{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,28]],"date-time":"2026-04-28T21:16:26Z","timestamp":1777410986285,"version":"3.51.4"},"reference-count":48,"publisher":"Oxford University Press (OUP)","issue":"11","license":[{"start":{"date-parts":[[2023,9,27]],"date-time":"2023-09-27T00:00:00Z","timestamp":1695772800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/academic.oup.com\/pages\/standard-publication-reuse-rights"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2023,11,15]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Metastable solid electrolytes exhibit superior conductivity compared to stable ones, making them a subject of considerable interest. However, synthesis of the metastable phase is affected by multiple thermodynamic and kinetic parameters, leading to ambiguity in the organization of stability and metastability. In this study, we organized remnant and intermediate metastability based on temperature. The intermediate metastable phase, which is less stable than the temperature-independent stable phase, typically transforms into the stable phase(s) at high temperatures. In contrast, the remnant metastable phase is formed by first obtaining most stable phase at specific temperatures and then \u201ctrapping\u201d it by rapidly changing the temperature. By investigating Li+ conducting chlorides, Li3MCl6 (M = Y and Ho), we demonstrated that heating starting materials to approximately 600 K produced low-temperature Li3MCl6 phase with one formula unit while further heating resulted in high-temperature Li3MCl6 phase with three formula units. Annealing quenched Li3MCl6 at 573 K resulted in a phase transition from the high-temperature to low-temperature phase, indicating that the high-temperature phase was remnant metastable at low temperatures.<\/jats:p>","DOI":"10.1246\/bcsj.20230132","type":"journal-article","created":{"date-parts":[[2023,9,26]],"date-time":"2023-09-26T17:00:24Z","timestamp":1695747624000},"page":"1262-1268","source":"Crossref","is-referenced-by-count":12,"title":["Stability and Metastability of Li3YCl6 and Li3HoCl6"],"prefix":"10.1093","volume":"96","author":[{"given":"Hiroaki","family":"Ito","sequence":"first","affiliation":[{"name":"Graduate School of Chemical Science and Engineering, Hokkaido University, Kita 13, Nishi 8, Sapporo, Hokkaido 060-8628 , Japan"}]},{"given":"Yuki","family":"Nakahira","sequence":"additional","affiliation":[{"name":"Foundational Quantum Technology Research Directorate, National Institutes for Quantum Science and Technology (QST), Hyogo 679-5148 , Japan"}]},{"given":"Naoki","family":"Ishimatsu","sequence":"additional","affiliation":[{"name":"Graduate School of Advanced Science and Engineering, Hiroshima University, 1-3-1 Kagamiyama, Higashihiroshima, Hiroshima 739-8526 , Japan"}]},{"given":"Yosuke","family":"Goto","sequence":"additional","affiliation":[{"name":"National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8568 , Japan"}]},{"given":"Aichi","family":"Yamashita","sequence":"additional","affiliation":[{"name":"Department of Physics, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397 , Japan"}]},{"given":"Yoshikazu","family":"Mizuguchi","sequence":"additional","affiliation":[{"name":"Department of Physics, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397 , Japan"}]},{"given":"Chikako","family":"Moriyoshi","sequence":"additional","affiliation":[{"name":"Graduate School of Advanced Science and Engineering, Hiroshima University, 1-3-1 Kagamiyama, Higashihiroshima, Hiroshima 739-8526 , Japan"}]},{"given":"Takashi","family":"Toyao","sequence":"additional","affiliation":[{"name":"Institute for Catalysis, Hokkaido University, Kita 21, Nishi 10, Sapporo, Hokkaido 001-0021 , Japan"}]},{"given":"Ken-ichi","family":"Shimizu","sequence":"additional","affiliation":[{"name":"Institute for Catalysis, Hokkaido University, Kita 21, Nishi 10, Sapporo, Hokkaido 001-0021 , Japan"}]},{"given":"Hiroshi","family":"Oike","sequence":"additional","affiliation":[{"name":"PRESTO, Japan Science and Technology Agency, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012 , Japan"}]},{"given":"Masanori","family":"Enoki","sequence":"additional","affiliation":[{"name":"Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai, Miyagi 980-8577 , Japan"}]},{"given":"Nataly Carolina","family":"Rosero-Navarro","sequence":"additional","affiliation":[{"name":"Instituto de Cer\u00e1mica y Vidrio (CSIC), Campus de Cantoblanco, 28049 Madrid , Spain"},{"name":"Faculty of Engineering, Hokkaido University, Kita 13, Nishi 8, Sapporo, Hokkaido 060-8628 , Japan"}]},{"given":"Akira","family":"Miura","sequence":"additional","affiliation":[{"name":"Faculty of Engineering, Hokkaido University, Kita 13, Nishi 8, Sapporo, Hokkaido 060-8628 , Japan"}]},{"given":"Kiyoharu","family":"Tadanaga","sequence":"additional","affiliation":[{"name":"Faculty of Engineering, Hokkaido University, Kita 13, Nishi 8, Sapporo, Hokkaido 060-8628 , Japan"}]}],"member":"286","published-online":{"date-parts":[[2023,9,27]]},"reference":[{"key":"2024011619342704900_r1","doi-asserted-by":"publisher","first-page":"24","DOI":"10.1063\/1.881303","volume":"44","author":"Sleight","year":"1991","journal-title":"Phys. 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