{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,14]],"date-time":"2026-07-14T23:30:24Z","timestamp":1784071824678,"version":"3.55.0"},"reference-count":84,"publisher":"Public Library of Science (PLoS)","issue":"6","license":[{"start":{"date-parts":[[2024,6,17]],"date-time":"2024-06-17T00:00:00Z","timestamp":1718582400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":["www.plosone.org"],"crossmark-restriction":false},"short-container-title":["PLoS ONE"],"abstract":"<jats:p>In this study, a simple calcination route was adopted to prepare hausmannite Mn<jats:sub>3<\/jats:sub>O<jats:sub>4<\/jats:sub> nanoparticles using rice powder as soft bio-template. Prepared Mn<jats:sub>3<\/jats:sub>O<jats:sub>4<\/jats:sub> was characterized by Fourier Transform Infra-Red Spectroscopy (FTIR), Field Emission Scanning Electron Microscopy (FESEM), Energy Dispersive X-ray microanalysis (EDX), Powder X-Ray Diffraction (XRD), Transmission Electron Microscopy (TEM), Brunauer-Emmett-Teller (BET) and Solid state UV-Vis spectroscopic techniques. Mn-O stretching in tetrahedral site was confirmed by FTIR and Raman spectra. % of Mn and O content supported Mn<jats:sub>3<\/jats:sub>O<jats:sub>4<\/jats:sub> formation. The crystallinity and grain size was found to be 68.76% and 16.43 nm, respectively; tetragonal crystal system was also cleared by XRD. TEM clarified the planes of crystal formed which supported the XRD results and BET demonstrated mesoporous nature of prepared Mn<jats:sub>3<\/jats:sub>O<jats:sub>4<\/jats:sub> having low pore volume. Low optical band gap of 3.24 eV of prepared Mn<jats:sub>3<\/jats:sub>O<jats:sub>4<\/jats:sub> nanoparticles indicated semiconductor property and was used as cathode material to fabricate CR-2032 coin cell of Aqueous Rechargeable Zinc Ion Battery (ARZIB). A reversible cyclic voltammogram (CV) showed good zinc ion storage performance. Low cell resistance was confirmed by Electrochemical Impedance Spectroscopy (EIS). The coin cell delivered high specific discharge capacity of 240.75 mAhg<jats:sup>-1<\/jats:sup> at 0.1 Ag<jats:sup>-1<\/jats:sup> current density. The coulombic efficiency was found to be 99.98%. It also delivered excellent capacity retention 94.45% and 64.81% after 300 and 1000 charge-discharge cycles, respectively. This work offers a facile and cost effective approach for preparing cathode material of ARZIBs.<\/jats:p>","DOI":"10.1371\/journal.pone.0305611","type":"journal-article","created":{"date-parts":[[2024,6,17]],"date-time":"2024-06-17T18:11:41Z","timestamp":1718647901000},"page":"e0305611","update-policy":"https:\/\/doi.org\/10.1371\/journal.pone.corrections_policy","source":"Crossref","is-referenced-by-count":12,"title":["Rice powder template for hausmannite Mn3O4 nanoparticles and its application to aqueous zinc ion battery"],"prefix":"10.1371","volume":"19","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-5672-3548","authenticated-orcid":true,"given":"Nusrat Tazeen","family":"Tonu","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Parbhej","family":"Ahamed","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0101-4749","authenticated-orcid":true,"given":"Mohammad Abu","family":"Yousuf","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"340","published-online":{"date-parts":[[2024,6,17]]},"reference":[{"key":"pone.0305611.ref001","first-page":"247","article-title":"Microfluidic-oriented assembly of Mn3O4@","volume":"208","author":"C Li","year":"2023","journal-title":"C\/GFF cathode with multiscale synergistic structure for high-performance aqueous zinc-ion