{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,2]],"date-time":"2025-11-02T19:52:11Z","timestamp":1762113131628,"version":"3.28.0"},"reference-count":62,"publisher":"Geological Society of London","issue":"2","license":[{"start":{"date-parts":[[2003,3,1]],"date-time":"2003-03-01T00:00:00Z","timestamp":1046476800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-002"}],"content-domain":{"domain":["www.lyellcollection.org"],"crossmark-restriction":true},"short-container-title":["JGS"],"published-print":{"date-parts":[[2003,3]]},"abstract":"<jats:p>\n            Vein-type and bedding-concordant mesothermal (180\u2013410 \u00b0C) stibnite\u2013sulphosalt mineralization at Arnsberg, NE Rhenish Massif, Germany, is hosted by Carboniferous pyrite-rich black shales and siliceous limestones. A detailed sulphur isotope study of the stibnite\u2013sulphosalt mineralization and pyrite from a variety of regional host-rock lithologies has been carried out using an\n            <jats:italic>in situ<\/jats:italic>\n            laser combustion technique. The\n            <jats:italic>\u03b4<\/jats:italic>\n            <jats:sup>34<\/jats:sup>\n            S values of stibnite of various textural types are distinctly negative and lie in a narrow range between \u221223.9\u2030 and \u221217.1\u2030 (mean \u221220.1\u2030). In contrast, regional sedimentary\u2013diagenetic pyrites display a large variation of their\n            <jats:italic>\u03b4<\/jats:italic>\n            <jats:sup>34<\/jats:sup>\n            S values between \u221245.4\u2030 and +9.3\u2030. There is little evidence for significant modification of the hydrothermal fluid during deposition and the S isotope signatures suggest that the sulphur of the stibnite mineralization was not locally derived. The\n            <jats:italic>\u03b4<\/jats:italic>\n            <jats:sup>34<\/jats:sup>\n            S values of pyrite in Givetian shales display a significantly narrower range of \u221228.2\u2030 to \u22127.5\u2030 and their mean composition (\u221217.1\u2030) is close to the\n            <jats:italic>\u03b4<\/jats:italic>\n            <jats:sup>34<\/jats:sup>\n            S values of the Arnsberg stibnite deposits. Considering the temperature-dependent isotopic fractionation between stibnite and reduced sulfur species, the\n            <jats:italic>\u03b4<\/jats:italic>\n            <jats:sup>34<\/jats:sup>\n            S values of the mineralizing fluid (\u221216.8\u2030; 200 \u00b0C) and the Givetian rock source are essentially identical. Therefore, we propose a model of leaching and isotopic homogenization of sulphur from the Middle Devonian shales and a subsequent northward migration of these fluids. The fluids were trapped in permeability-controlled positions within anticlinal zones, where fluid cooling induced deposition of stibnite and sulphosalts.\n          <\/jats:p>","DOI":"10.1144\/0016-764902-010","type":"journal-article","created":{"date-parts":[[2008,10,17]],"date-time":"2008-10-17T17:04:50Z","timestamp":1224263090000},"page":"299-308","update-policy":"http:\/\/dx.doi.org\/10.1144\/crossmark-policy","source":"Crossref","is-referenced-by-count":14,"title":["Sulphur isotope geochemistry of black shale-hosted antimony mineralization, Arnsberg, northern Rhenish Massif, Germany: implications for late-stage fluid flow during the Variscan orogeny"],"prefix":"10.1144","volume":"160","author":[{"given":"Thomas","family":"Wagner","sequence":"first","affiliation":[{"name":"1Mineralogisches Institut, Universita\u0308t Wu\u0308rzburg, Am Hubland, D-97074 Wu\u0308rzburg, Germany"},{"name":"2Department of Earth and Planetary Sciences, McGill University, 3450 University Street, Montre\u0301al H3A 2A7, Quebec, Canada (e-mail: wagner@eps.mcgill.ca)"}]},{"given":"Adrian J.","family":"Boyce","sequence":"additional","affiliation":[{"name":"3Scottish Universities Environmental Research Centre (SUERC), East Kilbride, Glasgow G75 0QF, UK"}]}],"member":"1881","published-online":{"date-parts":[[2022,6,6]]},"reference":[{"key":"e_1_3_2_1_1","doi-asserted-by":"crossref","unstructured":"Ahrendt H. Clauer N. Hunziker J.C. & Weber K. 1983. Migration of folding and metamorphism in the Rheinisches Schiefergebirge deduced from K\u2013Ar and Rb\u2013Sr age determinations. In: Martin H. & Eder F.W. (eds) Intracontinental Fold Belts . Springer Berlin 323\u2013339.","DOI":"10.1007\/978-3-642-69124-9_15"},{"key":"e_1_3_2_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0375-6742(97)00011-3"},{"key":"e_1_3_2_3_1","doi-asserted-by":"publisher","DOI":"10.1130\/0016-7606(1977)88<1305:LPSFIS>2.0.CO;2"},{"key":"e_1_3_2_4_1","doi-asserted-by":"publisher","DOI":"10.1046\/j.1525-1314.2000.00257.x"},{"key":"e_1_3_2_5_1","first-page":"D33","volume":"18","year":"1979","unstructured":"Bauer, G., Ebert, A. , et al., 1979. Die Blei\u2013Zink-Erzlagerst\u00e4tten von Ramsbeck und Umgebung. Geologisches Jahrbuch, 18, D33.","journal-title":"Geologisches Jahrbuch"},{"key":"e_1_3_2_6_1","first-page":"3","volume":"58","year":"1993","unstructured":"Behr, H.J., Gerler, J., Hein, U.F. & Reutel, C.J. 1993. Tectonic Brines und Basement Brines in den mitteleurop\u00e4ischen Varisziden: Herkunft, metallogenetische Bedeutung und geologische Aktivit\u00e4t. G\u00f6ttinger Arbeiten zur Geologie und Pal\u00e4ontologie, 58, 3\u201328.","journal-title":"G\u00f6ttinger Arbeiten zur Geologie und Pal\u00e4ontologie"},{"key":"e_1_3_2_7_1","first-page":"103","volume":"13","year":"2000","unstructured":"Bierlein, F.P. & Crowe, D.E. 2000. Phanerozoic orogenic lode gold deposits. Reviews in Economic Geology, 13, 103\u2013139.","journal-title":"Reviews in Economic Geology"},{"key":"e_1_3_2_8_1","doi-asserted-by":"publisher","DOI":"10.1180\/minmag.1990.054.375.09"},{"key":"e_1_3_2_9_1","doi-asserted-by":"publisher","DOI":"10.1144\/gsjgs.145.6.0941"},{"key":"e_1_3_2_10_1","doi-asserted-by":"publisher","DOI":"10.1144\/gsjgs.145.1.0139"},{"key":"e_1_3_2_11_1","doi-asserted-by":"publisher","DOI":"10.1127\/zdgg\/146\/1995\/321"},{"key":"e_1_3_2_12_1","doi-asserted-by":"crossref","unstructured":"Canfield D.E. & Raiswell R. 1991. Pyrite formation and fossil preservation. In: Allison P.A. & Briggs D.E.G. (eds) Taphonomy: Releasing the Data Locked in the Fossil Record . Plenum New York 337\u2013387.","DOI":"10.1007\/978-1-4899-5034-5_7"},{"key":"e_1_3_2_13_1","unstructured":"Clausen C.D. 1984 Erl\u00e4uterungen zur geologischen Karte von Nordrhein-Westfalen 1:25 000 Blatt 4515 Hirschberg . Geologisches Landesamt Nordrhein-Westfalen Krefeld."},{"key":"e_1_3_2_14_1","unstructured":"Clausen C.D. & Leuteritz K. 1984 Erl\u00e4uterungen zur geologischen Karte von Nordrhein-Westfalen 1:25000 Blatt 4516 Warstein . Geologisches Landesamt Nordrhein-Westfalen Krefeld."},{"key":"e_1_3_2_15_1","unstructured":"Clausen C.D. von Kamp H. et al. 1981 Erl\u00e4uterungen zur geologischen Karte von Nordrhein-Westfalen 1:100 000 Blatt C4714 Arnsberg . Geologisches Landesamt Nordrhein-Westfalen Krefeld."},{"key":"e_1_3_2_16_1","doi-asserted-by":"publisher","DOI":"10.1007\/s001260050244"},{"key":"e_1_3_2_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/0169-1368(87)90024-2"},{"key":"e_1_3_2_18_1","doi-asserted-by":"publisher","DOI":"10.1007\/BF01821205"},{"key":"e_1_3_2_19_1","doi-asserted-by":"publisher","DOI":"10.1007\/s001260050155"},{"key":"e_1_3_2_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/0191-8141(94)90001-9"},{"key":"e_1_3_2_21_1","first-page":"53","volume":"101","year":"1992","unstructured":"Fallick, A.E., McConville, P., Boyce, A.J., Burgess, R. & Kelley, S.P. 1992. Laser microprobe stable isotope measurements on geological materials: some experimental considerations (with special reference to (34S in sulphides). Chemical Geology, 101, 53\u201361.","journal-title":"Chemical Geology"},{"key":"e_1_3_2_22_1","unstructured":"Franke W. & Oncken O. 1990. Geodynamic evolution of the North\u2013Central Variscides\u2014a comic strip. In: Freeman R. Giese P. & Mueller S. (eds) The European Geotraverse: Integrative Studies . European Science Foundation Strasbourg 187\u2013194."