{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,4]],"date-time":"2025-10-04T08:11:25Z","timestamp":1759565485676,"version":"3.37.3"},"reference-count":27,"publisher":"Wiley","license":[{"start":{"date-parts":[[2021,4,16]],"date-time":"2021-04-16T00:00:00Z","timestamp":1618531200000},"content-version":"unspecified","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100006261","name":"Taif University","doi-asserted-by":"publisher","award":["TURSP-2020\/39"],"award-info":[{"award-number":["TURSP-2020\/39"]}],"id":[{"id":"10.13039\/501100006261","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Bioinorganic Chemistry and Applications"],"published-print":{"date-parts":[[2021,4,16]]},"abstract":"<jats:p>The solid adducts of SnCl2.(3amt).H2O, SnCl2.2(3amt).H2O, CdCl2.(3amt), CdCl2.2(3amt), SnCl2.(2mct).0.5H2O, SnCl2.2(2mct), CdCl2.(2mct), CdCl2.2(2mct).H2O, SnCl2.(2mcp).1.5H2O, &gt;2.2(2mcp).4H2O, CdCl2.(2mcp), CdCl2.2(2mcp), SnCl2.(4amt).4H2O, SnCl2.2(4amt).1.5H2O, CdCl2.(4amt).H2O, and CdCl2.2(4amt) (where the 3amt, 4amt, 2mct, and 2mcp represent 3-amino-1,2,4-triazole, 4-amino-1,2,4-triazole, 2-mercaptothiazoline, and 2-mercaptopyridine simple organic chelates, respectively) were prepared using a solid-state route and investigated by CHN elemental analysis and infrared spectroscopy. Additionally, we investigated the thermogravimetric characterization and antimicrobial proprieties. It is verified that for 3amt and 4amt adducts, the coordination occurs through nitrogen atom. For 2mct compounds, the coordination occurs through nitrogen (Sn) or sulfur (Cd). For 2mcp adducts, both coordination sites nitrogen and sulfur are involved. By examination of TG curves, it is confirmed that for each hydrated compounds, the first mass loss step is linked with the release of water molecules followed by the release of ligand molecules and sublimation of the metal chloride. Furthermore, it is verified that, considering only the release of ligand molecules (3amp, 4amp, 2mct, or 2mcp), the cadmium adducts are always more stable than the correspondent tin adducts probably due to the formation of cross-linking bonds in these compounds. Finally, of these 16 adducts, 14 showed antimicrobial activities against different bacterial and fungal strains.<\/jats:p>","DOI":"10.1155\/2021\/6638229","type":"journal-article","created":{"date-parts":[[2021,4,16]],"date-time":"2021-04-16T21:06:55Z","timestamp":1618607215000},"page":"1-10","source":"Crossref","is-referenced-by-count":3,"title":["Preparation and Thermogravimetric and Antimicrobial Investigation of Cd (II) and Sn (II) Adducts of Mercaptopyridine, Amino Triazole Derivatives, and Mercaptothiazoline Organic Ligand Moieties"],"prefix":"10.1155","volume":"2021","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-8297-935X","authenticated-orcid":true,"given":"Ahmed","family":"Gaber","sequence":"first","affiliation":[{"name":"Department of Biology, College of Science, Taif University, P.O. Box 11099, Taif 21944, Saudi Arabia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1291-0111","authenticated-orcid":true,"given":"Walaa F.","family":"Alsanie","sequence":"additional","affiliation":[{"name":"Department of Clinical Laboratories Sciences, The Faculty of Applied Medical Sciences, Taif University, P.O. Box 11099, Taif 21944, Saudi Arabia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3132-7754","authenticated-orcid":true,"given":"Robson F.","family":"de Farias","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica, Universidade Federal de Roraima, Cx. Postal 167, Boa Vista 69301-970, Roraima, Brazil"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5602-5096","authenticated-orcid":true,"given":"Moamen S.","family":"Refat","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Faculty of Science, Taif University, P.O. Box 11099, Taif 21944, Saudi Arabia"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","reference":[{"key":"1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ejmech.2010.10.007"},{"key":"2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ejmech.2008.12.005"},{"key":"3","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemphyslip.2020.104894"},{"key":"4","doi-asserted-by":"publisher","DOI":"10.1016\/j.dnarep.2019.102765"},{"key":"5","doi-asserted-by":"publisher","DOI":"10.1016\/j.ejmech.2020.112686"},{"key":"6","doi-asserted-by":"publisher","DOI":"10.1016\/j.ejmech.2019.04.043"},{"key":"7","doi-asserted-by":"publisher","DOI":"10.1016\/j.ejmech.2009.09.024"},{"key":"8","doi-asserted-by":"publisher","DOI":"10.1016\/j.ejmech.2007.04.010"},{"key":"9","doi-asserted-by":"publisher","DOI":"10.1016\/s0960-894x(01)00283-9"},{"key":"10","doi-asserted-by":"publisher","DOI":"10.1248\/cpb.58.160"},{"key":"11","doi-asserted-by":"publisher","DOI":"10.1016\/j.ejmech.2010.08.034"},{"key":"12","doi-asserted-by":"publisher","DOI":"10.1016\/j.bioorg.2020.104133"},{"key":"13","doi-asserted-by":"publisher","DOI":"10.1016\/j.ejmech.2008.01.039"},{"key":"14","doi-asserted-by":"publisher","DOI":"10.1007\/s00044-011-9691-4"},{"key":"15","doi-asserted-by":"publisher","DOI":"10.1007\/s00044-010-9308-3"},{"key":"16","doi-asserted-by":"publisher","DOI":"10.1023\/b:jtan.0000011024.89077.43"},{"key":"17","doi-asserted-by":"publisher","DOI":"10.1016\/s0040-6031(03)00229-6"},{"key":"18","doi-asserted-by":"crossref","first-page":"748","DOI":"10.1023\/A:1020330703486","article-title":"Synthesis, characterization and a thermogravimetric study of copper, cobalt and tin mono- and bis-adducts with ethyleneurea, ethylenethiourea and propyleneurea","volume":"27","author":"R. F. de Farias","year":"2002","journal-title":"Transition Metal Chemistry"},{"key":"19","doi-asserted-by":"publisher","DOI":"10.1016\/s0040-6031(02)00181-8"},{"key":"20","doi-asserted-by":"publisher","DOI":"10.1016\/s0277-5387(02)00982-8"},{"key":"21","doi-asserted-by":"publisher","DOI":"10.3390\/molecules25225447"},{"key":"22","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpcs.2004.04.008"},{"key":"23","doi-asserted-by":"crossref","first-page":"21","DOI":"10.1023\/A:1022558107121","article-title":"Nickel(II) and cerium(IV) ethyleneurea, ethylenethiourea and propyleneurea adducts","volume":"28","author":"R. F. de Farias","year":"2003","journal-title":"Transition Metal Chemistry"},{"key":"24","doi-asserted-by":"publisher","DOI":"10.1006\/jssc.2002.9576"},{"key":"25","doi-asserted-by":"publisher","DOI":"10.1016\/s0040-6031(02)00079-5"},{"key":"26","doi-asserted-by":"publisher","DOI":"10.1016\/s0040-6031(01)00529-9"},{"volume-title":"Chemistry of the Elements","year":"1984","author":"N. 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