{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T20:06:33Z","timestamp":1760299593371},"reference-count":36,"publisher":"Public Library of Science (PLoS)","issue":"5","license":[{"start":{"date-parts":[[2017,5,11]],"date-time":"2017-05-11T00:00:00Z","timestamp":1494460800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"the Natural Science Foundation of Anhui Province","award":["KJ2013B161"],"award-info":[{"award-number":["KJ2013B161"]}]},{"name":"the Special Project of the Scientific Research Institute Foundation","award":["XLY-201319"],"award-info":[{"award-number":["XLY-201319"]}]},{"name":"the Dr. Scientific Research Foundation of Chaohu University"}],"content-domain":{"domain":["www.plosone.org"],"crossmark-restriction":false},"short-container-title":["PLoS ONE"],"DOI":"10.1371\/journal.pone.0176332","type":"journal-article","created":{"date-parts":[[2017,5,11]],"date-time":"2017-05-11T17:47:04Z","timestamp":1494524824000},"page":"e0176332","update-policy":"http:\/\/dx.doi.org\/10.1371\/journal.pone.corrections_policy","source":"Crossref","is-referenced-by-count":6,"title":["Heterogeneous Ag-TiO2-SiO2 composite materials as novel catalytic systems for selective epoxidation of cyclohexene by H2O2"],"prefix":"10.1371","volume":"12","author":[{"given":"Xin","family":"Wang","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jianyue","family":"Xue","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xinyun","family":"Wang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xiaoheng","family":"Liu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"340","published-online":{"date-parts":[[2017,5,11]]},"reference":[{"key":"ref1","doi-asserted-by":"crossref","first-page":"17570","DOI":"10.1021\/jp074512c","article-title":"Selective catalytic cyclohexene oxidation using titanium-functionalized silicone nanospheres","volume":"111","author":"CA Bradley","year":"2007","journal-title":"J. Phys. Chem. C"},{"key":"ref2","first-page":"1617","article-title":"Selective Allylic oxidation of cyclohexene catalyzed by nitrogen-doped carbon nanotubes","volume":"3","author":"YH Cao","year":"2014","journal-title":"Catal"},{"key":"ref3","doi-asserted-by":"crossref","first-page":"3418","DOI":"10.1016\/j.jorganchem.2009.06.034","article-title":"Novel schiff-base complexes of methyltrioxorhenium (VII) and their performances in epoxidation of cyclohexene","volume":"694","author":"CJ Qiu","year":"2009","journal-title":"J. Organomet. Chem"},{"key":"ref4","doi-asserted-by":"crossref","first-page":"364","DOI":"10.1016\/j.apcata.2013.06.012","article-title":"A comparative study of molybdenum promoted vanadium phosphate catalysts towards epoxidation of cyclohexene","volume":"464\u2013465","author":"GC Behera","year":"2013","journal-title":"Appl. Catal. A: General"},{"key":"ref5","first-page":"2020","article-title":"Surface functionalization of supported Mn clusters to produce robust Mn catalysts for selective epoxidation","volume":"3","author":"S Muratsugu","year":"2013","journal-title":"Catal"},{"key":"ref6","first-page":"1719","article-title":"Host (dealuminated Y zeolite)-guest (trinuclear metal clusters of Co, Mn and Cox\/Mny) as nanocomposite catalysts for the epoxidation of cyclohexene","volume":"36","author":"M Moosavifar","year":"2015","journal-title":"J. Catal"},{"key":"ref7","doi-asserted-by":"crossref","first-page":"105","DOI":"10.1016\/j.molcata.2016.06.012","article-title":"Manganese porphines-NH<sub>2<\/sub>@SBA-15 as heterogeneous catalytic systems with homogeneous behavior: Effect of length of linker in immobilized manganese porphine catalysts in oxidation of olefins","volume":"423","author":"S Rayati","year":"2016","journal-title":"J. Mol. Catal. A: Chem"},{"key":"ref8","doi-asserted-by":"crossref","first-page":"11441","DOI":"10.1016\/j.ijhydene.2016.05.022","article-title":"Effects of heterogeneous-homogeneous interaction on the homogeneous ignition in hydrogen- fueled catalyticmicroreactors","volume":"41","author":"JJ Chen","year":"2016","journal-title":"Int. J. Hydrogen Energy"},{"key":"ref9","doi-asserted-by":"crossref","first-page":"70","DOI":"10.1016\/j.molcata.2013.11.033","article-title":"Direct decomposition of NO on Ba catalysts supported on rare earth oxides","volume":"383\u2013384","author":"Y Doi","year":"2014","journal-title":"J. Mol. Catal. A Chem"},{"key":"ref10","doi-asserted-by":"crossref","first-page":"292","DOI":"10.1016\/j.cattod.2015.07.021","article-title":"Palladium nanoparticles supported on CNT functionalized by rare-earth oxides for solvent-free aerobic oxidation of benzyl alcohol","volume":"259","author":"YB Yan","year":"2016","journal-title":"Catal. Today."