},{"key":"e_1_3_2_23_1","doi-asserted-by":"publisher","DOI":"10.1029\/91JB01639"},{"key":"e_1_3_2_24_1","first-page":"167","volume":"28","year":"1993","unstructured":"Guillemette, N., Williams-Jones, A.E. 1993. Genesis of the Sb\u2013W\u2013Au deposits at Ixtahuacan, Guatemala: evidence from fluid inclusions and stable isotopes. Mineralium Deposita, 28, 167\u2013180.","journal-title":"Mineralium Deposita"},{"key":"e_1_3_2_25_1","doi-asserted-by":"publisher","DOI":"10.2113\/gsecongeo.82.6.1453"},{"key":"e_1_3_2_26_1","doi-asserted-by":"publisher","DOI":"10.1180\/minmag.1993.057.388.08"},{"key":"e_1_3_2_27_1","first-page":"97","volume":"11","year":"2000","unstructured":"Heinrich, C.A., Andrew, A.S. & Knill, M.D. 2000. Regional metamorphism and ore formation: evidence from stable isotopes and other fluid tracers. Reviews in Economic Geology, 11, 97\u2013117.","journal-title":"Reviews in Economic Geology"},{"key":"e_1_3_2_28_1","doi-asserted-by":"publisher","DOI":"10.1007\/s005310050026"},{"key":"e_1_3_2_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/0016-7037(90)90381-T"},{"key":"e_1_3_2_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0191-8141(99)00187-X"},{"key":"e_1_3_2_31_1","unstructured":"Koch H.P. 1993 Sulfidgenese in Sedimenten des Rheinischen Schiefergebirges PhD Thesis University of G\u00f6ttingen."},{"key":"e_1_3_2_32_1","unstructured":"K\u00fchne F. 1938a Erl\u00e4uterungen zur geologischen Karte von Preu\u00dfen und benachbarten deutschen L\u00e4ndern 1:25 000 Blatt 4514 Arnsberg-Nord . Preu\u00dfische Geologische Landesanstalt Berlin."},{"key":"e_1_3_2_33_1","unstructured":"K\u00fchne F. 1938b Erl\u00e4uterungen zur geologischen Karte von Preu\u00dfen und benachbarten deutschen L\u00e4ndern 1:25 000 Blatt 4614 Arnsberg-S\u00fcd . Preu\u00dfische Geologische Landesanstalt Berlin."},{"key":"e_1_3_2_34_1","doi-asserted-by":"publisher","DOI":"10.1007\/s005310050216"},{"key":"e_1_3_2_35_1","first-page":"47","volume":"69","year":"2000","unstructured":"Muchez, P., Sintubin, M. & Swennen, R. 2000. Origin and migration of palaeofluids during orogeny: discussion on the Variscides of Belgium and northern France. Journal of Geochemical Exploration, 69-70, 47\u201351.","journal-title":"Journal of Geochemical Exploration"},{"key":"e_1_3_2_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/0016-7037(94)90008-6"},{"key":"e_1_3_2_37_1","doi-asserted-by":"publisher","DOI":"10.1111\/j.1365-3121.1992.tb00468.x"},{"key":"e_1_3_2_38_1","doi-asserted-by":"publisher","DOI":"10.2113\/gsecongeo.84.6.1489"},{"key":"e_1_3_2_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0375-6742(00)00153-9"},{"key":"e_1_3_2_40_1","doi-asserted-by":"publisher","DOI":"10.2113\/gsecongeo.67.5.551"},{"key":"e_1_3_2_41_1","unstructured":"Ohmoto H. & Goldhaber M.B. 1997. Sulfur and carbon isotopes. In: Barnes H.L. (ed.) Geochemistry of Hydrothermal Ore Deposits . 3rd edition Wiley New York 517\u2013611."},{"key":"e_1_3_2_42_1","unstructured":"Ohmoto H. & Rye R.O. 1979. Isotopes of sulfur and carbon. In: Barnes H.L. (ed.) Geochemistry of Hydrothermal Ore Deposits . 2nd edition Wiley New York 509\u2013567."