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However, multiconfigurational quantum chemical calculations predict the ground state of the compound to be dominated (76%) by a spin triplet. The apparent diamagnetism is explained by an extremely large SOC-induced positive zero-field splitting of more than 4500 wavenumbers that leaves the M\n            <jats:italic>\n              <jats:sub>S<\/jats:sub>\n            <\/jats:italic>\n            = 0 magnetic sublevel thermally isolated in the electronic ground state.\n          <\/jats:p>","DOI":"10.1126\/science.adg2833","type":"journal-article","created":{"date-parts":[[2023,5,18]],"date-time":"2023-05-18T18:00:45Z","timestamp":1684432845000},"page":"1043-1048","update-policy":"https:\/\/doi.org\/10.34133\/aaas_crossmark","source":"Crossref","is-referenced-by-count":126,"title":["Synthesis and isolation of a triplet bismuthinidene with a quenched magnetic response"],"prefix":"10.1126","volume":"380","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5152-6876","authenticated-orcid":true,"given":"Yue","family":"Pang","sequence":"first","affiliation":[{"name":"Max-Planck-Institut f\u00fcr Kohlenforschung, 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