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It was based on the on-line photoreaction of thiacloprid in a basic medium, with quinine acting as the sensitizer of the chemiluminescent response; cerium (IV) in sulfuric acid medium was used as the oxidant. High degrees of automation and reproducibility were achieved using a flow-injection analysis (FIA) manifold. The validation of the method was performed in terms of selectivity, linearity, limit of detection (LOD), precision, and accuracy. Liquid chromatography with ultraviolet (UV) detection was used as reference for mineral, tap, ground, and spring water samples. The proposed method is fast (with a throughput of 130 h<jats:sup>\u22121<\/jats:sup>), sensitive (LOD of 0.8 ng mL<jats:sup>\u22121<\/jats:sup> without preconcentration steps and of 0.08 ng mL<jats:sup>\u22121<\/jats:sup> with solid-phase extraction [SPE]), low cost, and possible to couple with separation methods for the simultaneous determination of other pesticides. The enhanced chemiluminescence intensity was linear with the thiacloprid concentration above the 2\u201380 and 80\u2013800 ng mL<jats:sup>\u22121<\/jats:sup> ranges. A possible reaction mechanism is also discussed. <\/jats:p>","DOI":"10.1366\/13-07330","type":"journal-article","created":{"date-parts":[[2015,2,5]],"date-time":"2015-02-05T22:42:43Z","timestamp":1423176163000},"page":"642-648","update-policy":"https:\/\/doi.org\/10.1177\/sage-journals-update-policy","source":"Crossref","is-referenced-by-count":6,"title":["Fast Determination of Thiacloprid by Photoinduced Chemiluminescence"],"prefix":"10.1177","volume":"68","author":[{"given":"M\u00f3nica","family":"Catal\u00e1-Icardo","sequence":"first","affiliation":[{"name":"Universitat Polit\u00e8cnica de Val\u00e8ncia, Instituto de Investigaci\u00f3n para la Gesti\u00f3n Integrada de Zonas Costeras (IGIC), C\/ Paranimf n\u00b01, 46730 Grao de Gand\u00eda, Valencia, Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jos\u00e9 Luis","family":"L\u00f3pez-Paz","sequence":"additional","affiliation":[{"name":"Universitat Polit\u00e8cnica de Val\u00e8ncia, Centro de Reconocimiento Molecular y Desarrollo Tecnol\u00f3gico (IDM), Camino de Vera s\/n, 46022 Valencia, Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Laura Mar\u00eda","family":"P\u00e9rez-Plancha","sequence":"additional","affiliation":[{"name":"Universitat Polit\u00e8cnica de Val\u00e8ncia, Instituto de Investigaci\u00f3n para la Gesti\u00f3n Integrada de Zonas Costeras (IGIC), C\/ Paranimf n\u00b01, 46730 Grao de Gand\u00eda, Valencia, Spain"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"179","published-online":{"date-parts":[[2014,6,1]]},"reference":[{"key":"bibr1-13-07330","doi-asserted-by":"publisher","DOI":"10.1146\/annurev.pharmtox.45.120403.095930"},{"key":"bibr2-13-07330","unstructured":"Environmental Protection Agency (EPA). \u201cPesticide Fact Sheet (Name of Chemical: Thiacloprid)\u201d. 2003. http:\/\/www.epa.gov\/pesticides\/chem_search\/reg_actions\/registration\/fs_PC-014019_26-Sep-03.pdf [accessed Jul 1 2013]."},{"key":"bibr3-13-07330","doi-asserted-by":"publisher","DOI":"10.1007\/s00216-012-6338-3"},{"key":"bibr4-13-07330","doi-asserted-by":"publisher","DOI":"10.1016\/j.tox.2013.04.007"},{"key":"bibr5-13-07330","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2011.03.039"},{"issue":"4","key":"bibr6-13-07330","first-page":"495","volume":"37","author":"Xie W.","year":"2009","journal-title":"Fenxi Huaxue [Chinese J. 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