},{"key":"e_1_3_2_43_1","doi-asserted-by":"publisher","DOI":"10.1046\/j.1468-8123.2001.00013.x"},{"key":"e_1_3_2_44_1","doi-asserted-by":"publisher","DOI":"10.1007\/BF01824975"},{"key":"e_1_3_2_45_1","doi-asserted-by":"publisher","DOI":"10.1016\/0040-1951(88)90027-3"},{"key":"e_1_3_2_46_1","first-page":"139","volume":"113","year":"1991","unstructured":"Oncken, O., 1991. Aspects of the structural and paleogeothermal evolution of the Rhenish Massif. Annales de Societe G\u00e9ologique Belgique, 113, 139\u2013159.","journal-title":"Annales de Societe G\u00e9ologique Belgique"},{"key":"e_1_3_2_47_1","doi-asserted-by":"publisher","DOI":"10.1127\/ejm\/7\/3\/0655"},{"key":"e_1_3_2_48_1","first-page":"69","volume":"13","year":"2000","unstructured":"Partington, G.A. & Williams, P.J. 2000. Proterozoic lode gold and (iron)\u2013 copper\u2013gold deposits: a comparison of Australian and global examples. Reviews in Economic Geology, 13, 69\u2013101.","journal-title":"Reviews in Economic Geology"},{"key":"e_1_3_2_49_1","doi-asserted-by":"publisher","DOI":"10.2113\/gsecongeo.92.4.389"},{"key":"e_1_3_2_50_1","doi-asserted-by":"publisher","DOI":"10.1130\/0091-7613(1999)027<0641:MGVAMD>2.3.CO;2"},{"key":"e_1_3_2_51_1","unstructured":"Ramsay J.G. & Huber M.I. 1987. The Techniques of Modern Structural Geology . Academic Press London 2 ."},{"key":"e_1_3_2_52_1","doi-asserted-by":"publisher","DOI":"10.1021\/ac60357a026"},{"key":"e_1_3_2_53_1","doi-asserted-by":"publisher","DOI":"10.2113\/gsecongeo.88.3.733"},{"key":"e_1_3_2_54_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0037-0738(99)00133-5"},{"key":"e_1_3_2_55_1","doi-asserted-by":"publisher","DOI":"10.2113\/gsecongeo.66.3.466"},{"key":"e_1_3_2_56_1","first-page":"1","volume":"12","year":"1999","unstructured":"Tosdal, R.M., Wooden, J.L. & Bouse, R.M. 1999. Pb isotopes, ore deposits, and metallogenic terranes. Reviews in Economic Geology, 12, 1\u201328.","journal-title":"Reviews in Economic Geology"},{"key":"e_1_3_2_57_1","doi-asserted-by":"publisher","DOI":"10.1007\/s001260100194"},{"key":"e_1_3_2_58_1","doi-asserted-by":"crossref","unstructured":"Wagner T. Boyce A.J. et al. 2001b. Sulphide\u2013sulphosalt reactions and sphalerite remobilization in siderite\u2013Pb\u2013Zn\u2013Sb veins of the Siegerland district Germany: a laser microprobe sulphur isotope study. In: Piestrzynski A. (ed.) Mineral Deposits at the Beginning of the 21st Century. Proceedings of the Joint 6th Biennial SGA\u2013SEG meeting Krakow . Balkena Rotterdam 185\u2013188.","DOI":"10.1201\/9781003077503-46"},{"key":"e_1_3_2_59_1","doi-asserted-by":"publisher","DOI":"10.1007\/s001260050016"},{"key":"e_1_3_2_60_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0016-7037(02)00891-8"},{"key":"e_1_3_2_61_1","first-page":"48","volume":"55","year":"1977","unstructured":"Weber, K., 1977. Bau und tektonische Entwicklung des Ostsauerl\u00e4nder Hauptsattels und der varistischen Ramsbecker Blei\u2013Zinkerzlagerst\u00e4tte. Fortschritte der Mineralogie, 55, 48\u201363.","journal-title":"Fortschritte der Mineralogie"},{"key":"e_1_3_2_62_1","doi-asserted-by":"publisher","DOI":"10.2113\/gsecongeo.92.3.308"}],"container-title":["Journal of the Geological Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.lyellcollection.org\/doi\/pdf\/10.1144\/0016-764902-010","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,11,19]],"date-time":"2024-11-19T12:15:32Z","timestamp":1732018532000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.lyellcollection.org\/doi\/10.1144\/0016-764902-010"},"secondary":[{"URL":"https:\/\/geoscienceworld.org\/jgs\/article-lookup?doi=10.1144\/0016-764902-010","label":"geoscienceworld"}]},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2003,3]]},"references-count":62,"journal-issue":{"issue":"2","published-online":{"date-parts":[[2022,6,6]]},"published-print":{"date-parts":[[2003,3]]}},"alternative-id":["10.1144\/0016-764902-010"],"URL":"https:\/\/doi.org\/10.1144\/0016-764902-010","relation":{},"ISSN":["0016-7649","2041-479X"],"issn-type":[{"type":"print","value":"0016-7649"},{"type":"electronic","value":"2041-479X"}],"subject":[],"published":{"date-parts":[[2003,3]]},"assertion":[{"value":"2002-01-30","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2002-09-19","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2022-06-06","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}