batteries. Carbon"},{"issue":"4","key":"pone.0305611.ref002","doi-asserted-by":"crossref","first-page":"1167","DOI":"10.1021\/ja3091438","article-title":"The Li-ion rechargeable battery: a perspective","volume":"135","author":"JB Goodenough","year":"2013","journal-title":"Journal of the American Chemical Society"},{"issue":"2","key":"pone.0305611.ref003","doi-asserted-by":"crossref","first-page":"119","DOI":"10.19053\/01217488.v9.n2.2018.7262","article-title":"Estudio termodin\u00e1mico de la lixiviaci\u00f3n de plomo reciclado con citrato de sodio.","volume":"9","author":"LC Villa","year":"2018","journal-title":"Ciencia en Desarrollo."},{"issue":"11","key":"pone.0305611.ref004","first-page":"3288","article-title":"Issues and opportunities facing aqueous zinc-ion batteries. Energy &","volume":"12","author":"B Tang","year":"2019","journal-title":"Environmental Science"},{"issue":"1","key":"pone.0305611.ref005","doi-asserted-by":"crossref","first-page":"190","DOI":"10.1021\/acsmaterialslett.1c00499","article-title":"Cathode materials challenge varied with different electrolytes in zinc batteries","volume":"4","author":"N Wang","year":"2021","journal-title":"ACS Materials Letters"},{"issue":"15","key":"pone.0305611.ref006","doi-asserted-by":"crossref","first-page":"7795","DOI":"10.1021\/acs.chemrev.9b00628","article-title":"Active materials for aqueous zinc ion batteries: synthesis, crystal structure, morphology, and electrochemistry","volume":"120","author":"X Jia","year":"2020","journal-title":"Chemical Reviews"},{"issue":"10","key":"pone.0305611.ref007","doi-asserted-by":"crossref","first-page":"12081","DOI":"10.1021\/acsnano.9b06484","article-title":"Graphene oxide wrapped CuV2O6 nanobelts as high-capacity and long-life cathode materials of aqueous zinc-ion batteries.","volume":"13","author":"Y Liu","year":"2019","journal-title":"ACS nano."},{"key":"pone.0305611.ref008","doi-asserted-by":"crossref","first-page":"143","DOI":"10.1016\/j.ensm.2018.07.022","article-title":"Freestanding graphene\/VO2 composite films for highly stable aqueous Zn-ion batteries with superior rate performance.","volume":"17","author":"X Dai","year":"2019","journal-title":"Energy Storage Materials."},{"issue":"6","key":"pone.0305611.ref009","doi-asserted-by":"crossref","first-page":"e202102390","DOI":"10.1002\/cssc.202102390","article-title":"In\u2010Situ Growth of Mn3O4 Nanoparticles on Nitrogen\u2010Doped Carbon Dots\u2010Derived Carbon Skeleton as Cathode Materials for Aqueous Zinc Ion Batteries.","volume":"15","author":"TB Song","year":"2022","journal-title":"ChemSusChem."},{"issue":"11","key":"pone.0305611.ref010","doi-asserted-by":"crossref","first-page":"14144","DOI":"10.1021\/acsaem.2c02690","article-title":"MOF-Derived Mn3O4@ C Hierarchical Nanospheres as Cathodes for Aqueous Zinc-Ion Batteries.","volume":"5","author":"C Yin","year":"2022","journal-title":"ACS Applied Energy Materials"},{"issue":"31","key":"pone.0305611.ref011","doi-asserted-by":"crossref","first-page":"18209","DOI":"10.1039\/C9TA05053A","article-title":"A review on recent developments and challenges of cathode materials for rechargeable aqueous Zn-ion batteries","volume":"7","author":"D Selvakumaran","year":"2019","journal-title":"Journal of Materials Chemistry A"},{"key":"pone.0305611.ref012","doi-asserted-by":"crossref","first-page":"508","DOI":"10.1016\/j.ensm.2021.10.039","article-title":"Unveiling performance evolution mechanisms of MnO2 polymorphs for durable aqueous zinc-ion batteries.","volume":"44","author":"Y Liao","year":"2022","journal-title":"Energy Storage Materials."