{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2022,4,2]],"date-time":"2022-04-02T14:04:58Z","timestamp":1648908298777},"reference-count":34,"publisher":"Springer Science and Business Media LLC","issue":"1","license":[{"start":{"date-parts":[[2013,5,20]],"date-time":"2013-05-20T00:00:00Z","timestamp":1369008000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0"}],"content-domain":{"domain":["link.springer.com"],"crossmark-restriction":false},"short-container-title":["Chemistry Central Journal"],"published-print":{"date-parts":[[2013,12]]},"abstract":"<jats:title>Abstract<\/jats:title>\n          <jats:sec>\n            <jats:title>Background<\/jats:title>\n            <jats:p>The novel chiral phosphorus-1,1-dithiolates [4-CH<jats:sub>3<\/jats:sub>OC<jats:sub>6<\/jats:sub>H<jats:sub>4<\/jats:sub>P(S)(OR)S]<jats:sup>-<\/jats:sup>[H<jats:sub>3<\/jats:sub>NC(CH<jats:sub>3<\/jats:sub>)<jats:sub>3<\/jats:sub>]<jats:sup>+<\/jats:sup> were synthesized by the reaction of [RPS<jats:sub>2<\/jats:sub>)]<jats:sub>2<\/jats:sub> (R\u2009=\u20094-MeOC<jats:sub>6<\/jats:sub>H<jats:sub>4<\/jats:sub>) or P<jats:sub>2<\/jats:sub>S<jats:sub>5<\/jats:sub> and the respective alcohol ROH (R\u2009=\u2009myrtanyl, 2-naphthylethyl, myrtenyl, borneol) in toluene. The reaction of phosphorus-1,1-dithiolates <jats:bold>1<\/jats:bold>\u2013<jats:bold>4<\/jats:bold> and Au(tht)Cl, AuClPPh<jats:sub>3<\/jats:sub> or AgNO<jats:sub>3<\/jats:sub> and PPh<jats:sub>3<\/jats:sub> gave rise to gold(I)- and silver(I)-complexes in THF. All compounds have been characterised by elemental analyses, IR, NMR (<jats:sup>1<\/jats:sup>H-, <jats:sup>13<\/jats:sup>C- and <jats:sup>31<\/jats:sup>P-) spectroscopy as well as MS measurements. Optical rotation values confirmed the chirality of the compounds. The Compound <jats:bold>4<\/jats:bold> has been characterized structurally by X-ray crystallography.<\/jats:p>\n          <\/jats:sec>\n          <jats:sec>\n            <jats:title>Results<\/jats:title>\n            <jats:p>Phosphorus-1,1,-dithiolate compounds were formed as liquids and were treated with suitable amine in order to convert them to their salts <jats:bold>1<\/jats:bold>\u2013<jats:bold>4<\/jats:bold> . They have been successfully characterized spectroscopically (IR, <jats:sup>1<\/jats:sup>H, <jats:sup>13<\/jats:sup>C, <jats:sup>31<\/jats:sup>P NMR) as well as mass spectra. The compound <jats:bold>4<\/jats:bold> has been also structurally by X-ray crystallography. The compound <jats:bold>4<\/jats:bold> crystallizes in the orthorhombic space group P2(1)2(1)2(1) with Z\u2009=\u20094. Compounds containing phosphorus and sulfur donor atoms are excellent ligands due to offering many metal complexes especially group 11\u201312 metals. The synthesis of gold(I) and silver(I) complexes with chiral phosphorus-1,1,-dithiolate and triphenylphosphine have been described and investigated.<\/jats:p>\n          <\/jats:sec>\n          <jats:sec>\n            <jats:title>Conclusions<\/jats:title>\n            <jats:p>In the present work, we report the synthesis, charactreization of the chiral phosphorus-1,1-dithiolate ligands and preparing the gold(I) and silver(I) phosphorus-1,1-dithiolate or S-donor with phosphine complexes. The molecular structure of the Compound <jats:bold>4<\/jats:bold> was determined by X-ray diffraction. Due to an easy synthesis method of phosphorus-1,1-dithiolate compounds and a good complexion reagent, it is possible the improvement of the collecting metallic gold or silver from the minerals. When the more ionic salt of phosphorus-1,1-dithiolate compounds were prepared in this way, the water can be used as a cheap solvent. As a result, it can be an alternatively method for the collecting metallic gold or silver from the minerals in future.<\/jats:p>\n          <\/jats:sec>","DOI":"10.1186\/1752-153x-7-89","type":"journal-article","created":{"date-parts":[[2013,5,20]],"date-time":"2013-05-20T10:16:42Z","timestamp":1369045002000},"update-policy":"http:\/\/dx.doi.org\/10.1007\/springer_crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Novel Gold(I) and Silver(I) Complexes of Phosphorus-1,1,-dithiolates and Molecular Structure of [O,O\u2019-(Bornyl)2PS2]H3NC(CH3)3"],"prefix":"10.1186","volume":"7","author":[{"given":"Samet","family":"Solak","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Cemal","family":"Aydemir","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mehmet","family":"Karakus","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Peter","family":"L\u00f6nnecke","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"297","published-online":{"date-parts":[[2013,5,20]]},"reference":[{"key":"613_CR1","doi-asserted-by":"publisher","first-page":"265","DOI":"10.1039\/p29950000265","volume":"2","author":"AJ Burn","year":"1995","unstructured":"Burn AJ, Gosney I, Warrens CP, Wastle JP: Phosphorus-31 NMR investigation of the heterogeneous hydrolytic decomposition of zinc(II) bis(O, O-dialkyl dithiophosphate) lubricant additives. 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