{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,1]],"date-time":"2026-09-01T12:52:47Z","timestamp":1788267167159,"version":"build-2803163510"},"reference-count":23,"publisher":"The Electrochemical Society","issue":"1","license":[{"start":{"date-parts":[[2001,1,1]],"date-time":"2001-01-01T00:00:00Z","timestamp":978307200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/iopscience.iop.org\/page\/copyright"},{"start":{"date-parts":[[2001,1,1]],"date-time":"2001-01-01T00:00:00Z","timestamp":978307200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/iopscience.iop.org\/info\/page\/text-and-data-mining"}],"content-domain":{"domain":["iopscience.iop.org"],"crossmark-restriction":false},"short-container-title":["J. Electrochem. Soc."],"published-print":{"date-parts":[[2001,1,1]]},"abstract":"<jats:p>Potential-pH equilibria and potentiodynamic polarization studies were used to examine the electrochemical behavior of copper in aqueous glycine solutions. Potential-pH diagrams for the copper-water-glycine system were derived at different total copper <jats:inline-formula>\n                     <mml:math xmlns:mml=\"http:\/\/www.w3.org\/1998\/Math\/MathML\" display=\"inline\" id=\"ML1\" overflow=\"scroll\">\n                        <mml:mo stretchy=\"false\">{<\/mml:mo>\n                        <mml:msub>\n                           <mml:mi mathvariant=\"normal\">Cu<\/mml:mi>\n                           <mml:mrow>\n                              <mml:mo>T<\/mml:mo>\n                           <\/mml:mrow>\n                        <\/mml:msub>\n                        <mml:mo stretchy=\"false\">}<\/mml:mo>\n                     <\/mml:math>\n                     <jats:inline-graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"jes_148_1_B51ieqn1.jpg\" xlink:type=\"simple\"\/>\n                  <\/jats:inline-formula> and glycine <jats:inline-formula>\n                     <mml:math xmlns:mml=\"http:\/\/www.w3.org\/1998\/Math\/MathML\" display=\"inline\" id=\"ML2\" overflow=\"scroll\">\n                        <mml:mo stretchy=\"false\">{<\/mml:mo>\n                        <mml:msub>\n                           <mml:mo>L<\/mml:mo>\n                           <mml:mrow>\n                              <mml:mo>T<\/mml:mo>\n                           <\/mml:mrow>\n                        <\/mml:msub>\n                        <mml:mo stretchy=\"false\">}<\/mml:mo>\n                     <\/mml:math>\n                     <jats:inline-graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"jes_148_1_B51ieqn2.jpg\" xlink:type=\"simple\"\/>\n                  <\/jats:inline-formula> activities. The diagrams show that glycine significantly extended the solubility range of copper. Polarization experiments were conducted in deaerated and aerated aqueous solutions of <jats:inline-formula>\n                     <mml:math xmlns:mml=\"http:\/\/www.w3.org\/1998\/Math\/MathML\" display=\"inline\" id=\"ML3\" overflow=\"scroll\">\n                        <mml:msup>\n                           <mml:mrow>\n                              <mml:mn>10<\/mml:mn>\n                           <\/mml:mrow>\n                           <mml:mrow>\n                              <mml:mo>\u2212<\/mml:mo>\n                              <mml:mn>2<\/mml:mn>\n                           <\/mml:mrow>\n                        <\/mml:msup>\n                        <mml:mo>M<\/mml:mo>\n                     <\/mml:math>\n                     <jats:inline-graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"jes_148_1_B51ieqn3.jpg\" xlink:type=\"simple\"\/>\n                  <\/jats:inline-formula> glycine with <jats:inline-formula>\n                     <mml:math xmlns:mml=\"http:\/\/www.w3.org\/1998\/Math\/MathML\" display=\"inline\" id=\"ML4\" overflow=\"scroll\">\n                        <mml:msup>\n                           <mml:mrow>\n                              <mml:mn>10<\/mml:mn>\n                           <\/mml:mrow>\n                           <mml:mrow>\n                              <mml:mo>\u2212<\/mml:mo>\n                              <mml:mn>5<\/mml:mn>\n                           <\/mml:mrow>\n                        <\/mml:msup>\n                        <mml:mo>M<\/mml:mo>\n                     <\/mml:math>\n                     <jats:inline-graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"jes_148_1_B51ieqn4.jpg\" xlink:type=\"simple\"\/>\n                  <\/jats:inline-formula> cupric nitrate and <jats:inline-formula>\n                     <mml:math xmlns:mml=\"http:\/\/www.w3.org\/1998\/Math\/MathML\" display=\"inline\" id=\"ML5\" overflow=\"scroll\">\n                        <mml:msup>\n                           <mml:mrow>\n                              <mml:mn>10<\/mml:mn>\n                           <\/mml:mrow>\n                           <mml:mrow>\n                              <mml:mo>\u2212<\/mml:mo>\n                              <mml:mn>1<\/mml:mn>\n                           <\/mml:mrow>\n                        <\/mml:msup>\n                        <mml:mo>M<\/mml:mo>\n                     <\/mml:math>\n                     <jats:inline-graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"jes_148_1_B51ieqn5.jpg\" xlink:type=\"simple\"\/>\n                  <\/jats:inline-formula> glycine with <jats:inline-formula>\n                     <mml:math xmlns:mml=\"http:\/\/www.w3.org\/1998\/Math\/MathML\" display=\"inline\" id=\"ML6\" overflow=\"scroll\">\n                        <mml:msup>\n                           <mml:mrow>\n                              <mml:mn>10<\/mml:mn>\n                           <\/mml:mrow>\n                           <mml:mrow>\n                              <mml:mo>\u2212<\/mml:mo>\n                              <mml:mn>4<\/mml:mn>\n                           <\/mml:mrow>\n                        <\/mml:msup>\n                        <mml:mo>M<\/mml:mo>\n                     <\/mml:math>\n                     <jats:inline-graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"jes_148_1_B51ieqn6.jpg\" xlink:type=\"simple\"\/>\n                  <\/jats:inline-formula> cupric nitrate at pH values between 9 and 12. The results of these experiments are discussed in terms of the relevant potential-pH diagrams. Good correlations were observed. \u00a9 2000 The Electrochemical Society.   All rights reserved.<\/jats:p>","DOI":"10.1149\/1.1344532","type":"journal-article","created":{"date-parts":[[2002,7,26]],"date-time":"2002-07-26T14:23:28Z","timestamp":1027693408000},"page":"B51-B57","update-policy":"https:\/\/doi.org\/10.1088\/crossmark-policy","source":"Crossref","is-referenced-by-count":144,"title":["Electrochemistry of Copper in Aqueous Glycine Solutions"],"prefix":"10.1149","volume":"148","author":[{"given":"Serdar","family":"Aksu","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fiona M.","family":"Doyle","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"77","reference":[{"key":"bb51_1-1"},{"key":"bb51_1-2","doi-asserted-by":"crossref","first-page":"137","DOI":"10.1179\/bcj.1995.30.2.137","volume":"30","author":"Sequeira","year":"1995","journal-title":"Br. Corros. 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