},{"key":"pone.0305611.ref013","doi-asserted-by":"crossref","first-page":"231023","DOI":"10.1016\/j.jpowsour.2022.231023","article-title":"Rechargeable zinc-ion batteries with manganese dioxide cathode: How critical is choice of manganese dioxide polymorphs in aqueous solutions","volume":"523","author":"U Siamionau","year":"2022","journal-title":"Journal of Power Sources"},{"key":"pone.0305611.ref014","first-page":"1","article-title":"Self-assembled Al nanostructure\/ZnO quantum dot heterostructures for high responsivity and fast UV photodetector.","volume":"12","author":"S Liu","year":"2020","journal-title":"Nano-micro letters."},{"key":"pone.0305611.ref015","doi-asserted-by":"crossref","first-page":"140396","DOI":"10.1016\/j.electacta.2022.140396","article-title":"Ultrasmall Mn3O4 nanocrystalline@ three-dimensional macroporous honeycomb-like hollow carbon matrix for high-rate and long-lifetime zinc-ion storage","volume":"419","author":"SY Zhu","year":"2022","journal-title":"Electrochimica Acta"},{"issue":"2","key":"pone.0305611.ref016","doi-asserted-by":"crossref","first-page":"20210014","DOI":"10.1002\/bte2.20210014","article-title":"Manganese\u2010based materials as cathode for rechargeable aqueous zinc\u2010ion batteries.","volume":"1","author":"Y Guo","year":"2022","journal-title":"Battery Energy."},{"key":"pone.0305611.ref017","doi-asserted-by":"crossref","first-page":"170","DOI":"10.1016\/j.electacta.2017.10.166","article-title":"Electrochemically induced spinel-layered phase transition of Mn3O4 in high performance neutral aqueous rechargeable zinc battery","volume":"259","author":"J Hao","year":"2018","journal-title":"Electrochimica Acta"},{"issue":"9","key":"pone.0305611.ref018","doi-asserted-by":"crossref","first-page":"2510","DOI":"10.1002\/celc.201900376","article-title":"Mn3O4@ NC composite nanorods as a cathode for rechargeable aqueous Zn\u2010ion batteries.","volume":"6","author":"M Sun","year":"2019","journal-title":"ChemElectroChem."},{"key":"pone.0305611.ref019","doi-asserted-by":"crossref","first-page":"151812","DOI":"10.1016\/j.jallcom.2019.151812","article-title":"Porous cube-like Mn3O4@ C as an advanced cathode for low-cost neutral zinc-ion battery","volume":"813","author":"H Chen","year":"2020","journal-title":"Journal of Alloys and Compounds"},{"issue":"2","key":"pone.0305611.ref020","doi-asserted-by":"crossref","first-page":"355","DOI":"10.1039\/C8QI00993G","article-title":"Fabrication of a 1D Mn3O4 nano-rod electrode for aqueous asymmetric supercapacitors and capacitive deionization","volume":"6","author":"H Zhang","year":"2019","journal-title":"Inorganic Chemistry Frontiers"},{"issue":"18","key":"pone.0305611.ref021","doi-asserted-by":"crossref","first-page":"11129","DOI":"10.1039\/C7RA00435D","article-title":"Mn3O4 hollow microcubes and solid nanospheres derived from a metal formate framework for electrochemical capacitor applications.","volume":"7","author":"Z Liu","year":"2017","journal-title":"RSC advances."},{"key":"pone.0305611.ref022","doi-asserted-by":"crossref","first-page":"330","DOI":"10.1016\/j.electacta.2017.12.067","article-title":"Enhanced supercapacitive performance of binary cooperative complementary Co(OH)2\/Mn3O4 nanomaterials directly synthesized through ion diffusion method controlled by ion exchange membrane","volume":"260","author":"H Liu","year":"2018","journal-title":"Electrochimica Acta"},{"issue":"9","key":"pone.0305611.ref023","doi-asserted-by":"crossref","first-page":"e24788","DOI":"10.1371\/journal.pone.0024788","article-title":"Biogenic hierarchical TiO2\/SiO2 derived from rice husk and enhanced photocatalytic properties for dye degradation.","volume":"6","author":"D Yang","year":"2011","journal-title":"PLoS One."