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This paper presents a comprehensive research on measuring political polarization on X (Twitter) during election cycles in Spain, from 2011 to 2019. A wide comparative analysis is performed on algorithms used to identify and measure polarization or controversy on microblogging platforms. This analysis is specifically tailored towards publications made by official political party accounts during pre-campaign, campaign, election day, and the week post-election. Guided by the findings of this comparative evaluation, we propose a novel algorithm better suited to capture polarization in the context of political events, which is validated with real data. 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