},{"key":"ref11","doi-asserted-by":"crossref","first-page":"258","DOI":"10.1016\/j.jallcom.2016.05.278","article-title":"Green synthesis of the Ag\/HZSM-5 nanocomposite by using Euphorbia heterophylla leaf extract: A recoverablecatalyst for reduction of organic dyes","volume":"685","author":"M Tajbakhsh","year":"2016","journal-title":"J. Alloys Compd"},{"key":"ref12","doi-asserted-by":"crossref","first-page":"213","DOI":"10.1016\/j.apcata.2015.10.023","article-title":"Exploring the mechanisms of metal co-catalysts in photocatalytic reduction reactions: Is Ag a good candidate?","volume":"518","author":"Q Yang","year":"2016","journal-title":"Appl. Catal., A"},{"key":"ref13","doi-asserted-by":"crossref","first-page":"188","DOI":"10.1016\/j.jcat.2016.01.019","article-title":"Soot oxidation over CeO<sub>2<\/sub> and Ag\/CeO<sub>2<\/sub>: Factors determining the catalyst activity and stability during reaction","volume":"337","author":"S Liu","year":"2016","journal-title":"J. Catal"},{"key":"ref14","first-page":"1183","article-title":"Cyclohexene epoxidation with cyclohexyl hydroperoxide: a catalytic route to largely increase oxygenate yield from cyclohexane oxidation","volume":"1","author":"BPC Hereijgers","year":"2011","journal-title":"Catal"},{"key":"ref15","doi-asserted-by":"crossref","first-page":"16","DOI":"10.1016\/j.micromeso.2016.06.031","article-title":"Effective hierarchization of TS-1 and its catalytic performance in cyclohexene epoxidation","volume":"233","author":"J Tekla","year":"2016","journal-title":"Microporous Mesoporous Mater"},{"key":"ref16","doi-asserted-by":"crossref","first-page":"10","DOI":"10.1016\/j.molcata.2016.01.034","article-title":"Encapsulation of SALEN- and SALHD-Mn(III) complexes in an Al-pillared clay for bicarbonate-assisted catalyticepoxidation of cyclohexene","volume":"416","author":"AM Garcia","year":"2016","journal-title":"J. Mol. Catal. A: Chem"},{"key":"ref17","doi-asserted-by":"crossref","first-page":"14","DOI":"10.1016\/j.clay.2015.01.026","article-title":"Novel vanadium- chromium-bentonite green catalysts for cyclohexene epoxidation","volume":"107","author":"N Belaidi","year":"2015","journal-title":"Appl. Clay Sci"},{"key":"ref18","doi-asserted-by":"crossref","first-page":"393","DOI":"10.1016\/j.molcata.2016.07.038","article-title":"Highly efficient epoxidation of cyclohexene with aqueous H<sub>2<\/sub>O<sub>2<\/sub> over powdered anion-resin supported solid catalysts","volume":"423","author":"C Peng","year":"2016","journal-title":"J. Mol. Catal. A: Chem"},{"key":"ref19","doi-asserted-by":"crossref","first-page":"12","DOI":"10.1016\/j.renene.2016.01.070","article-title":"Development of novel Ag\/bauxite nanocomposite as a heterogeneous catalyst for biodiesel production","volume":"92","author":"E Bet-Moushoul","year":"2016","journal-title":"Renewable Energy"},{"key":"ref20","doi-asserted-by":"crossref","first-page":"98","DOI":"10.1016\/j.materresbull.2015.07.019","article-title":"A novel and active catalyst Ag\/ZnO for oxidant-free dehydrogenation of alcohols","volume":"72","author":"M Hosseini-Sarvari","year":"2015","journal-title":"Mater. Res. Bull"},{"key":"ref21","doi-asserted-by":"crossref","first-page":"422","DOI":"10.1016\/j.apcata.2015.03.047","article-title":"Cyclodehydration of diethylene glycol over Ag-modified Al<sub>2<\/sub>O<sub>3<\/sub> catalyst","volume":"505","author":"DL Sun","year":"2015","journal-title":"Appl. Catal. A"},{"key":"ref22","doi-asserted-by":"crossref","first-page":"8509","DOI":"10.1021\/ja039378y","article-title":"Mechanism, selectivity promotion, and new ultra-selective pathways in Ag-catalyzed heterogeneous epoxidation","volume":"126","author":"FJ Williams","year":"2004","journal-title":"J. Am. Chem. Soc"},{"key":"ref23","doi-asserted-by":"crossref","first-page":"868","DOI":"10.1016\/j.catcom.2008.12.013","article-title":"Styrene epoxidation over Ag-\u03b3-ZrP catalyst prepared by ion-exchange","volume":"10","author":"JH Liu","year":"2009","journal-title":"Catal. Comm"},{"key":"ref24","doi-asserted-by":"crossref","first-page":"50","DOI":"10.1016\/j.sna.2016.02.036","article-title":"Ag\/ZnO\/p-Si\/Ag heterojunction and their optoelectronic characteristics under different UV wavelength illumination","volume":"242","author":"NH