{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,9,19]],"date-time":"2025-09-19T07:45:19Z","timestamp":1758267919214},"reference-count":25,"publisher":"American Association for the Advancement of Science (AAAS)","issue":"5276","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Science"],"published-print":{"date-parts":[[1996,8,9]]},"abstract":"<jats:p>\n            Irradiation of gaseous carbon disulfide [CS\n            <jats:sub>2(g)<\/jats:sub>\n            ] at 313 nanometers produces a dark brown aerosol of (CS\n            <jats:sub>2<\/jats:sub>\n            )\n            <jats:sub>\n              <jats:italic>x<\/jats:italic>\n            <\/jats:sub>\n            . Its thermal decomposition products include disulfur (S\n            <jats:sub>2<\/jats:sub>\n            ), carbon monosulfide (CS), and (CS)\n            <jats:sub>\n              <jats:italic>x<\/jats:italic>\n            <\/jats:sub>\n            . The photopolymerization process is accompanied by a large mass-independent isotopic fractionation of sulfur (a 5 to 10 per mil sulfur-33 excess and a 61 to 84 per mil sulfur-36 deficit). Excess sulfur-33 has been observed in several classes of meteorites. Photochemical production of (CS\n            <jats:sub>2<\/jats:sub>\n            )\n            <jats:sub>\n              <jats:italic>x<\/jats:italic>\n            <\/jats:sub>\n            may be important in the origin and evolution of cosmochemical environments such as the presolar nebula, meteorites, asteroids, and planetary atmospheres.\n          <\/jats:p>","DOI":"10.1126\/science.273.5276.774","type":"journal-article","created":{"date-parts":[[2006,10,27]],"date-time":"2006-10-27T18:30:41Z","timestamp":1161973841000},"page":"774-776","source":"Crossref","is-referenced-by-count":49,"title":["Photopolymerization and Mass-Independent Sulfur Isotope Fractionations in Carbon Disulfide"],"prefix":"10.1126","volume":"273","author":[{"given":"Jonah J.","family":"Colman","sequence":"first","affiliation":[{"name":"Department of Chemistry and Biochemistry, University of California at San Diego, La Jolla, CA 92093-0358, USA."}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xianping","family":"Xu","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry, University of California at San Diego, La Jolla, CA 92093-0358, USA."}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mark H.","family":"Thiemens","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry, University of California at San Diego, La Jolla, CA 92093-0358, USA."}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"William C.","family":"Trogler","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry, University of California at San Diego, La Jolla, CA 92093-0358, USA."}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"221","reference":[{"key":"e_1_2_1_2_2","doi-asserted-by":"crossref","first-page":"399","DOI":"10.2307\/20023421","volume":"74","author":"BRIDGMAN P.W.","year":"1941","unstructured":"BRIDGMAN P.W., P AM ACAD ARTS SCI 74, 399 (1941).","journal-title":"P AM ACAD ARTS SCI"},{"key":"e_1_2_1_3_2","doi-asserted-by":"crossref","first-page":"116","DOI":"10.1016\/0009-2614(71)80629-2","article-title":"2 EXPONENTIAL DECAY OF 3371 A LASER EXCITED CS2 FLUORESCENCE","volume":"12","author":"BRUS L.E.","year":"1971","unstructured":"BRUS L.E., 2 EXPONENTIAL DECAY OF 3371 A LASER EXCITED CS2 FLUORESCENCE, CHEMICAL PHYSICS LETTERS 12, 116 (1971).","journal-title":"CHEMICAL PHYSICS LETTERS"},{"key":"e_1_2_1_4_2","doi-asserted-by":"crossref","first-page":"2131","DOI":"10.1029\/95GL01898","article-title":"HIGH, ROOM AND LOW-TEMPERATURE PHOTOABSORPTION CROSS-SECTIONS OF CS2 IN THE 1800-2300-ANGSTROM REGION","volume":"22","author":"CHEN F.Z.","year":"1995","unstructured":"CHEN F.Z., HIGH, ROOM AND LOW-TEMPERATURE PHOTOABSORPTION CROSS-SECTIONS OF CS2 IN THE 