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We report chirality-mediated interfaces based on\n            <jats:italic>R<\/jats:italic>\n            -\/\n            <jats:italic>S<\/jats:italic>\n            -methylbenzyl-ammonium between the perovskite absorber and electron-transport layer to create an elastic yet strong heterointerface with increased mechanical reliability. This interface harnesses enantiomer-controlled entropy to enhance tolerance to thermal cycling\u2013induced fatigue and material degradation, and a heterochiral arrangement of organic cations leads to closer packing of benzene rings, which enhances chemical stability and charge transfer. The encapsulated PSCs showed retentions of 92% of power-conversion efficiency under a thermal cycling test (\u221240\u00b0C to 85\u00b0C; 200 cycles over 1200 hours) and 92% under a damp heat test (85% relative humidity; 85\u00b0C; 600 hours).\n          <\/jats:p>","DOI":"10.1126\/science.ado5172","type":"journal-article","created":{"date-parts":[[2024,5,23]],"date-time":"2024-05-23T18:03:18Z","timestamp":1716487398000},"page":"878-884","update-policy":"https:\/\/doi.org\/10.34133\/aaas_crossmark","source":"Crossref","is-referenced-by-count":226,"title":["Chiral-structured heterointerfaces enable durable perovskite solar cells"],"prefix":"10.1126","volume":"384","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-2692-508X","authenticated-orcid":true,"given":"Tianwei","family":"Duan","sequence":"first","affiliation":[{"name":"Department of Physics, Hong Kong Baptist University, Kowloon, Hong Kong SAR 999077, 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