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This article develops a bibliometric review to shed light and discuss how the (multi-dimensional) notion of periphery has been conceived and implicitly declinate in different literature streams studying low-carbon sustainability transitions at the sub-national level. While the studies explicitly addressing the issues of peripherality are still scarce, the article identifies four critical dimensions that contribute to frame structural bottlenecks and opportunities: socio-spatial unevenness, asset fragility, network positionality and agency and the multi-scalar embeddedness of transition policies. 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