{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,7]],"date-time":"2025-11-07T13:15:52Z","timestamp":1762521352829},"reference-count":0,"publisher":"Institute of Organic Chemistry & Biochemistry","issue":"4","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Collect. Czech. Chem. Commun."],"published-print":{"date-parts":[[1990]]},"abstract":"<jats:p>The heterogeneous K<jats:sub>2<\/jats:sub>SeO<jats:sub>4<\/jats:sub>-M<jats:sup>II<\/jats:sup>SeO<jats:sub>4<\/jats:sub>-H<jats:sub>2<\/jats:sub>O system (M<jats:sup>II<\/jats:sup> = Mn, Co, Ni, Cu, Zn) at 298 K was studied using the Filippov eutonic method, yielding values for the change in the standard Gibbs energy \u0394<jats:italic>G<\/jats:italic><jats:sup>0<\/jats:sup> for the formation of double selenates in the range 16.2-30.3 kJ\/mol. It follows from the \u0394<jats:italic>G<\/jats:italic><jats:sup>0<\/jats:sup> values that, in systems without strong interactions in the liquid phase, the formation of poorly soluble double selenates from readily soluble selenates is energetically most favourable.<\/jats:p>","DOI":"10.1135\/cccc19900994","type":"journal-article","created":{"date-parts":[[2010,2,11]],"date-time":"2010-02-11T14:00:46Z","timestamp":1265896846000},"page":"994-1001","source":"Crossref","is-referenced-by-count":3,"title":["The change in the standard Gibbs energy \u0394G0 in the formation of double selenates K2MII(SCo4)2\u00b7x H2O (MII = Mn, Co, Ni, Cu, Zn; x = 6 or 2)"],"prefix":"10.1135","volume":"55","author":[{"given":"Pavel","family":"Vojt\u00ed\u0161ek","sequence":"first","affiliation":[]},{"given":"Miroslav","family":"Ebert","sequence":"additional","affiliation":[]}],"member":"111","published-online":{"date-parts":[[1990]]},"container-title":["Collection of Czechoslovak Chemical Communications"],"original-title":[],"language":"en","deposited":{"date-parts":[[2018,9,9]],"date-time":"2018-09-09T15:44:12Z","timestamp":1536507852000},"score":1,"resource":{"primary":{"URL":"http:\/\/cccc.uochb.cas.cz\/55\/4\/0994\/"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[1990]]},"references-count":0,"journal-issue":{"issue":"4","published-online":{"date-parts":[[1990]]},"published-print":{"date-parts":[[1990]]}},"alternative-id":["cccc19900994"],"URL":"https:\/\/doi.org\/10.1135\/cccc19900994","relation":{},"ISSN":["0010-0765","1212-6950"],"issn-type":[{"value":"0010-0765","type":"print"},{"value":"1212-6950","type":"electronic"}],"subject":[],"published":{"date-parts":[[1990]]}}}