{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,9]],"date-time":"2026-10-09T16:19:44Z","timestamp":1791562784654,"version":"4.3.4"},"reference-count":12,"publisher":"American Association for the Advancement of Science (AAAS)","issue":"5143","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Science"],"published-print":{"date-parts":[[1994,1,7]]},"abstract":"<jats:p>\n            Hydrofluorocarbons, many of which contain a CF\n            <jats:sub>3<\/jats:sub>\n            group, are one of the major substitutes for the chlorofluorocarbons and halons that are being phased out because they contribute to stratospheric ozone depletion. It is critical to ensure that CF\n            <jats:sub>3<\/jats:sub>\n            groups do not cause significant ozone depletion. The rate coefficients for the key reactions that determine the efficiency of the CF\n            <jats:sub>3<\/jats:sub>\n            radical as a catalyst for ozone loss in the stratosphere have been measured and used in a model to calculate the possible depletion of ozone. From these results, it is concluded that the ozone depletion potentials related to the presence of the CF\n            <jats:sub>3<\/jats:sub>\n            group in hydrofluorocarbons are negligibly small.\n          <\/jats:p>","DOI":"10.1126\/science.263.5143.71","type":"journal-article","created":{"date-parts":[[2006,10,6]],"date-time":"2006-10-06T00:01:25Z","timestamp":1160092885000},"page":"71-75","source":"Crossref","is-referenced-by-count":248,"title":["Do Hydrofluorocarbons Destroy Stratospheric Ozone?"],"prefix":"10.1126","volume":"263","author":[{"given":"A. R.","family":"Ravishankara","sequence":"first","affiliation":[{"name":"National Oceanic and Atmospheric Administration, Aeronomy Laboratory, 325 Broadway, Boulder, CO 80303"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andrew A.","family":"Turnipseed","sequence":"additional","affiliation":[{"name":"National Oceanic and Atmospheric Administration, Aeronomy Laboratory, 325 Broadway, Boulder, CO 80303"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Niels R.","family":"Jensen","sequence":"additional","affiliation":[{"name":"National Oceanic and Atmospheric Administration, Aeronomy Laboratory, 325 Broadway, Boulder, CO 80303"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Stephen","family":"Barone","sequence":"additional","affiliation":[{"name":"National Oceanic and Atmospheric Administration, Aeronomy Laboratory, 325 Broadway, Boulder, CO 80303"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michael","family":"Mills","sequence":"additional","affiliation":[{"name":"National Oceanic and Atmospheric Administration, Aeronomy Laboratory, 325 Broadway, Boulder, CO 80303"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Carleton J.","family":"Howard","sequence":"additional","affiliation":[{"name":"National Oceanic and Atmospheric Administration, Aeronomy Laboratory, 325 Broadway, Boulder, CO 80303"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Susan","family":"Solomon","sequence":"additional","affiliation":[{"name":"National Oceanic and Atmospheric Administration, Aeronomy Laboratory, 325 Broadway, Boulder, CO 80303"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"221","reference":[{"key":"e_1_2_1_1_1","unstructured":"Scientific Assessment of Stratospheric Ozone: 1991 (1992)."},{"key":"e_1_2_1_2_1","doi-asserted-by":"crossref","first-page":"3750","DOI":"10.1021\/j100117a020","volume":"97","year":"1993","unstructured":"Bevilacqua, T. B., Journal of Physical Chemistry 97: 3750 (1993).","journal-title":"Journal of Physical Chemistry"},{"key":"e_1_2_1_3_1","unstructured":"Biggs P. paper presented at STEPHALOCIDE\/AFEAS Workshop University College Dublin Ireland 23 to 25 March (1993)."