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However, due to the nonlinear fluctuations brought about by extreme events, investors face more difficulties in the choice of risk portfolio. We adopt empirical mode decomposition and STVAR model, along with the basis data of optimized original sample interval. In addition, we retain the mature research of multiscale systemic risk under frequency and divide the dimension of systemic risk into two states. When frequency is combined with states, the risk spillover center undergoes subversive changes, particularly in the longest term, and metals become the risk spillover center, substituting the energy commodity, on the condition that the compositions of extreme value add persuasive power to the perspective of long term. We proposed that the joint fluctuation of agricultural commodities and energy commodities makes the former become another important risk spillover point. 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