{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T17:24:37Z","timestamp":1788369877621,"version":"build-2803163510"},"reference-count":26,"publisher":"SAGE Publications","issue":"12","license":[{"start":{"date-parts":[[2012,12,1]],"date-time":"2012-12-01T00:00:00Z","timestamp":1354320000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/journals.sagepub.com\/page\/policies\/text-and-data-mining-license"}],"content-domain":{"domain":["journals.sagepub.com"],"crossmark-restriction":true},"short-container-title":["Appl Spectrosc"],"published-print":{"date-parts":[[2012,12]]},"abstract":"<jats:p> Laser-induced breakdown spectroscopy (LIBS) has shown great promise for applications in chemical, biological, and explosives sensing and has significant potential for real-time standoff detection and analysis. In this study, LIBS emissions were obtained in the mid-infrared (MIR) and long-wave infrared (LWIR) spectral regions for potential applications in explosive material sensing. The IR spectroscopy region revealed vibrational and rotational signatures of functional groups in molecules and fragments thereof. The silicon-based detector for conventional ultraviolet\u2013visible LIBS operations was replaced with a mercury\u2013cadmium\u2013telluride detector for MIR\u2013LWIR spectral detection. The IR spectral signature region between 4 and 12 \u03bcm was mined for the appearance of MIR and LWIR\u2013LIBS emissions directly indicative of oxygenated breakdown products as well as dissociated, and\/or recombined sample molecular fragments. Distinct LWIR\u2013LIBS emission signatures from dissociated-recombination sample molecular fragments between 4 and 12 \u03bcm are observed for the first time. <\/jats:p>","DOI":"10.1366\/12-06700","type":"journal-article","created":{"date-parts":[[2012,12,11]],"date-time":"2012-12-11T04:38:24Z","timestamp":1355200704000},"page":"1397-1402","update-policy":"https:\/\/doi.org\/10.1177\/sage-journals-update-policy","source":"Crossref","is-referenced-by-count":24,"title":["Long-Wave, Infrared Laser-Induced Breakdown (LIBS) Spectroscopy Emissions from Energetic Materials"],"prefix":"10.1177","volume":"66","author":[{"given":"Clayton S.-C.","family":"Yang","sequence":"first","affiliation":[{"name":"Battelle Eastern Science and Technology Center, Aberdeen, MD 21001, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ei E.","family":"Brown","sequence":"additional","affiliation":[{"name":"Department of Physics, Hampton University, Hampton, VA 23668, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Uwe","family":"Hommerich","sequence":"additional","affiliation":[{"name":"Department of Physics, Hampton University, Hampton, VA 23668, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Feng","family":"Jin","sequence":"additional","affiliation":[{"name":"Brimrose Corporation of America, Baltimore, MD 21152, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sudhir B.","family":"Trivedi","sequence":"additional","affiliation":[{"name":"Brimrose Corporation of America, Baltimore, MD 21152, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alan C.","family":"Samuels","sequence":"additional","affiliation":[{"name":"Edgewood Chemical Biological Center, Aberdeen Proving Ground, MD 21010, USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"A. 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