Al-Hardan","year":"2016","journal-title":"Sens. Actuators, A"},{"key":"ref25","doi-asserted-by":"crossref","first-page":"2201","DOI":"10.1351\/pac198254112201","article-title":"Reporting physisorption data for gas\/solid systems with special reference to the determination of surface area and porosity","volume":"54","author":"KSW Sing","year":"1982","journal-title":"Pure&Appl. Chem"},{"key":"ref26","doi-asserted-by":"crossref","first-page":"5023","DOI":"10.1021\/ja067631z","article-title":"Bifunctional binding of cisplatin to DNA: why does cisplatin form 1,2-intrastrand cross-links with Ag but not with GA?","volume":"129","author":"Y Mantri","year":"2007","journal-title":"J. Am. Chem. Soc"},{"key":"ref27","doi-asserted-by":"crossref","first-page":"23","DOI":"10.1016\/j.chemosphere.2016.05.080","article-title":"Removal of phosphate using iron oxide nanoparticles synthesized by eucalyptus leaf extract in the presence of CTAB surfactant","volume":"159","author":"D Cao","year":"2016","journal-title":"Chemosphere"},{"key":"ref28","doi-asserted-by":"crossref","first-page":"17570","DOI":"10.1021\/jp074512c","article-title":"Selective catalytic cyclohexene oxidation using titanium-functionalized silicone nanospheres","volume":"111","author":"CA Bradley","year":"2007","journal-title":"J. Phys. Chem. C"},{"key":"ref29","doi-asserted-by":"crossref","first-page":"7181","DOI":"10.1021\/jp8101095","article-title":"Study of higher selectivity to styrene oxide in the epoxidation of styrene with hydrogen peroxide over La-doped MCM-48 Catalyst","volume":"113","author":"WC Zhan","year":"2009","journal-title":"J. Phys. Chem. C"},{"key":"ref30","doi-asserted-by":"crossref","first-page":"253","DOI":"10.1016\/S0360-0564(08)60042-5","article-title":"Microporous crystalline Titanium Silicates","volume":"41","author":"B Notari","year":"1996","journal-title":"Adv. Catal"},{"key":"ref31","doi-asserted-by":"crossref","first-page":"6377","DOI":"10.1002\/anie.200461113","article-title":"In situ magnetic resonance investigation of styrene oxidation over TS-1 zeolites","volume":"43","author":"JQ Zhuang","year":"2004","journal-title":"Angew. Chem. Int. Ed"},{"key":"ref32","doi-asserted-by":"crossref","first-page":"2611","DOI":"10.1016\/j.apsusc.2009.11.003","article-title":"Synthesis of hollow silver spheres using poly-(styrene-methyl acrylic acid) as templates in the presence of sodium polyacrylate","volume":"256","author":"AL Wang","year":"2010","journal-title":"Appl. Surf. Sci"},{"key":"ref33","doi-asserted-by":"crossref","first-page":"60","DOI":"10.1016\/j.molcata.2009.11.008","article-title":"Synthesis and characterization of Fe\/CeO<sub>2<\/sub> catalysts: Epoxidation of cyclohexene","volume":"318","author":"AS Reddy","year":"2010","journal-title":"J. Mol. Catal. A: Chem"},{"key":"ref34","doi-asserted-by":"crossref","first-page":"107","DOI":"10.1016\/j.jcat.2015.04.005","article-title":"A kinetic study of vapor-phase cyclohexene epoxidation by H<sub>2<\/sub>O<sub>2<\/sub> over mesoporous TS-1","volume":"326","author":"S Kwon","year":"2015","journal-title":"J. Catal"},{"key":"ref35","doi-asserted-by":"crossref","first-page":"1373","DOI":"10.1021\/acs.iecr.5b04187","article-title":"Effective continuous flow Process for the epoxidation of cyclohexene","volume":"55","author":"W He","year":"2016","journal-title":"Ind. Eng. Chem. Res"},{"key":"ref36","doi-asserted-by":"crossref","first-page":"1988","DOI":"10.1021\/cm9030667","article-title":"Controlled postgrafting of titanium chelates for improved synthesis of Ti-SBA-15 epoxidation catalysts","volume":"22","author":"F Berube","year":"2010","journal-title":"Chem. Mater"}],"container-title":["PLOS ONE"],"original-title":[],"language":"en","link":[{"URL":"http:\/\/dx.plos.org\/10.1371\/journal.pone.0176332","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,6,24]],"date-time":"2024-06-24T02:16:13Z","timestamp":1719195373000},"score":1,"resource":{"primary":{"URL":"https:\/\/dx.plos.org\/10.1371\/journal.pone.0176332"}},"subtitle":[],"editor":[{"given":"Elena A.","family":"Rozhkova","sequence":"first","affiliation":[],"role":[{"role":"editor","vocabulary":"crossref"}]}],"short-title":[],"issued":{"date-parts":[[2017,5,11]]},"references-count":36,"journal-issue":{"issue":"5","published-online":{"date-parts":[[2017,5,11]]}},"URL":"https:\/\/doi.org\/10.1371\/journal.pone.0176332","relation":{},"ISSN":["1932-6203"],"issn-type":[{"value":"1932-6203","type":"electronic"}],"subject":[],"published":{"date-parts":[[2017,5,11]]}}}