},{"key":"pone.0305611.ref024","doi-asserted-by":"crossref","first-page":"119","DOI":"10.1007\/978-94-007-2442-6_5","volume-title":"Environmental Chemistry for a Sustainable World","author":"D Visinescu","year":"2012"},{"issue":"2","key":"pone.0305611.ref025","doi-asserted-by":"crossref","first-page":"285","DOI":"10.3329\/jsr.v1i2.1777","article-title":"Preparation of zeolite Y using local raw material rice husk as a silica source","volume":"1","author":"MM Rahman","year":"2009","journal-title":"Journal of Scientific Research"},{"issue":"15","key":"pone.0305611.ref026","doi-asserted-by":"crossref","first-page":"7145","DOI":"10.1021\/jp110256s","article-title":"Facile synthesis of monodisperse porous ZnO spheres by a soluble starch-assisted method and their photocatalytic activity","volume":"115","author":"G Zhang","year":"2011","journal-title":"The Journal of Physical Chemistry C"},{"issue":"4","key":"pone.0305611.ref027","doi-asserted-by":"crossref","first-page":"805","DOI":"10.1039\/b110424c","article-title":"Formation of uniform and monodisperse zincite crystals in the presence of soluble starch","volume":"12","author":"A Taubert","year":"2002","journal-title":"Journal of Materials Chemistry"},{"issue":"22","key":"pone.0305611.ref028","doi-asserted-by":"crossref","first-page":"6779","DOI":"10.3390\/ma14226779","article-title":"Green synthesis of hexagonal hematite (\u03b1-Fe2O3) flakes using pluronic F127-gelatin template for adsorption and photodegradation of ibuprofen.","volume":"14","author":"M Ulfa","year":"2021","journal-title":"Materials"},{"issue":"2","key":"pone.0305611.ref029","doi-asserted-by":"crossref","first-page":"637","DOI":"10.1016\/j.matchemphys.2012.09.068","article-title":"Facile synthesis and optical band gap calculation of Mn3O4 nanoparticles","volume":"137","author":"NM Hosny","year":"2012","journal-title":"Materials Chemistry and Physics"},{"issue":"10","key":"pone.0305611.ref030","doi-asserted-by":"crossref","first-page":"2746","DOI":"10.3390\/nano11102746","article-title":"Zn metal anodes for Zn-ion batteries in mild aqueous electrolytes: Challenges and strategies.","volume":"11","author":"VP Hoang Huy","year":"2021","journal-title":"Nanomaterials"},{"key":"pone.0305611.ref031","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1007\/s00339-021-04428-6","article-title":"Dye degradation studies of hausmannite manganese oxide (Mn3O4) nanoparticles synthesized by chemical method.","volume":"127","author":"Y Wang","year":"2021","journal-title":"Applied Physics A"},{"key":"pone.0305611.ref032","doi-asserted-by":"crossref","first-page":"249","DOI":"10.1007\/s41101-017-0017-3","article-title":"Oxidative degradation of methylene blue using Mn3O4 nanoparticles","volume":"1","author":"AK Atique Ullah","year":"2017","journal-title":"Water Conservation Science and Engineering"},{"issue":"1","key":"pone.0305611.ref033","doi-asserted-by":"crossref","first-page":"175","DOI":"10.1016\/j.jcis.2005.05.005","article-title":"One-step synthesis of Mn3O4 nanoparticles: Structural and magnetic study","volume":"291","author":"A V\u00e1zquez-Olmos","year":"2005","journal-title":"Journal of colloid and interface science"},{"key":"pone.0305611.ref034","doi-asserted-by":"crossref","first-page":"529","DOI":"10.1007\/s10973-017-6766-6","article-title":"Effects of gamma radiation on the thermoanalytical, structural and pasting properties of black rice (Oryza sativa L.) flour.","volume":"133","author":"VC Ito","year":"2018","journal-title":"Journal of Thermal Analysis and