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Scanning electron and atomic force microscopy, \u03bc-Raman spectroscopy, low incident angle and classical X-ray diffraction, acoustic emission assisted Brale indentation and thermal conductivity measurements were employed for the full characterisation of the diamond\/ Si<jats:sub>3<\/jats:sub>N<jats:sub>4<\/jats:sub> system. Using these techniques, the nucleation and growth stages as a function of substrate composition and surface pretreatment were characterised, as well as the diamond quality, the existence of residual stresses and the adhesion between the diamond film and the substrate. Based on this study, a tailored material was developed and tested in the machining of hardmetal workpieces with encouraging results. <\/jats:p>","DOI":"10.1179\/026708403225010136","type":"journal-article","created":{"date-parts":[[2004,4,21]],"date-time":"2004-04-21T13:44:10Z","timestamp":1082555050000},"page":"410-416","source":"Crossref","is-referenced-by-count":21,"title":["Tailored Si<sub>3<\/sub>N<sub>4<\/sub> Ceramic Substrates for CVD Diamond Coating"],"prefix":"10.1177","volume":"19","author":[{"given":"M.","family":"Amaral","sequence":"first","affiliation":[{"name":"Drs Amaral (msamaral@cv.ua.pt), Oliveira, Belmonte and Silva are in the Department of Ceramics and Glass Engineering, CICECO, University of Aveiro, 3810-193 Aveiro, Portugal and Drs Fernandes and Costa are in the Department of Physics, University of Aveiro, 3810 - 193 Aveiro, Portugal."}]},{"given":"F. 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