{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,30]],"date-time":"2026-04-30T21:38:12Z","timestamp":1777585092603,"version":"3.51.4"},"reference-count":43,"publisher":"SAGE Publications","issue":"1","license":[{"start":{"date-parts":[[2020,2,18]],"date-time":"2020-02-18T00:00:00Z","timestamp":1581984000000},"content-version":"vor","delay-in-days":382,"URL":"http:\/\/www.sagepub.com\/licence-information-for-chorus"}],"funder":[{"name":"Robert Dean Loughney Faculty Development Fund"},{"DOI":"10.13039\/100000001","name":"National Science Foundation","doi-asserted-by":"publisher","award":["CHE-0963450"],"award-info":[{"award-number":["CHE-0963450"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Netherlands Organization for Scientific Research","award":["vici-grant 724.011.002"],"award-info":[{"award-number":["vici-grant 724.011.002"]}]},{"name":"U.S. Department of Energy, Office of Basic Energy Sciences, Heavy Elements Chemistry","award":["DE-AC02-05CH11231"],"award-info":[{"award-number":["DE-AC02-05CH11231"]}]}],"content-domain":{"domain":["journals.sagepub.com"],"crossmark-restriction":true},"short-container-title":["Eur J Mass Spectrom (Chichester)"],"published-print":{"date-parts":[[2019,2]]},"abstract":"<jats:p>\n                    Electrospray ionization was used to generate species such as [ZnNO\n                    <jats:sub>3<\/jats:sub>\n                    (CH\n                    <jats:sub>3<\/jats:sub>\n                    OH)\n                    <jats:sub>2<\/jats:sub>\n                    ]\n                    <jats:sup>+<\/jats:sup>\n                    from Zn(NO\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    \u2022XH\n                    <jats:sub>2<\/jats:sub>\n                    O dissolved in a mixture of CH\n                    <jats:sub>3<\/jats:sub>\n                    OH and H\n                    <jats:sub>2<\/jats:sub>\n                    O. Collision-induced dissociation of [ZnNO\n                    <jats:sub>3<\/jats:sub>\n                    (CH\n                    <jats:sub>3<\/jats:sub>\n                    OH)\n                    <jats:sub>2<\/jats:sub>\n                    ]\n                    <jats:sup>+<\/jats:sup>\n                    causes elimination of CH\n                    <jats:sub>3<\/jats:sub>\n                    OH to form [ZnNO\n                    <jats:sub>3<\/jats:sub>\n                    (CH\n                    <jats:sub>3<\/jats:sub>\n                    OH)]\n                    <jats:sup>+<\/jats:sup>\n                    . Subsequent collision-induced dissociation of [ZnNO\n                    <jats:sub>3<\/jats:sub>\n                    (CH\n                    <jats:sub>3<\/jats:sub>\n                    OH)]\n                    <jats:sup>+<\/jats:sup>\n                    causes elimination of 47 mass units (u), consistent with ejection of HNO\n                    <jats:sub>2<\/jats:sub>\n                    . The neutral loss shifts to 48\u2009u for collision-induced dissociation of [ZnNO\n                    <jats:sub>3<\/jats:sub>\n                    (CD\n                    <jats:sub>3<\/jats:sub>\n                    OH)]\n                    <jats:sup>+<\/jats:sup>\n                    , demonstrating the ejection of HNO\n                    <jats:sub>2<\/jats:sub>\n                    involves intra-complex transfer of H from the methyl group methanol ligand. Subsequent collision-induced dissociation causes the elimination of 30\u2009u (32\u2009u for the complex with CD\n                    <jats:sub>3<\/jats:sub>\n                    OH), suggesting the elimination of formaldehyde (CH\n                    <jats:sub>2<\/jats:sub>\n                    \u2009=\u2009O). The product ion is [ZnOH]\n                    <jats:sup>+<\/jats:sup>\n                    . Collision-induced dissociation of a precursor complex created using CH\n                    <jats:sub>3<\/jats:sub>\n                    -\n                    <jats:sup>18<\/jats:sup>\n                    OH shows the isotope label is retained in CH\n                    <jats:sub>2<\/jats:sub>\n                    \u2009=\u2009O. Density functional theory calculations suggested that the \u201crearranged\u201d product, ZnOH with bound HNO\n                    <jats:sub>2<\/jats:sub>\n                    