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Soc."],"published-print":{"date-parts":[[2026,10,28]]},"abstract":"<jats:p>Lithium-manganese-rich cathodes offer exceptional theoretical capacities but suffer from manganese dissolution\/deposition, which limits performance. This work demonstrates that first-cycle electrochemical reduction can be modulated through electrolyte chemistry and applied C-rate. We show that solid-electrolyte interphase passivation quality is not an inherent guarantee of the reduction process, but rather a variable outcome of the specific electrochemical pathways triggered. While some reduction processes rapidly establish passivation, others consume substantially more electrolyte before the interface is effectively stabilized. 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