Calorimetry"},{"issue":"5","key":"pone.0305611.ref035","doi-asserted-by":"crossref","first-page":"2424","DOI":"10.1021\/acs.energyfuels.1c04435","article-title":"Review on template removal techniques for synthesis of mesoporous silica materials","volume":"36","author":"H Ghaedi","year":"2022","journal-title":"Energy & Fuels"},{"issue":"10","key":"pone.0305611.ref036","doi-asserted-by":"crossref","first-page":"2887","DOI":"10.1039\/D1NA00144B","article-title":"Enhanced electrochemical activities of morphologically tuned MnFe2O4 nanoneedles and nanoparticles integrated on reduced graphene oxide for highly efficient supercapacitor electrodes.","volume":"3","author":"R Rajalakshmi","year":"2021","journal-title":"Nanoscale Advances"},{"issue":"2","key":"pone.0305611.ref037","doi-asserted-by":"crossref","first-page":"388","DOI":"10.1007\/s10971-022-06022-5","article-title":"Effect of sintering temperature on structural, morphological, magnetic, and electrochemical properties of Mn0.3Co0.2Zn0.5Fe2O4 Ferrite","volume":"105","author":"H Mahajan","year":"2023","journal-title":"Journal of Sol-Gel Science and Technology"},{"issue":"2","key":"pone.0305611.ref038","doi-asserted-by":"crossref","first-page":"258","DOI":"10.1143\/JPSJ.16.258","article-title":"Oxygen positional parameters of tetragonal Mn3O4","volume":"16","author":"KI Satomi","year":"1961","journal-title":"Journal of the Physical Society of Japan"},{"key":"pone.0305611.ref039","doi-asserted-by":"crossref","first-page":"1099","DOI":"10.1007\/s10876-018-1428-9","article-title":"Synthesis of saucer shaped manganese oxide nanoparticles by co-precipitation method and the application as fuel additive","volume":"29","author":"S Jamil","year":"2018","journal-title":"Journal of Cluster Science"},{"issue":"3","key":"pone.0305611.ref040","doi-asserted-by":"crossref","first-page":"154","DOI":"10.4236\/wjnse.2012.23020","article-title":"Modified Scherrer equation to estimate more accurately nano-crystallite size using XRD","volume":"2","author":"A Monshi","year":"2012","journal-title":"World journal of nano science and engineering"},{"key":"pone.0305611.ref041","first-page":"012070","volume-title":"InJournal of Physics: Conference Series","author":"A Rizky","year":"2021"},{"issue":"5","key":"pone.0305611.ref042","doi-asserted-by":"crossref","first-page":"669","DOI":"10.1080\/16583655.2018.1497440","article-title":"Investigation on the electrochemical performance of hausmannite Mn3O4 nanoparticles by ultrasonic irradiation assisted co-precipitation method for supercapacitor electrodes","volume":"12","author":"R Tholkappiyan","year":"2018","journal-title":"Journal of Taibah University for Science"},{"issue":"1","key":"pone.0305611.ref043","doi-asserted-by":"crossref","first-page":"719","DOI":"10.1166\/jnn.2018.14644","article-title":"Electrochemical properties of controlled size Mn3O4 nanoparticles for supercapacitor applications","volume":"18","author":"HU Shah","year":"2018","journal-title":"Journal of nanoscience and nanotechnology"},{"issue":"45","key":"pone.0305611.ref044","doi-asserted-by":"crossref","first-page":"29158","DOI":"10.1021\/acsomega.0c03888","article-title":"Electrochemical sodiation\/desodiation into Mn3O4 nanoparticles.","volume":"5","author":"NF Mahamad Yusoff","year":"2020","journal-title":"ACS omega"},{"key":"pone.0305611.ref045","doi-asserted-by":"crossref","first-page":"585","DOI":"10.1016\/B978-0-12-384746-1.00014-8","volume-title":"Progress in filtration and separation","author":"M. Naderi","year":"2015"},{"key":"pone.0305611.ref046","doi-asserted-by":"crossref","first-page":"128216","DOI":"10.1016\/j.cej.2020.128216","article-title":"W18O49 