1800-2300-ANGSTROM REGION, GEOPHYSICAL RESEARCH LETTERS 22, 2131 (1995).","journal-title":"GEOPHYSICAL RESEARCH LETTERS"},{"key":"e_1_2_1_5_2","doi-asserted-by":"crossref","first-page":"321","DOI":"10.1029\/93GB00568","article-title":"GLOBAL SOURCES AND SINKS OF OCS AND CS2 AND THEIR DISTRIBUTIONS","volume":"7","author":"CHIN M","year":"1993","unstructured":"CHIN M, GLOBAL SOURCES AND SINKS OF OCS AND CS2 AND THEIR DISTRIBUTIONS, GLOBAL BIOGEOCHEMICAL CYCLES 7, 321 (1993).","journal-title":"GLOBAL BIOGEOCHEMICAL CYCLES"},{"key":"e_1_2_1_6_2","doi-asserted-by":"crossref","first-page":"11270","DOI":"10.1021\/ja00150a026","article-title":"PHOTOPOLYMERIZATION OF CARBON-DISULFIDE YIELDS THE HIGH-PRESSURE-PHASE (CS2)(X)","volume":"117","author":"COLMAN J.J.","year":"1995","unstructured":"COLMAN J.J., PHOTOPOLYMERIZATION OF CARBON-DISULFIDE YIELDS THE HIGH-PRESSURE-PHASE (CS2)(X), JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 117, 11270 (1995).","journal-title":"JOURNAL OF THE AMERICAN CHEMICAL SOCIETY"},{"key":"e_1_2_1_7_2","author":"COLMAN J.J.","year":"1994","unstructured":"COLMAN J.J., 207 NAT M AM CHEM SO (1994).","journal-title":"207 NAT M AM CHEM SO"},{"key":"e_1_2_1_8_2","first-page":"500","article-title":"SULFUR AND HYDROGEN ISOTOPIC ANOMALIES IN ORGANIC-COMPOUNDS FROM THE MURCHISON METEORITE","volume":"30","author":"COOPER G.W.","year":"1995","unstructured":"COOPER G.W., SULFUR AND HYDROGEN ISOTOPIC ANOMALIES IN ORGANIC-COMPOUNDS FROM THE MURCHISON METEORITE, METEORITICS 30, 500 (1995).","journal-title":"METEORITICS"},{"key":"e_1_2_1_9_2","doi-asserted-by":"crossref","first-page":"246","DOI":"10.1016\/0019-1035(91)90210-K","article-title":"MICROWAVE OBSERVATIONS OF HYDROGEN-SULFIDE AND SEARCHES FOR OTHER SULFUR-COMPOUNDS IN COMETS AUSTIN (1989C1) AND LEVY (1990C)","volume":"93","author":"CROVISIER J","year":"1991","unstructured":"CROVISIER J, MICROWAVE OBSERVATIONS OF HYDROGEN-SULFIDE AND SEARCHES FOR OTHER SULFUR-COMPOUNDS IN COMETS AUSTIN (1989C1) AND LEVY (1990C), ICARUS 93, 246 (1991).","journal-title":"ICARUS"},{"key":"e_1_2_1_10_2","doi-asserted-by":"crossref","first-page":"357","DOI":"10.1063\/1.1725874","article-title":"ZEEMAN EFFECT + ROTATIONAL ANALYSES OF NEAR-ULTRAVIOLET BANDS OF CS2","volume":"41","author":"DOUGLAS A.E.","year":"1964","unstructured":"DOUGLAS A.E., ZEEMAN EFFECT + ROTATIONAL ANALYSES OF NEAR-ULTRAVIOLET BANDS OF CS2, JOURNAL OF CHEMICAL PHYSICS 41, 357 (1964).","journal-title":"JOURNAL OF CHEMICAL PHYSICS"},{"key":"e_1_2_1_11_2","doi-asserted-by":"crossref","first-page":"3159","DOI":"10.1016\/0016-7037(93)90300-L","article-title":"ISOTOPIC COMPOSITION AND CONCENTRATION OF SULFUR IN CARBONACEOUS CHONDRITES","volume":"57","author":"GAO X","year":"1993","unstructured":"GAO X, ISOTOPIC COMPOSITION AND CONCENTRATION OF SULFUR IN CARBONACEOUS CHONDRITES, GEOCHIMICA ET COSMOCHIMICA ACTA 57, 3159 (1993).","journal-title":"GEOCHIMICA ET COSMOCHIMICA ACTA"},{"key":"e_1_2_1_12_2","doi-asserted-by":"crossref","first-page":"327","DOI":"10.1111\/j.1945-5100.1992.tb00215.x","article-title":"UREILITES - A CRITICAL-REVIEW","volume":"27","author":"GOODRICH C.A.","year":"1992","unstructured":"GOODRICH C.A., UREILITES - A CRITICAL-REVIEW, METEORITICS 27, 327 (1992).","journal-title":"METEORITICS"},{"key":"e_1_2_1_13_2","doi-asserted-by":"crossref","first-page":"2752","DOI":"10.1063\/1.467658","article-title":"SUB-DOPPLER LASER SPECTROSCOPY OF THE B-1(2)((1)DELTA(U)) STATE OF CS2 IN A COLD MOLECULAR-BEAM","volume":"101","author":"HABIB A","year":"1994","unstructured":"HABIB A, SUB-DOPPLER LASER SPECTROSCOPY OF THE B-1(2)((1)DELTA(U)) STATE OF CS2 IN A COLD MOLECULAR-BEAM, JOURNAL OF CHEMICAL PHYSICS 101, 2752 (1994).","journal-title":"JOURNAL OF CHEMICAL PHYSICS"},{"key":"e_1_2_1_14_2","doi-asserted-by":"crossref","first-page":"515","DOI":"10.1086\/164185","article-title":"THE ORIGIN OF CS IN COMET