},{"key":"e_1_2_1_4_1","first-page":"6115","volume":"96","year":"1992","unstructured":"Chen, J., Journal of Physical Chemistry 96: 6115 (1992).","journal-title":"Journal of Physical Chemistry"},{"key":"e_1_2_1_5_1","unstructured":"DeMore W. B. Jet Propulsion Laboratory Chemical Kinetics and Photochemical Data for Use in Stratospheric Modeling (1992)."},{"key":"e_1_2_1_6_1","doi-asserted-by":"crossref","first-page":"12967","DOI":"10.1029\/92JD00960","volume":"97","year":"1992","unstructured":"GARCIA, R. R., JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES 97: 12967 (1992).","journal-title":"JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES"},{"key":"e_1_2_1_7_1","doi-asserted-by":"crossref","first-page":"336","DOI":"10.1016\/0009-2614(91)90188-F","volume":"186","year":"1991","unstructured":"LI, Z, LASER-INDUCED FLUORESCENCE SPECTROSCOPIC STUDY OF THE A2A1-X2E TRANSITION OF TRIFLUOROMETHOXY RADICAL, CHEMICAL PHYSICS LETTERS 186: 336 (1991).","journal-title":"CHEMICAL PHYSICS LETTERS"},{"key":"e_1_2_1_8_1","doi-asserted-by":"crossref","first-page":"151","DOI":"10.1016\/0009-2614(93)87216-P","volume":"209","year":"1993","unstructured":"LI, Z.J., AN EXAMINATION OF PATHWAYS FOR THE REACTION OF OXYGEN-ATOMS WITH CF3O RADICALS - IMPLICATIONS FOR THE ROLE OF CF3 RADICALS IN STRATOSPHERIC CHEMICAL PROCESSES, CHEMICAL PHYSICS LETTERS 209: 151 (1993).","journal-title":"CHEMICAL PHYSICS LETTERS"},{"key":"e_1_2_1_9_1","doi-asserted-by":"crossref","first-page":"349","DOI":"10.1016\/0009-2614(93)85563-4","volume":"206","year":"1993","unstructured":"SAATHOFF, H, LIF DETECTION OF THE CF3O RADICAL AND KINETICS OF ITS REACTIONS WITH CH4 AND C2H6, CHEMICAL PHYSICS LETTERS 206: 349 (1993).","journal-title":"CHEMICAL PHYSICS LETTERS"},{"key":"e_1_2_1_10_1","doi-asserted-by":"crossref","first-page":"825","DOI":"10.1029\/91JD02613","volume":"97","year":"1992","unstructured":"SOLOMON, S, JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES 97: 825 (1992).","journal-title":"JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES"},{"key":"e_1_2_1_11_1","doi-asserted-by":"crossref","first-page":"7502","DOI":"10.1021\/j100198a006","volume":"96","year":"1992","unstructured":"TURNIPSEED, A.A., OBSERVATION OF CH3S ADDITION TO O-2 IN THE GAS-PHASE, JOURNAL OF PHYSICAL CHEMISTRY 96: 7502 (1992).","journal-title":"JOURNAL OF PHYSICAL CHEMISTRY"},{"key":"e_1_2_1_12_1","doi-asserted-by":"crossref","first-page":"5926","DOI":"10.1021\/j100124a025","volume":"97","year":"1993","unstructured":"TURNIPSEED, A.A., REACTIONS OF CH3S AND CH3SOO WITH O3, NO2, AND NO, JOURNAL OF PHYSICAL CHEMISTRY 97: 5926 (1993).","journal-title":"JOURNAL OF PHYSICAL CHEMISTRY"}],"container-title":["Science"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.science.org\/doi\/pdf\/10.1126\/science.263.5143.71","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,1,12]],"date-time":"2024-01-12T22:39:26Z","timestamp":1705099166000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.science.org\/doi\/10.1126\/science.263.5143.71"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[1994,1,7]]},"references-count":12,"journal-issue":{"issue":"5143","published-print":{"date-parts":[[1994,1,7]]}},"alternative-id":["10.1126\/science.263.5143.71"],"URL":"https:\/\/doi.org\/10.1126\/science.263.5143.71","relation":{},"ISSN":["0036-8075","1095-9203"],"issn-type":[{"value":"0036-8075","type":"print"},{"value":"1095-9203","type":"electronic"}],"subject":[],"published":{"date-parts":[[1994,1,7]]}}}