{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T19:52:31Z","timestamp":1740167551095,"version":"3.37.3"},"reference-count":0,"publisher":"The Electrochemical Society","issue":"2","license":[{"start":{"date-parts":[[2009,9,25]],"date-time":"2009-09-25T00:00:00Z","timestamp":1253836800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/iopscience.iop.org\/page\/copyright"},{"start":{"date-parts":[[2009,9,25]],"date-time":"2009-09-25T00:00:00Z","timestamp":1253836800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/iopscience.iop.org\/info\/page\/text-and-data-mining"}],"content-domain":{"domain":["iopscience.iop.org"],"crossmark-restriction":false},"short-container-title":["ECS Trans."],"published-print":{"date-parts":[[2009,9,25]]},"abstract":"<jats:p>Powder mixtures of 3%Y2O3 (3Y) and 8%Y2O3 (8Y) were used to obtain heterogeneous solid electrolytes with good sinterability and mostly fine grain sizes, without significantly undue effects on ionic conductivity. Samples with 8Y:3Y{less than or equal to}1:1 retain submicrometer grain sizes, with very rare grains above 1 {less than or equal to}m. Impedance spectroscopy was used to de-convolute the bulk and grain boundary contributions, and to analyze their dependence on the fraction of 3Y. Bulk conductivity and its activation energy vary gradually with increasing 8Y:3Y ratio. The lower grain boundary conductivity of homogeneous 3Y can be ascribed to a combination of finer grain sizes and also lower specific grain boundary conductivity. However, the grain boundary conductivity differences of heterogeneous samples obtained from 3Y+8Y mixtures can be mainly ascribed to differences in grain size. Specific grain boundary conductivity results of these heterogeneous solid electrolytes are similar to those obtained for homogeneous 8Y.<\/jats:p>","DOI":"10.1149\/1.3205698","type":"journal-article","created":{"date-parts":[[2009,9,28]],"date-time":"2009-09-28T21:01:23Z","timestamp":1254171683000},"page":"1617-1624","update-policy":"https:\/\/doi.org\/10.1088\/crossmark-policy","source":"Crossref","is-referenced-by-count":0,"title":["Heterogeneous Zirconia-based Solid Electrolytes Obtained by Sintering TZP+YSZ Powder Mixtures"],"prefix":"10.1149","volume":"25","author":[{"given":"Cristina","family":"Fernandes","sequence":"first","affiliation":[]},{"given":"Gabriel","family":"Cunto","sequence":"additional","affiliation":[]},{"given":"Filipe","family":"Figueiredo","sequence":"additional","affiliation":[]},{"given":"Jorge R.","family":"Frade","sequence":"additional","affiliation":[]}],"member":"77","container-title":["ECS Transactions"],"original-title":[],"link":[{"URL":"https:\/\/iopscience.iop.org\/article\/10.1149\/1.3205698\/pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/iopscience.iop.org\/article\/10.1149\/1.3205698","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/iopscience.iop.org\/article\/10.1149\/1.3205698","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/iopscience.iop.org\/article\/10.1149\/1.3205698\/pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/iopscience.iop.org\/article\/10.1149\/1.3205698\/pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/syndication.highwire.org\/content\/doi\/10.1149\/1.3205698","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"},{"URL":"https:\/\/iopscience.iop.org\/article\/10.1149\/1.3205698\/pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"similarity-checking"},{"URL":"https:\/\/iopscience.iop.org\/article\/10.1149\/1.3205698","content-type":"text\/html","content-version":"vor","intended-application":"similarity-checking"},{"URL":"https:\/\/iopscience.iop.org\/article\/10.1149\/1.3205698\/pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2022,2,6]],"date-time":"2022-02-06T00:01:57Z","timestamp":1644105717000},"score":1,"resource":{"primary":{"URL":"https:\/\/iopscience.iop.org\/article\/10.1149\/1.3205698"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2009,9,25]]},"references-count":0,"journal-issue":{"issue":"2","published-print":{"date-parts":[[2009,9,25]]}},"URL":"https:\/\/doi.org\/10.1149\/1.3205698","relation":{},"ISSN":["1938-5862","1938-6737"],"issn-type":[{"type":"print","value":"1938-5862"},{"type":"electronic","value":"1938-6737"}],"subject":[],"published":{"date-parts":[[2009,9,25]]},"assertion":[{"value":"Heterogeneous Zirconia-based Solid Electrolytes Obtained by Sintering TZP+YSZ Powder Mixtures","name":"article_title","label":"Article Title"},{"value":"ECS Transactions","name":"journal_title","label":"Journal Title"},{"value":"paper","name":"article_type","label":"Article Type"},{"value":"\u00a9 2009 ECS - The Electrochemical Society","name":"copyright_information","label":"Copyright Information"},{"name":"date_received","label":"Date Received","group":{"name":"publication_dates","label":"Publication dates"}},{"name":"date_accepted","label":"Date Accepted","group":{"name":"publication_dates","label":"Publication dates"}},{"name":"date_epub","label":"Online publication date","group":{"name":"publication_dates","label":"Publication dates"}}]}}