{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2022,4,3]],"date-time":"2022-04-03T14:39:24Z","timestamp":1648996764641},"reference-count":0,"publisher":"American Scientific Publishers","issue":"7","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["j nanosci nanotechnol"],"published-print":{"date-parts":[[2021,7,1]]},"abstract":"<jats:p>The complete oxidation of toluene (as a model volatile organic compound) was studied to determine the influence of adding a transition metal (Mn, Cr, Fe, Co, and Ni) to the 5 Cu\/Al catalyst. The physcochemical properties of the catalysts were characterized by Brunauer\u2013Emmett\u2013Teller\n (BET) surface area analysis, X-ray diffraction (XRD) analysis, field emission transmission electron microscopy (FE\/TEM), and hydrogen temperature programmed reduction (H<jats:sub>2<\/jats:sub>-TPR). The catalytic activity of the supported bimetallic catalysts followed the order: 5Cu-5Mn\/Al &gt; 5Cu-5Cr\/Al\n &gt; 5Cu-5Fe\/Al &gt; 5Cu-5Co\/Al &gt; 5Cu &gt; 5Cu-5Ni\/Al, based on the temperature for <jats:italic>T<\/jats:italic><jats:sub>90<\/jats:sub> of toluene conversion (T<jats:sub>90<\/jats:sub>). Two different reaction mechanisms (mixing and the synergistic effect) were operative in the supported bimetallic catalysts except for the 5Cu\u20135Mn\/Al\n and 5Cu\u20135Ni\/Al catalysts, on the basis of the reaction temperature. The difference between the electronegativity of copper and the added transition metal was associated with the catalytic activity.<\/jats:p>","DOI":"10.1166\/jnn.2021.19177","type":"journal-article","created":{"date-parts":[[2021,3,15]],"date-time":"2021-03-15T04:31:27Z","timestamp":1615782687000},"page":"4060-4066","source":"Crossref","is-referenced-by-count":0,"title":["Catalytic Performance of Supported Bimetallic Catalysts for Complete Oxidation of Toluene"],"prefix":"10.1166","volume":"21","author":[{"given":"Sang-Chul","family":"Jung","sequence":"first","affiliation":[{"name":"Department of Environmental Engineering, Sunchon National University, Suncheon 57922, Republic of Korea"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Young-Kwon","family":"Park","sequence":"additional","affiliation":[{"name":"School of Environmental Engineering, University of Seoul, Seoul 02504, Republic of Korea"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ho-Young","family":"Jung","sequence":"additional","affiliation":[{"name":"Department of Environment and Energy Engineering, Chonnam National University, Gwangju 61186, Republic of Korea"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sang Chai","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Environmental Education, Mokpo National University, Muan 58554, Republic of Korea"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"17","container-title":["Journal of Nanoscience and Nanotechnology"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.ingentaconnect.com\/content\/asp\/jnn\/2021\/00000021\/00000007\/art00078","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2021,7,9]],"date-time":"2021-07-09T04:41:47Z","timestamp":1625805707000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.ingentaconnect.com\/content\/10.1166\/jnn.2021.19177"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,7,1]]},"references-count":0,"journal-issue":{"issue":"7","published-print":{"date-parts":[[2021,7,1]]}},"alternative-id":["1533-4880(20210701)21:7L.4060;1-"],"URL":"https:\/\/doi.org\/10.1166\/jnn.2021.19177","relation":{},"ISSN":["1533-4880"],"issn-type":[{"value":"1533-4880","type":"print"}],"subject":[],"published":{"date-parts":[[2021,7,1]]}}}