{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,13]],"date-time":"2026-01-13T04:26:49Z","timestamp":1768278409723,"version":"3.49.0"},"reference-count":17,"publisher":"Wiley","license":[{"start":{"date-parts":[[2023,10,9]],"date-time":"2023-10-09T00:00:00Z","timestamp":1696809600000},"content-version":"unspecified","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Qingdao Huanghai University"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Journal of Analytical Methods in Chemistry"],"published-print":{"date-parts":[[2023,10,9]]},"abstract":"<jats:p>Simultaneous enantioseparation of three commonly used chiral antifungal pesticides (diniconazole, hexaconazole, and imazalil) was first studied based on micellar electrokinetic chromatography (MEKC) with hydroxypropyl-\u03b3-CD (HP-\u03b3-CD) as chiral selector. In this study, the importance of experimental parameters such as chiral selector type and concentration, sodium dodecyl sulfate (SDS) concentration, the ratio of methanol, and separation voltage in optimizing were investigated. The simultaneous enantioseparation of diniconazole, hexaconazole, and imazalil was successfully achieved in 30\u2009mM borate buffer (pH 9.0) containing 10\u2009mM HP-\u03b3-CD and 20\u2009mM SDS with methanol (8%) added as organic modifiers. The resolution of diniconazole, hexaconazole, and imazalil was 15.2, 2.12, and 2.78, respectively, and the peak efficiency (N) was over 566,825 plates\/m. This study provides an alternative way to systematically separate chiral antifungal pesticides with high efficiency.<\/jats:p>","DOI":"10.1155\/2023\/9993526","type":"journal-article","created":{"date-parts":[[2023,10,9]],"date-time":"2023-10-09T20:35:07Z","timestamp":1696883707000},"page":"1-6","source":"Crossref","is-referenced-by-count":2,"title":["Simultaneous Enantioseparation of Three Chiral Antifungal Pesticides by Hydroxypropyl-\u03b3-CD-Modified Micellar Electrokinetic Chromatography"],"prefix":"10.1155","volume":"2023","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-9641-1768","authenticated-orcid":true,"given":"Xiaoyu","family":"Yang","sequence":"first","affiliation":[{"name":"Qingdao Huanghai University, Qingdao 266427, China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","reference":[{"issue":"12","key":"1","article-title":"Green aspects during synthesis, application and chromatographic analysis of chiral pesticides","volume":"27","author":"H. 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