{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,26]],"date-time":"2026-03-26T19:49:49Z","timestamp":1774554589445,"version":"3.50.1"},"reference-count":30,"publisher":"Wiley","issue":"1","license":[{"start":{"date-parts":[[2006,12,13]],"date-time":"2006-12-13T00:00:00Z","timestamp":1165968000000},"content-version":"vor","delay-in-days":346,"URL":"http:\/\/creativecommons.org\/licenses\/by\/3.0\/"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Bioinorganic Chemistry and Applications"],"published-print":{"date-parts":[[2006,1]]},"abstract":"<jats:p>We review the results of our work on the iodine interaction with\nthioamides, selenoamides, and amides. Complexes with (i) \u201cspoke\u201d or \u201cextended\nspoke\u201d structures, D \u00b7 I<jats:sub>2<\/jats:sub> and D \u00b7 I<jats:sub>2<\/jats:sub> \u00b7 I<jats:sub>2<\/jats:sub>, respectively, (D is the ligand donor) (ii) iodonium salts of\n\n (<jats:italic>n<\/jats:italic> = 3, 7) and  formulae and (iii) disulfides of the categories\n(a) [D \u2212 D], (b)  have been isolated and\ncharacterized. A compound of formula  containing both types of complexes\n(i) and (ii) was also isolated.\nThe interaction of diiodine with selenium analogs of the antithyroid drug 6\u2010<jats:italic>n<\/jats:italic>\u2010propyl\u20102\u2010thiouracil (PTU), of formulae RSeU (6\u2010alkyl\u20102\u2010Selenouracil) results in the formation of complexes with \nformulae [(RSeU)I<jats:sub>2<\/jats:sub>]. All these results are correlated with the mechanism of\naction of antithyroid drugs. Finally, we review here our work on the diiodine interaction\nwith the amides (LO).<\/jats:p>","DOI":"10.1155\/bca\/2006\/60291","type":"journal-article","created":{"date-parts":[[2006,12,27]],"date-time":"2006-12-27T07:57:03Z","timestamp":1167206223000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":16,"title":["Interaction of Thioamides, Selenoamides, and Amides with Diiodine"],"prefix":"10.1155","volume":"2006","author":[{"given":"Sotiris K.","family":"Hadjikakou","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2037-9172","authenticated-orcid":false,"given":"Nick","family":"Hadjiliadis","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2006,12,13]]},"reference":[{"key":"e_1_2_1_1_2","doi-asserted-by":"crossref","unstructured":"DagaV HadjikakouS K HadjiliadisN KubickiM dos SantosJ HZ andButlerI S Synthesis spectroscopic and structural characterization of novel diiodine adducts with the heterocyclic thioamides thiazolidine-2-thione (tzdtH) benzothiazole-2-thione (bztzdtH) and benzimidazole-2-thione (bzimtH) 2002 2002 no. 7 1718\u20131728 https:\/\/doi.org\/10.1002\/1099-0682(200207)2002:7<1718::AID-EJIC1718>3.0.CO;2-S.","DOI":"10.1002\/1099-0682(200207)2002:7<1718::AID-EJIC1718>3.0.CO;2-S"},{"key":"e_1_2_1_2_2","doi-asserted-by":"crossref","unstructured":"dos SantosJ HZ ButlerI S DagaV HadjikakouS K andHadjiliadisN High-pressure Fourier transform micro-Raman spectroscopic investigation of diiodine-heterocyclic thioamide adducts 2002 58 no. 12 2725\u20132735 https:\/\/doi.org\/10.1016\/S1386-1425(02)00028-8.","DOI":"10.1016\/S1386-1425(02)00028-8"},{"key":"e_1_2_1_3_2","doi-asserted-by":"crossref","unstructured":"AntoniadisC D CorbanG HadjikakouS Ket al. 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