{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,9,21]],"date-time":"2025-09-21T17:41:54Z","timestamp":1758476514526},"reference-count":41,"publisher":"Walter de Gruyter GmbH","issue":"7","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2009,6,30]]},"abstract":"<jats:p>A review discussing general structural features of oxygen-bridged dinuclear vanadium(IV and\/or V) complexes is presented, covering those that have been characterized by single-crystal X-ray diffraction. Many of these compounds contain functional Schiff bases or amines as ligands, this work illustrating the high propensity of the V center to increase its coordination number via dimerization of two tetra- or penta-coordinate monomers, if the steric and electronic control exerted by the ligands allows it. We also report the synthesis and characterization by single-crystal X-ray diffraction of two new dinuclear complexes: [{V<jats:sup>V<\/jats:sup>O[sal(<jats:italic>R<\/jats:italic>,<jats:italic>R<\/jats:italic>-chen)]}<jats:sub>2<\/jats:sub>(\u03bc<jats:sub>2<\/jats:sub>-O)<jats:sub>2<\/jats:sub>] and [{V<jats:sup>V<\/jats:sup>O[mvan(<jats:italic>S<\/jats:italic>,<jats:italic>S<\/jats:italic>-chen)]}<jats:sub>2<\/jats:sub>(\u03bc<jats:sub>2<\/jats:sub>-O)<jats:sub>2<\/jats:sub>]. The complexes contain tridentate ligands with O-phenolate, N-imine, and N-amine coordination to the V<jats:sup>V<\/jats:sup> center. The molecular structures of these compounds demonstrate that they form dinuclear species in the solid state with a {OV<jats:sup>V<\/jats:sup>(\u03bc<jats:sub>2<\/jats:sub>-O)<jats:sub>2<\/jats:sub>V<jats:sup>V<\/jats:sup>O} core.<\/jats:p>","DOI":"10.1351\/pac-con-08-09-16","type":"journal-article","created":{"date-parts":[[2009,7,16]],"date-time":"2009-07-16T16:04:35Z","timestamp":1247760275000},"page":"1297-1311","source":"Crossref","is-referenced-by-count":14,"title":["Influence of polydentate ligands in the structure of dinuclear vanadium compounds"],"prefix":"10.1515","volume":"81","author":[{"given":"Fernando","family":"Avecilla","sequence":"first","affiliation":[{"name":"1Departamento de Qu\u00edmica Fundamental, Universidade da Coru\u00f1a, Campus da Zapateira s\/n, 15071, A Coru\u00f1a, Spain"}]},{"given":"Pedro","family":"Ad\u00e3o","sequence":"additional","affiliation":[{"name":"2Centro de Qu\u00edmica Estrutural, Instituto Superior T\u00e9cnico, TU Lisbon, Av. 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