IRAS-ARAKI-ALCOCK-1983D","volume":"304","author":"JACKSON W.M.","year":"1986","unstructured":"JACKSON W.M., THE ORIGIN OF CS IN COMET IRAS-ARAKI-ALCOCK-1983D, ASTROPHYSICAL JOURNAL 304, 515 (1986).","journal-title":"ASTROPHYSICAL JOURNAL"},{"key":"e_1_2_1_15_2","doi-asserted-by":"crossref","first-page":"2601","DOI":"10.1139\/v73-393","article-title":"FLUORESCENCE OF CS2 VAPOR","volume":"51","author":"LAMBERT C","year":"1973","unstructured":"LAMBERT C, FLUORESCENCE OF CS2 VAPOR, CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE 51, 2601 (1973).","journal-title":"CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE"},{"key":"e_1_2_1_16_2","doi-asserted-by":"crossref","first-page":"592","DOI":"10.1038\/373592a0","volume":"373","author":"LELBUCH E","year":"1995","unstructured":"LELBUCH E, NATURE 373, 592 (1995).","journal-title":"NATURE"},{"key":"e_1_2_1_17_2","doi-asserted-by":"crossref","first-page":"1597","DOI":"10.1029\/95GL01200","article-title":"POST-SL9 SULFUR PHOTOCHEMISTRY ON JUPITER","volume":"22","author":"MOSES J.I.","year":"1995","unstructured":"MOSES J.I., POST-SL9 SULFUR PHOTOCHEMISTRY ON JUPITER, GEOPHYSICAL RESEARCH LETTERS 22, 1597 (1995).","journal-title":"GEOPHYSICAL RESEARCH LETTERS"},{"key":"e_1_2_1_18_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.272.5263.846"},{"key":"e_1_2_1_19_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.7871428"},{"key":"e_1_2_1_20_2","first-page":"1697","volume":"41","author":"REES C.E.","year":"1977","unstructured":"REES C.E., GEOCHIM COSMOCHIM AC 41, 1697 (1977).","journal-title":"GEOCHIM COSMOCHIM AC"},{"key":"e_1_2_1_21_2","doi-asserted-by":"crossref","first-page":"138","DOI":"10.1021\/bk-1992-0502.ch009","author":"THIEMENS M.H.","year":"1992","unstructured":"THIEMENS M.H., ISOTOPE EFFECTS GAS: 138 (1992).","journal-title":"ISOTOPE EFFECTS GAS"},{"key":"e_1_2_1_22_2","first-page":"1405","volume":"26","author":"THIEMENS M.H.","year":"1995","unstructured":"THIEMENS M.H., LUNAR PLANET SCI 26, 1405 (1995).","journal-title":"LUNAR PLANET SCI"},{"key":"e_1_2_1_23_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.7871424"},{"key":"e_1_2_1_24_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.7871426"},{"key":"e_1_2_1_25_2","doi-asserted-by":"crossref","first-page":"1709","DOI":"10.1016\/0016-7037(91)90141-Q","article-title":"NOBLE-GASES IN PHASE-Q - CLOSED-SYSTEM ETCHING OF AN ALLENDE RESIDUE","volume":"55","author":"WIELER R","year":"1991","unstructured":"WIELER R, NOBLE-GASES IN PHASE-Q - CLOSED-SYSTEM ETCHING OF AN ALLENDE RESIDUE, GEOCHIMICA ET COSMOCHIMICA ACTA 55, 1709 (1991).","journal-title":"GEOCHIMICA ET COSMOCHIMICA ACTA"},{"key":"e_1_2_1_26_2","doi-asserted-by":"crossref","first-page":"1593","DOI":"10.1029\/95GL01190","article-title":"SULFUR CHEMISTRY IN THE WAKE OF COMET SHOEMAKER-LEVY-9","volume":"22","author":"ZAHNLE K","year":"1995","unstructured":"ZAHNLE K, SULFUR CHEMISTRY IN THE WAKE OF COMET SHOEMAKER-LEVY-9, GEOPHYSICAL RESEARCH LETTERS 22, 1593 (1995).","journal-title":"GEOPHYSICAL RESEARCH LETTERS"}],"container-title":["Science"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.science.org\/doi\/pdf\/10.1126\/science.273.5276.774","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,1,13]],"date-time":"2024-01-13T04:14:15Z","timestamp":1705119255000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.science.org\/doi\/10.1126\/science.273.5276.774"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[1996,8,9]]},"references-count":25,"journal-issue":{"issue":"5276","published-print":{"date-parts":[[1996,8,9]]}},"alternative-id":["10.1126\/science.273.5276.774"],"URL":"https:\/\/doi.org\/10.1126\/science.273.5276.774","relation":{},"ISSN":["0036-8075","1095-9203"],"issn-type":[{"value":"0036-8075","type":"print"},{"value":"1095-9203","type":"electronic"}],"subject":[],"published":{"date-parts":[[1996,8,9]]}}}