nanowires-graphene nanocomposite for asymmetric supercapacitors employing AlCl3 aqueous electrolyte","volume":"409","author":"MR Thalji","year":"2021","journal-title":"Chemical Engineering Journal"},{"key":"pone.0305611.ref047","doi-asserted-by":"crossref","first-page":"182","DOI":"10.1016\/j.apcatb.2012.08.014","article-title":"Heterogeneous oxidation of naproxen in the presence of \u03b1-MnO2 nanostructures with different morphologies","volume":"127","author":"Y Zhang","year":"2012","journal-title":"Applied Catalysis B: Environmental"},{"key":"pone.0305611.ref048","doi-asserted-by":"crossref","first-page":"145341","DOI":"10.1016\/j.cej.2023.145341","article-title":"Cobalt-doped tungsten suboxides for supercapacitor applications","volume":"473","author":"MR Thalji","year":"2023","journal-title":"Chemical Engineering Journal"},{"key":"pone.0305611.ref049","first-page":"18897","article-title":"The electrochemical performance and catalytic properties of Ytterbium substitution on Manganese oxide nanoparticles: BET study; preparation and characterization","volume":"30","author":"Y Hanifehpour","year":"2019","journal-title":"Journal of Materials Science: Materials in Electronics"},{"issue":"25","key":"pone.0305611.ref050","doi-asserted-by":"crossref","first-page":"4263","DOI":"10.1016\/j.atmosenv.2011.04.082","article-title":"Light absorption coefficient measurement of SOA using a UV\u2013Visible spectrometer connected with an integrating sphere","volume":"45","author":"M Zhong","year":"2011","journal-title":"Atmospheric environment"},{"key":"pone.0305611.ref051","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1007\/s10971-011-2582-9","article-title":"Band-gap energy estimation from diffuse reflectance measurements on sol\u2013gel and commercial TiO2: a comparative study","volume":"61","author":"R L\u00f3pez","year":"2012","journal-title":"Journal of sol-gel science and technology"},{"issue":"4","key":"pone.0305611.ref052","doi-asserted-by":"crossref","first-page":"561","DOI":"10.1080\/13642819308217935","article-title":"The origin of reversible and irreversible photostructural changes in chalcogenide glasses","volume":"68","author":"H. Fritzsche","year":"1993","journal-title":"Philosophical Magazine B"},{"issue":"14","key":"pone.0305611.ref053","doi-asserted-by":"crossref","first-page":"4411","DOI":"10.1016\/j.apsusc.2009.12.057","article-title":"A novel chemical synthesis and characterization of Mn3O4 thin films for supercapacitor application","volume":"256","author":"DP Dubal","year":"2010","journal-title":"Applied Surface Science"},{"issue":"20","key":"pone.0305611.ref054","doi-asserted-by":"crossref","first-page":"9677","DOI":"10.1039\/C8TA01198B","article-title":"Binder-free stainless steel@ Mn3O4 nanoflower composite: a high-activity aqueous zinc-ion battery cathode with high-capacity and long-cycle-life","volume":"6","author":"C Zhu","year":"2018","journal-title":"Journal of Materials Chemistry A"},{"issue":"18","key":"pone.0305611.ref055","doi-asserted-by":"crossref","first-page":"14072","DOI":"10.1021\/acs.inorgchem.1c01397","article-title":"Cu\/Ag complex modified Keggin-type coordination polymers for improved electrochemical capacitance, dual-function electrocatalysis, and sensing performance","volume":"60","author":"X Liu","year":"2021","journal-title":"Inorganic Chemistry"},{"issue":"42","key":"pone.0305611.ref056","doi-asserted-by":"crossref","first-page":"16755","DOI":"10.1021\/jacs.9b06962","article-title":"Two-dimensional mesoporous heterostructure delivering superior pseudocapacitive sodium storage via