{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,29]],"date-time":"2026-04-29T05:47:32Z","timestamp":1777441652144,"version":"3.51.4"},"reference-count":19,"publisher":"SAGE Publications","issue":"2","license":[{"start":{"date-parts":[[2004,2,1]],"date-time":"2004-02-01T00:00:00Z","timestamp":1075593600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/journals.sagepub.com\/page\/policies\/text-and-data-mining-license"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Appl Spectrosc"],"published-print":{"date-parts":[[2004,2]]},"abstract":"<jats:p>\n                    Cyanogenic glucosides were studied using Raman spectroscopy. Spectra of the crystal forms of linamarin, linustatin, neolinustatin, amygdalin, sambunigrin, and dhurrin were obtained using a Raman spectrograph microscope equipped with a 532 nm laser. The position of the signal from the C=N triple bond of the cyanohydrin group was influenced by the nature of the side group and was above 2240 cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    for the three cyanogenic glucosides that contain a neighboring aromatic ring, and below or partially below 2240 cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    for the non-aromatic cyanoglucosides. Signals from the CN bond of linamarin\/lotaustralin in leaves and roots from a medium cyanogenic cassava variety were obtained in situ using a Fourier transform near-infrared (FT-NIR) Raman interferometer with a 1064 nm laser, but the signal was very weak and difficult to obtain. A spectrum containing a signal from the CN bond of dhurrin in a freeze-dried sorghum leaf was also obtained using this instrument. Surface-enhanced Raman Spectroscopy (SERS) was demonstrated to be a more sensitive method that enabled determination of the cyanogenic potential of plant tissue. The SERS method was optimized by flow injection (FI) using a colloidal gold dispersion as effluent. Potential problems and pitfalls of the method are discussed.\n                  <\/jats:p>","DOI":"10.1366\/000370204322842959","type":"journal-article","created":{"date-parts":[[2004,4,21]],"date-time":"2004-04-21T08:32:35Z","timestamp":1082536355000},"page":"212-217","source":"Crossref","is-referenced-by-count":23,"title":["Raman Spectroscopic Analysis of Cyanogenic Glucosides in Plants: Development of a Flow Injection Surface-Enhanced Raman Scatter (FI-SERS) Method for Determination of Cyanide"],"prefix":"10.1177","volume":"58","author":[{"given":"Lisbeth Garbrecht","family":"Thygesen","sequence":"first","affiliation":[{"name":"Centre for Advanced Food Studies, Department of Dairy and Food Science, Food Technology, The Royal Veterinary and Agricultural University, 30 Rolighedsvej, DK-1958 Frederiksberg C, Denmark (L.G.T., S.B.E.); Plant Biochemistry Laboratory, Department of Plant Biology, 40 Thorvaldsensvej, DK-1871 Frederiksberg C, Denmark (K.J., B.L.M.)"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Kirsten","family":"J\u00f8rgensen","sequence":"additional","affiliation":[{"name":"Centre for Advanced Food Studies, Department of Dairy and Food Science, Food Technology, The Royal Veterinary and Agricultural University, 30 Rolighedsvej, DK-1958 Frederiksberg C, Denmark (L.G.T., S.B.E.); Plant Biochemistry Laboratory, Department of Plant Biology, 40 Thorvaldsensvej, DK-1871 Frederiksberg C, Denmark (K.J., B.L.M.)"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Birger Lindberg","family":"M\u00f8ller","sequence":"additional","affiliation":[{"name":"Centre for Advanced Food Studies, Department of Dairy and Food Science, Food Technology, The Royal Veterinary and Agricultural University, 30 Rolighedsvej, DK-1958 Frederiksberg C, Denmark (L.G.T., S.B.E.); Plant Biochemistry Laboratory, Department of Plant Biology, 40 Thorvaldsensvej, DK-1871 Frederiksberg C, Denmark (K.J., B.L.M.)"