and formaldehyde is significantly lower in energy than ZnNO\n                    <jats:sub>3<\/jats:sub>\n                    with bound methanol. We therefore used infrared multiple-photon photodissociation spectroscopy to determine the structures of both [ZnNO\n                    <jats:sub>3<\/jats:sub>\n                    (CH\n                    <jats:sub>3<\/jats:sub>\n                    OH)\n                    <jats:sub>2<\/jats:sub>\n                    ]\n                    <jats:sup>+<\/jats:sup>\n                    and [ZnNO\n                    <jats:sub>3<\/jats:sub>\n                    (CH\n                    <jats:sub>3<\/jats:sub>\n                    OH)]\n                    <jats:sup>+<\/jats:sup>\n                    . The infrared spectra clearly show that both ions contain intact nitrate and methanol ligands, which suggests that rearrangement occurs during collision-induced dissociation of [ZnNO\n                    <jats:sub>3<\/jats:sub>\n                    (CH\n                    <jats:sub>3<\/jats:sub>\n                    OH)]\n                    <jats:sup>+<\/jats:sup>\n                    . Based on the density functional theory calculations, we propose that transfer of H, from the methyl group of the CH\n                    <jats:sub>3<\/jats:sub>\n                    OH ligand to nitrate, occurs in concert with the formation of a Zn\u2013C bond. After dissociation to release HNO\n                    <jats:sub>2<\/jats:sub>\n                    , the product rearranges with the insertion of the remaining O atom into the Zn\u2013C bond. Subsequent C\u2013O bond cleavage, with H transfer, produces an ion\u2013molecule complex composed of [ZnOH]\n                    <jats:sup>+<\/jats:sup>\n                    and O\u2009=\u2009CH\n                    <jats:sub>2<\/jats:sub>\n                    .\n                  <\/jats:p>","DOI":"10.1177\/1469066718809881","type":"journal-article","created":{"date-parts":[[2019,2,18]],"date-time":"2019-02-18T08:34:37Z","timestamp":1550478877000},"page":"58-72","update-policy":"https:\/\/doi.org\/10.1177\/sage-journals-update-policy","source":"Crossref","is-referenced-by-count":0,"title":["Isotope labeling and infrared multiple-photon photodissociation investigation of product ions generated by dissociation of [ZnNO\n                    <sub>3<\/sub>\n                    (CH\n                    <sub>3<\/sub>\n                    OH)\n                    <sub>2<\/sub>\n                    ]\n                    <sup>+<\/sup>\n                    : Conversion of methanol to formaldehyde"],"prefix":"10.1177","volume":"25","author":[{"given":"Evan","family":"Perez","sequence":"first","affiliation":[{"name":"Department of Chemistry and Biochemistry, Duquesne University, Pittsburgh, PA, USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5716-1188","authenticated-orcid":false,"given":"Theodore A","family":"Corcovilos","sequence":"additional","affiliation":[{"name":"Department of Physics, Duquesne University, Pittsburgh, PA, USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"John K","family":"Gibson","sequence":"additional","affiliation":[{"name":"Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA, USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jonathan","family":"Martens","sequence":"additional","affiliation":[{"name":"Institute for Molecules and Materials, FELIX Facility, Radboud University Nijmegen, Nijmegen, The Netherlands"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Giel","family":"Berden","sequence":"additional","affiliation":[{"name":"Institute for Molecules and Materials, FELIX Facility, Radboud University Nijmegen, Nijmegen, The Netherlands"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jos","family":"Oomens","sequence":"additional","affiliation":[{"name":"Institute for Molecules and Materials, FELIX Facility, Radboud University Nijmegen, Nijmegen, The Netherlands"},{"name":"van\u2018t Hoff Institute for Molecular Sciences, University of Amsterdam, Amsterdam, The Netherlands"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Michael J","family":"Van Stipdonk","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry, Duquesne University, Pittsburgh, PA, 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