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The breadth of these synthetically valuable transformations is constrained by the range of molecules\u2014and particularly the functional groups\u2014that can deliver productive excited states, with most methods using the same functional groups that were defined more than 100 years ago. In this work, we show that\n                    <jats:italic toggle=\"yes\">N<\/jats:italic>\n                    -silyl sulfinylamines can undergo synthetically useful excited-state reactivity accessed using energy transfer catalysts and visible light. We exploit these intermediates in reactions with alkenes to form four-membered cyclic sulfinamide products. The reactions are efficient and broad in scope, and the products are advanced to sulfonamides as well as four-membered cyclic sulfonimidamides.\n                  <\/jats:p>","DOI":"10.1126\/science.aec3158","type":"journal-article","created":{"date-parts":[[2026,1,8]],"date-time":"2026-01-08T19:02:31Z","timestamp":1767898951000},"page":"202-207","update-policy":"https:\/\/doi.org\/10.34133\/aaas_crossmark","source":"Crossref","is-referenced-by-count":16,"title":["Access to four-membered cyclic sulfinamides by energy transfer catalysis"],"prefix":"10.1126","volume":"391","author":[{"ORCID":"https:\/\/orcid.org\/0009-0007-0816-3647","authenticated-orcid":true,"given":"Di","family":"Zhai","sequence":"first","affiliation":[{"name":"Department of Chemistry, University of Oxford, Oxford, UK."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0003-3238-3560","authenticated-orcid":true,"given":"Benedict A.","family":"Williams","sequence":"additional","affiliation":[{"name":"Department of Chemistry, University of Oxford, Oxford, UK."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4477-3027","authenticated-orcid":true,"given":"Lo\u00efc R. 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