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Express"],"published-print":{"date-parts":[[2020,5,11]]},"abstract":"<jats:p>A core-removed D-shaped structure with different residual thickness (RT) was manufactured on a single mode silica fiber (SMF) to enhance the sensitivity by using of ultra-precise polishing technology. With six different RTs ranging from \u223c55 \u00b5m to \u223c28 \u00b5m, the RT enhancement effect in a D-shaped SMF was researched in detail. The influence of the RT on its transmission spectra was investigated both theoretically and experimentally. Considering a compromise between the multimode interference efficiency and optical power loss, an optimum RT value of 34.09 \u00b5m was achieved. The obtained refractive index (RI) sensitivity was 10243 nm\/RIU in the RI range of 1.430-1.444, corresponding to a RI resolution of 1.9\u00d710<jats:sup>\u22126<\/jats:sup> RIU. A high-performance all-fiber sensor was developed to monitor the evaporation process volatile organic compounds (VOCs) based on the RT-enhanced D-shaped SMF. As proof of concept, a 2-hour continuous monitoring was carried to monitor the chloroform and alcohol mixture. As a result, the evaporation of alcohol and chloroform were clearly identified and monitored. 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