{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,8]],"date-time":"2026-05-08T05:38:47Z","timestamp":1778218727040,"version":"3.51.4"},"reference-count":29,"publisher":"Optica Publishing Group","issue":"18","license":[{"start":{"date-parts":[[2025,9,5]],"date-time":"2025-09-05T00:00:00Z","timestamp":1757030400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/doi.org\/10.1364\/OA_License_v2#VOR"},{"start":{"date-parts":[[2025,9,5]],"date-time":"2025-09-05T00:00:00Z","timestamp":1757030400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/opg.optica.org\/policies\/opg-tdm-policy.json"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["12174153"],"award-info":[{"award-number":["12174153"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100011789","name":"Department of Science and Technology of Jilin Province","doi-asserted-by":"publisher","award":["20250201054GX"],"award-info":[{"award-number":["20250201054GX"]}],"id":[{"id":"10.13039\/501100011789","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["opg.optica.org"],"crossmark-restriction":false},"short-container-title":["Opt. Lett."],"published-print":{"date-parts":[[2025,9,15]]},"abstract":"<jats:p>Stimulated Raman Scattering (SRS) characteristic features of water molecules in acid and alkaline solution environments are investigated. SRS was switched from existence of one single peak (3364\u2009cm<jats:sup>\u22121<\/jats:sup>) to coexistence of two peaks (3295\u2009cm<jats:sup>\u22121<\/jats:sup> and 3367\u2009cm<jats:sup>\u22121<\/jats:sup>) and three peaks (3227\u2009cm<jats:sup>\u22121<\/jats:sup>, 3319\u2009cm<jats:sup>\u22121<\/jats:sup>, and 3429\u2009cm<jats:sup>\u22121<\/jats:sup>) via pH adjustment. The single SRS peak attributes to O\u2013H antisymmetric stretching vibration at 3364\u2009cm<jats:sup>\u22121<\/jats:sup> with pH\u2009=\u20097.0. SRS spectra exhibit the characteristic peak of the O\u2013H symmetric stretching vibration locating from 3227\u2009cm<jats:sup>\u22121<\/jats:sup> to 3295\u2009cm<jats:sup>\u22121<\/jats:sup> when pH\u2009=\u20093.6, 4.0, 10.4, and 11.0, because the hydrogen and hydroxide ions lead to a stronger network structure of hydrogen bonding (HB) in water molecules. At the same time, the SRS threshold lowered to 7.50\u2009mJ and 7.40\u2009mJ at pH\u2009=\u20094.0 and 11.0. The optimized structures of water clusters were calculated by the density functional theory, and the simulated Raman spectra of (H<jats:sub>2<\/jats:sub>O)<jats:sub>5<\/jats:sub>, H<jats:sub>3<\/jats:sub>O<jats:sup>+<\/jats:sup>-(H<jats:sub>2<\/jats:sub>O)<jats:sub>5<\/jats:sub>, and OH<jats:sup>\u2212<\/jats:sup>-(H<jats:sub>2<\/jats:sub>O)<jats:sub>5<\/jats:sub> structures match the SRS results at pH\u2009=\u20097.0, 4.0, and 11.0, respectively. The results reveal that acid or alkaline environment affects the intermolecular forces within the HB network, regulating symmetric and antisymmetric stretching vibration modes of O\u2013H. This study provides a novel insight into the HB network and can be extended to other organic solvents.<\/jats:p>","DOI":"10.1364\/ol.570042","type":"journal-article","created":{"date-parts":[[2025,7,22]],"date-time":"2025-07-22T14:59:35Z","timestamp":1753196375000},"page":"5670","update-policy":"https:\/\/doi.org\/10.1364\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Dominating stimulated Raman scattering of O\u2013H symmetric and antisymmetric stretching vibrations in water molecule by pH-dependent hydrogen-bonding network"],"prefix":"10.1364","volume":"50","author":[{"given":"Jiayi","family":"Li","sequence":"first","affiliation":[{"name":"Jilin University"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Haixin","family":"Wang","sequence":"additional","affiliation":[{"name":"Jilin University"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chengqi","family":"Li","sequence":"additional","affiliation":[{"name":"Jilin University"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Wei","family":"Zhang","sequence":"additional","affiliation":[{"name":"Nanjing University of Science and Technology"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Wenhui","family":"Fang","sequence":"additional","affiliation":[{"name":"Changchun University of Science and Technology"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1904-7461","authenticated-orcid":true,"given":"Zhiwei","family":"Men","sequence":"additional","affiliation":[{"name":"Jilin University"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"285","published-online":{"date-parts":[[2025,9,5]]},"reference":[{"key":"ol-50-18-5670-R1","doi-asserted-by":"publisher","first-page":"5385","DOI":"10.1021\/jp405052g","volume":"117","author":"Do","year":"2013","journal-title":"J. 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