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The coordination of the sulfur donor atom led to interest in them as precursor for semiconductor nanoparticles. In this study, cadmium(II) complex of diethylthiourea was synthesized and characterized by elemental analysis, FTIR, and X\u2010ray crystallography. Single crystal X\u2010ray structure of the complex showed that the octahedral geometry around the Cd ion consists of two molecules of diethylthiourea acting as monodentate ligands and two chelating acetate ions. The thermal decomposition of the compound showed that it decomposed to give CdS. The compound was thermolysed in hexadecylamine (HDA) to prepare HDA\u2010capped CdS nanoparticles. The absorption spectrum showed blue shifts in its absorption band edges which clearly indicated quantum confinement effect, and the emission spectrum showed characteristic band edge luminescence. The broad diffraction peaks of the XRD pattern showed the materials to be of the nanometric size.<\/jats:p>","DOI":"10.1155\/2013\/907562","type":"journal-article","created":{"date-parts":[[2013,11,1]],"date-time":"2013-11-01T03:10:57Z","timestamp":1383275457000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Synthesis and Use of [Cd(Detu)<sub>2<\/sub>(OOCCH<sub>3<\/sub>)<sub>2<\/sub>]\u00b7H<sub>2<\/sub>O as Single Molecule Precursor for Cds Nanoparticles"],"prefix":"10.1155","volume":"2013","author":[{"given":"Peter A.","family":"Ajibade","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2013,10,31]]},"reference":[{"key":"e_1_2_7_1_2","doi-asserted-by":"publisher","DOI":"10.1080\/00958970902926795"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0162-0134(01)00408-1"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1080\/00958972.2010.510558"},{"key":"e_1_2_7_4_2","first-page":"238","article-title":"Synthesis and antibacterial activity of pyridyl thioureas and arylthiosemicarbazones","volume":"140","author":"Kumar K. 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