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An Earth observation (EO)-based UV index can estimate area-level UV indexes without effort in open-sky environments but can not provide sufficient accuracy for shaded environments. In contrast, conventional methods for monitoring individual-level, i.e., personal, UV exposure, such as mobile and wearable UV sensors, face limitations in terms of measurement and usability, presenting challenges for practical long-term usage. To address these issues, we introduce A-UVI, a method that enhances the accuracy of the EO-based UV index by leveraging raw signals from global navigation satellite systems (GNSS). By integrating this EO-based UV index and an attenuation ratio estimated from raw GNSS signals, our method especially improves estimation accuracy in shady environments affected by obstructions. We evaluated our method on data collected by different GNSS receivers in different mobility scenarios encompassing a diverse range of contexts and observation areas over the course of three days. Our evaluation showed that A-UVI estimates the UV index with a precision exceeding existing methods by at least 44.25%, achieving 5.53 times higher estimation accuracy in forest environments. We also confirmed that A-UVI is compatible with GNSS receivers in consumer-grade smartphones and has an average accuracy that is 23% better than the baseline EO-based method. Our findings demonstrate that utilizing raw GNSS signals enables accurate estimation of the UV index in various conditions, including in shaded areas, without the need for particular measurement actions or devices. 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