{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,18]],"date-time":"2026-08-18T01:49:28Z","timestamp":1787017768395,"version":"build-2736575974"},"reference-count":42,"publisher":"Wiley","issue":"1","license":[{"start":{"date-parts":[[2010,10,10]],"date-time":"2010-10-10T00:00:00Z","timestamp":1286668800000},"content-version":"vor","delay-in-days":282,"URL":"http:\/\/creativecommons.org\/licenses\/by\/3.0\/"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Bioinorganic Chemistry and Applications"],"published-print":{"date-parts":[[2010,1]]},"abstract":"<jats:p>\n                    The reaction of\n                    <jats:italic>N<\/jats:italic>\n                    ,\n                    <jats:italic>N<\/jats:italic>\n                    \u2010bis(2\u2010hydroxyethyl)glycine (bicine; bicH\n                    <jats:sub>3<\/jats:sub>\n                    ) with  in MeOH yielded the polymeric compound . The complex crystallizes in the tetragonal space group\n                    <jats:italic>P<\/jats:italic>\n                    4\n                    <jats:sub>1<\/jats:sub>\n                    2\n                    <jats:sub>1<\/jats:sub>\n                    2. The lattice constants are\n                    <jats:italic>a<\/jats:italic>\n                    =\n                    <jats:italic>b<\/jats:italic>\n                    = 12.737(5) and c = 18.288(7)\u2009\u00c5. The compound contains chains of repeating  units. One Cd\n                    <jats:sup>II<\/jats:sup>\n                    atom is coordinated by two carboxylate oxygen, four hydroxyl oxygen, and two nitrogen atoms from two symmetry\u2010related 2.21111 (Harris notation)  ligands. The other Cd\n                    <jats:sup>II<\/jats:sup>\n                    atom is coordinated by six carboxylate oxygen atoms, four from two  ligands and two from the monodentate benzoate groups. Each bicinate(\u20101) ligand chelates the 8\u2010coordinate, square antiprismatic Cd\n                    <jats:sup>II<\/jats:sup>\n                    atom through one carboxylate oxygen, the nitrogen, and both hydroxyl oxygen atoms and bridges the second, six\u2010coordinate trigonal prismatic Cd\n                    <jats:sup>II<\/jats:sup>\n                    center through its carboxylate oxygen atoms. Compound\n                    <jats:bold>1<\/jats:bold>\n                    is the first structurally characterized cadmium(II) complex containing any anionic form of bicine as ligand. IR data of\n                    <jats:bold>1<\/jats:bold>\n                    are discussed in terms of the coordination modes of the ligands and the known structure.\n                  <\/jats:p>","DOI":"10.1155\/2010\/281932","type":"journal-article","created":{"date-parts":[[2010,10,10]],"date-time":"2010-10-10T15:31:31Z","timestamp":1286724691000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Synthesis, X\u2010Ray Structure, and Characterization of\n                    <i>Catena<\/i>\n                    \u2010bis(benzoate)bis{\n                    <i>N<\/i>\n                    ,\n                    <i>N<\/i>\n                    \u2010bis(2\u2010hydroxyethyl)glycinate}cadmium(II)"],"prefix":"10.1155","volume":"2010","author":[{"given":"Eugenia","family":"Katsoulakou","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Konstantis F.","family":"Konidaris","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Catherine P.","family":"Raptopoulou","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vassilis","family":"Psyharis","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Evy","family":"Manessi-Zoupa","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Spyros P.","family":"Perlepes","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2010,10,10]]},"reference":[{"key":"e_1_2_5_1_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00282a010"},{"key":"e_1_2_5_2_2","volume-title":"Metal Pollution in the Aquatic Environment","author":"F\u00f6rstner U.","year":"1983"},{"key":"e_1_2_5_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/0010-8545(84)85053-5"},{"key":"e_1_2_5_4_2","volume-title":"Cadmium and Health: A Toxicological and Epidemiological Appraisal","author":"Friberg L.","year":"1985"},{"key":"e_1_2_5_5_2","doi-asserted-by":"publisher","DOI":"10.1007\/978-3-0348-6493-0"},{"key":"e_1_2_5_6_2","volume-title":"Clinical Toxicology of Commercial Products","author":"Gosselin R. 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