journal-title":"JOURNAL OF THE AMERICAN CHEMICAL SOCIETY"},{"key":"e_1_2_1_15_1","doi-asserted-by":"crossref","first-page":"1463","DOI":"10.1103\/PhysRev.102.1463","volume":"102","year":"1956","unstructured":"HOLDEN, A.N., NEW LOW-TEMPERATURE FERROMAGNETS, PHYSICAL REVIEW 102: 1463 (1956).","journal-title":"PHYSICAL REVIEW"},{"key":"e_1_2_1_16_1","doi-asserted-by":"crossref","first-page":"3597","DOI":"10.1063\/1.1669656","volume":"48","year":"1968","unstructured":"ITO, A, MOSSBAUER STUDY OF SOLUBLE PRUSSIAN BLUE INSOLUBLE PRUSSIAN BLUE AND TURNBULLS BLUE, JOURNAL OF CHEMICAL PHYSICS 48: 3597 (1968).","journal-title":"JOURNAL OF CHEMICAL PHYSICS"},{"key":"e_1_2_1_17_1","first-page":"37","year":"1985","unstructured":"Kahn, O., Magneto-Structural Correlations, in Exchanged Coupled Systems: 37 (1985).","journal-title":"Magneto-Structural Correlations, in Exchanged Coupled Systems"},{"key":"e_1_2_1_18_1","first-page":"35","year":"1991","unstructured":"Kahn, O., Molecular Magnetic Materials: 35 (1991).","journal-title":"Molecular Magnetic Materials"},{"key":"e_1_2_1_19_1","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1007\/BFb0016869","volume":"14","year":"1973","unstructured":"Ludi, A., Structure and Bonding 14: 1 (1973).","journal-title":"Structure and Bonding"},{"key":"e_1_2_1_20_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.252.5011.1415"},{"key":"e_1_2_1_21_1","first-page":"151","year":"1991","unstructured":"Miller, J. S., Molecular Magnetic Materials: 151 (1991).","journal-title":"Molecular Magnetic Materials"},{"key":"e_1_2_1_22_1","unstructured":"Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordination Compounds 3 259 (1978)."},{"key":"e_1_2_1_23_1","first-page":"10","volume":"3","year":"1948","unstructured":"NEEL, L, ANN PHYS-PARIS 3: 10 (1948).","journal-title":"ANN PHYS-PARIS"},{"key":"e_1_2_1_24_1","first-page":"203","year":"1991","unstructured":"Rey, P., Molecular Magnetic Materials: 203 (1991).","journal-title":"Molecular Magnetic Materials"},{"key":"e_1_2_1_25_1","doi-asserted-by":"crossref","first-page":"337","DOI":"10.1021\/ic50002a028","volume":"1","year":"1962","unstructured":"ROBIN, M.B., COLOR AND ELECTRONIC CONFIGURATIONS OF PRUSSIAN BLUE, INORGANIC CHEMISTRY 1: 337 (1962).","journal-title":"INORGANIC CHEMISTRY"},{"key":"e_1_2_1_26_1","first-page":"467","volume":"1","year":"1977","unstructured":"TOLA, P, NOUVEAU JOURNAL DE CHIMIE-NEW JOURNAL OF CHEMISTRY 1: 467 (1977).","journal-title":"NOUVEAU JOURNAL DE CHIMIE-NEW JOURNAL OF CHEMISTRY"},{"key":"e_1_2_1_27_1","first-page":"15","volume":"33","year":"1734","unstructured":"WOODWARD, M, PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY OF LONDON 33: 15 (1734).","journal-title":"PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY OF LONDON"}],"container-title":["Science"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.science.org\/doi\/pdf\/10.1126\/science.262.5139.1554","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,1,12]],"date-time":"2024-01-12T23:19:14Z","timestamp":1705101554000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.science.org\/doi\/10.1126\/science.262.5139.1554"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[1993,12,3]]},"references-count":27,"journal-issue":{"issue":"5139","published-print":{"date-parts":[[1993,12,3]]}},"alternative-id":["10.1126\/science.262.5139.1554"],"URL":"https:\/\/doi.org\/10.1126\/science.262.5139.1554","relation":{},"ISSN":["0036-8075","1095-9203"],"issn-type":[{"value":"0036-8075","type":"print"},{"value":"1095-9203","type":"electronic"}],"subject":[],"published":{"date-parts":[[1993,12,3]]}}}