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Several photophysical studies were carried out to access the influence of the unsymmetrical substitution at the porphyrinic macrocycle on porthyrin\u2032s photophysical properties, especially porthyrin\u2032s efficiency as singlet oxygen sensitizers. The quantum yields of singlet oxygen generation were determined in benzene (<jats:italic>\u03a6<\/jats:italic><jats:sub><jats:italic>\u0394<\/jats:italic><\/jats:sub>(TPP) = 0.66\u2009\u00b1\u20090.05; <jats:italic>\u03a6<\/jats:italic><jats:sub><jats:italic>\u0394<\/jats:italic><\/jats:sub>(TPPOH<jats:sub>O<\/jats:sub>) = 0.69\u2009\u00b1\u20090.04; <jats:italic>\u03a6<\/jats:italic><jats:sub><jats:italic>\u0394<\/jats:italic><\/jats:sub>(TPPOH<jats:sub>M<\/jats:sub>) = 0.62\u2009\u00b1\u20090.04; <jats:italic>\u03a6<\/jats:italic><jats:sub><jats:italic>\u0394<\/jats:italic><\/jats:sub>(TPPOH<jats:sub>P<\/jats:sub>) = 0.73\u2009\u00b1\u20090.03; <jats:italic>\u03a6<\/jats:italic><jats:sub><jats:italic>\u0394<\/jats:italic><\/jats:sub>(TBP) = 0.76\u2009\u00b1\u20090.03; <jats:italic>\u03a6<\/jats:italic><jats:sub><jats:italic>\u0394<\/jats:italic><\/jats:sub>(TBPOH<jats:sub>O<\/jats:sub>) = 0.73\u2009\u00b1\u20090.02) using the 5,10,15,20\u2010tetraphenyl\u201021,23\u2010H\u2010porphine (<jats:italic>\u03a6<\/jats:italic><jats:sub><jats:italic>\u0394<\/jats:italic><\/jats:sub>(TPP) = 0.66) and Phenazine (<jats:italic>\u03a6<\/jats:italic><jats:sub><jats:italic>\u0394<\/jats:italic><\/jats:sub>(Phz) = 0.83) as reference compounds. Their fluorescence quantum yields were found to be (<jats:italic>\u03a6<\/jats:italic><jats:sub>f<\/jats:sub>(TPPOH<jats:sub>O<\/jats:sub>) = 0.10\u2009\u00b1\u20090.04; <jats:italic>\u03a6<\/jats:italic><jats:sub>f<\/jats:sub>(TPPOH<jats:sub>M<\/jats:sub>) = 0.09\u2009\u00b1\u20090.03; <jats:italic>\u03a6<\/jats:italic><jats:sub>f<\/jats:sub>(TPPOH<jats:sub>P<\/jats:sub>) = 0.13\u2009\u00b1\u20090.02; <jats:italic>\u03a6<\/jats:italic><jats:sub>f<\/jats:sub>(TBP) = 0.08\u2009\u00b1\u20090.03 and <jats:italic>\u03a6<\/jats:italic><jats:sub>f<\/jats:sub>(TBPOH<jats:sub>O<\/jats:sub>) = 0.08\u2009\u00b1\u20090.02 using 5,10,15,20\u2010tetraphenyl\u201021,23\u2010H\u2010porphine as reference <jats:italic>\u03a6<\/jats:italic><jats:sub>f<\/jats:sub>(TPP) = 0.13). Singlet state lifetimes were also determined in the same solvent. All the porphyrins presented very similar fluorescence lifetimes  (mean values of <jats:italic>\u03c4<\/jats:italic><jats:sub>S<\/jats:sub> (with O<jats:sub>2<\/jats:sub>, air equilibrated) = 9.6\u2009\u00b1\u20090.3 nanoseconds and (without O<jats:sub>2<\/jats:sub>, argon purged) = 10.1\u2009\u00b1\u20090.6 nanoseconds, resp.). The phosphorescence emission was found to be negligible for this series of unsymmetrically substituted mesoporphyrins, but an E\u2010type, thermally activated, delayed fluorescence process was proved to occur at room temperature.<\/jats:p>","DOI":"10.1155\/2009\/413915","type":"journal-article","created":{"date-parts":[[2009,6,8]],"date-time":"2009-06-08T13:36:19Z","timestamp":1244468179000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":19,"title":["A Singlet Oxygen Photogeneration and Luminescence Study of Unsymmetrically Substituted Mesoporphyrinic Compounds"],"prefix":"10.1155","volume":"2009","author":[{"given":"Anabela Sousa","family":"Oliveira","sequence":"first","affiliation":[]},{"given":"Dumitru","family":"Licsandru","sequence":"additional","affiliation":[]},{"given":"Rica","family":"Boscencu","sequence":"additional","affiliation":[]},{"given":"Radu","family":"Socoteanu","sequence":"additional","affiliation":[]},{"given":"Veronica","family":"Nacea","sequence":"additional","affiliation":[]},{"given":"Luis Filipe","family":"Vieira Ferreira","sequence":"additional","affiliation":[]}],"member":"311","published-online":{"date-parts":[[2009,6,8]]},"reference":[{"key":"e_1_2_6_1_2","volume-title":"The Porphyrin Handbook","author":"Kadish K. 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