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Extracts from<jats:italic>Cunninghamella<\/jats:italic>revealed tetradecanoic acid and 13-tetradecenoic acid from the oxidation of<jats:italic>n<\/jats:italic>-tetradecane and 1-tetradecene, respectively, thereby indicating that these hydrocarbons were subject to methyl group oxidation. In contrast to<jats:italic>Cunninghamella<\/jats:italic>, the<jats:italic>Penicillium<\/jats:italic>oxidized the two substrates by subterminal attacks on methylene rather than methyl groups. This was evidenced by tentative identifications of the following alcohols and ketones from oxidation of the hydrocarbons: tetradecan-2-ol, dodecan-1-ol, tetradecan-2-one, and tetradecan-4-one from<jats:italic>n<\/jats:italic>-tetradecane, and tetradecen-4-ol, 13-tetradecen-4-ol, tetradecen-3-ol, 13-tetradecen-4-one, and tetradecen-3-one from 1-tetradecene. A pathway for hydrocarbon oxidation is proposed for subterminal oxidation at the methylene alpha to the methyl group.<\/jats:p>","DOI":"10.1128\/jb.103.2.426-434.1970","type":"journal-article","created":{"date-parts":[[2020,1,3]],"date-time":"2020-01-03T14:26:50Z","timestamp":1578061610000},"page":"426-434","update-policy":"http:\/\/dx.doi.org\/10.1128\/asmj-crossmark-policy-page","source":"Crossref","is-referenced-by-count":28,"title":["Oxidation of<i>n<\/i>-Tetradecane and 1-Tetradecene by Fungi"],"prefix":"10.1128","volume":"103","author":[{"given":"J. E.","family":"Allen","sequence":"first","affiliation":[{"name":"Department of Microbiology, University of Iowa, Iowa City, Iowa 52240"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"A. 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