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"S\u00f8ren Balling","family":"Engelsen","sequence":"additional","affiliation":[{"name":"Centre for Advanced Food Studies, Department of Dairy and Food Science, Food Technology, The Royal Veterinary and Agricultural University, 30 Rolighedsvej, DK-1958 Frederiksberg C, Denmark (L.G.T., S.B.E.); Plant Biochemistry Laboratory, Department of Plant Biology, 40 Thorvaldsensvej, DK-1871 Frederiksberg C, Denmark (K.J., B.L.M.)"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"179","published-online":{"date-parts":[[2004,2,1]]},"reference":[{"key":"bibr1-000370204322842959","doi-asserted-by":"publisher","DOI":"10.1016\/0022-0728(94)03765-U"},{"key":"bibr2-000370204322842959","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-0728(96)04810-3"},{"key":"bibr3-000370204322842959","doi-asserted-by":"publisher","DOI":"10.1366\/000370202760295368"},{"key":"bibr4-000370204322842959","doi-asserted-by":"publisher","DOI":"10.1016\/S0924-2244(02)00243-1"},{"key":"bibr5-000370204322842959","doi-asserted-by":"publisher","DOI":"10.1074\/jbc.275.3.1966"},{"key":"bibr6-000370204322842959","doi-asserted-by":"publisher","DOI":"10.1016\/0305-1978(86)90093-1"},{"key":"bibr7-000370204322842959","doi-asserted-by":"publisher","DOI":"10.1021\/ac60004a018"},{"key":"bibr8-000370204322842959","doi-asserted-by":"publisher","DOI":"10.1021\/ac60356a036"},{"key":"bibr9-000370204322842959","doi-asserted-by":"publisher","DOI":"10.1002\/0471721646"},{"key":"bibr10-000370204322842959","doi-asserted-by":"publisher","DOI":"10.1177\/25.11.21217"},{"key":"bibr11-000370204322842959","doi-asserted-by":"publisher","DOI":"10.1366\/0003702001950508"},{"key":"bibr12-000370204322842959","doi-asserted-by":"publisher","DOI":"10.1366\/0003702021955358"},{"key":"bibr13-000370204322842959","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-2860(99)00221-5"},{"key":"bibr14-000370204322842959","doi-asserted-by":"publisher","DOI":"10.1104\/pp.35.4.535"},{"key":"bibr15-000370204322842959","doi-asserted-by":"publisher","DOI":"10.1366\/0003702944029677"},{"key":"bibr16-000370204322842959","doi-asserted-by":"publisher","DOI":"10.1021\/j150668a038"},{"key":"bibr17-000370204322842959","doi-asserted-by":"publisher","DOI":"10.1016\/S0924-2031(00)00108-9"},{"key":"bibr18-000370204322842959","doi-asserted-by":"publisher","DOI":"10.1016\/S0924-2031(02)00034-6"},{"key":"bibr19-000370204322842959","doi-asserted-by":"publisher","DOI":"10.1366\/0003702894202201"}],"container-title":["Applied Spectroscopy"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/journals.sagepub.com\/doi\/pdf\/10.1366\/000370204322842959","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/journals.sagepub.com\/doi\/pdf\/10.1366\/000370204322842959","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,4,28]],"date-time":"2026-04-28T12:15:07Z","timestamp":1777378507000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.sagepub.com\/doi\/10.1366\/000370204322842959"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2004,2]]},"references-count":19,"journal-issue":{"issue":"2","published-print":{"date-parts":[[2004,2]]}},"alternative-id":["10.1366\/000370204322842959"],"URL":"https:\/\/doi.org\/10.1366\/000370204322842959","relation":{},"ISSN":["0003-7028","1943-3530"],"issn-type":[{"value":"0003-7028","type":"print"},{"value":"1943-3530","type":"electronic"}],"subject":[],"published":{"date-parts":[[2004,2]]}}}