bottom-up monomicelle assembly","volume":"141","author":"K Lan","year":"2019","journal-title":"Journal of the American Chemical Society"},{"issue":"3","key":"pone.0305611.ref057","doi-asserted-by":"crossref","first-page":"1911","DOI":"10.1021\/nl504764m","article-title":"High performance pseudocapacitor based on 2D layered metal chalcogenide nanocrystals","volume":"15","author":"GA Muller","year":"2015","journal-title":"Nano letters"},{"issue":"1","key":"pone.0305611.ref058","doi-asserted-by":"crossref","first-page":"6929","DOI":"10.1038\/ncomms7929","article-title":"Na+ intercalation pseudocapacitance in graphene-coupled titanium oxide enabling ultra-fast sodium storage and long-term cycling","volume":"6","author":"C Chen","year":"2015","journal-title":"Nature communications"},{"issue":"11","key":"pone.0305611.ref059","doi-asserted-by":"crossref","first-page":"10211","DOI":"10.1021\/acsnano.6b05566","article-title":"Pseudocapacitive Na-ion storage boosts high rate and areal capacity of self-branched 2D layered metal chalcogenide nanoarrays.","volume":"10","author":"D Chao","year":"2016","journal-title":"ACS nano."},{"issue":"18","key":"pone.0305611.ref060","doi-asserted-by":"crossref","first-page":"2200067","DOI":"10.1002\/advs.202200067","article-title":"In Situ Anchoring Anion\u2010Rich and Multi\u2010Cavity NiS2 Nanoparticles on NCNTs for Advanced Magnesium\u2010Ion Batteries.","volume":"9","author":"Z Ye","year":"2022","journal-title":"Advanced Science"},{"key":"pone.0305611.ref061","doi-asserted-by":"crossref","first-page":"100518","DOI":"10.1016\/j.mtphys.2021.100518","article-title":"Oxygen vacancies-enriched Mn3O4 enabling high-performance rechargeable aqueous zinc-ion battery","volume":"21","author":"C Huang","year":"2021","journal-title":"Materials Today Physics"},{"issue":"11","key":"pone.0305611.ref062","doi-asserted-by":"crossref","first-page":"2310393","DOI":"10.1002\/adfm.202310393","article-title":"Advances and Perspectives of Ion\u2010Intercalated Vanadium Oxide Cathodes for High\u2010Performance Aqueous Zinc Ion Battery","volume":"34","author":"Y Bai","year":"2024","journal-title":"Advanced Functional Materials"},{"key":"pone.0305611.ref063","doi-asserted-by":"crossref","first-page":"1027","DOI":"10.1007\/s10008-016-3456-4","article-title":"Performance of SnSb: Ce, Co alloy as anode for lithium-ion batteries","volume":"21","author":"D Lakshmi","year":"2017","journal-title":"Journal of Solid State Electrochemistry"},{"key":"pone.0305611.ref064","first-page":"1","article-title":"Enhanced electrochemical energy storage devices utilizing a one-dimensional (1D) \u03b1-MnO2 nanocomposite encased in onion-like carbon","volume":"27","author":"N Palaniyandy","year":"2024","journal-title":"Journal of Materials Science"},{"issue":"23","key":"pone.0305611.ref065","doi-asserted-by":"crossref","first-page":"12200","DOI":"10.1021\/acs.jpcc.8b03306","article-title":"Magnetic electrodeposition of the hierarchical cobalt oxide nanostructure from spent lithium-ion batteries: its application as a supercapacitor electrode","volume":"122","author":"EA Aboelazm","year":"2018","journal-title":"The Journal of Physical Chemistry C"},{"key":"pone.0305611.ref066","doi-asserted-by":"crossref","first-page":"185","DOI":"10.3938\/NPSM.68.185","article-title":"An activated carbon and carbon nanotube composite for a high-performance capacitor.","volume":"68","author":"O Ibukun","year":"2018","journal-title":"New Phys. Sae. Mulli"},{"issue":"12","key":"pone.0305611.ref067","doi-asserted-by":"crossref","first-page":"16055","DOI":"10.1021\/acssuschemeng.8b02502","article-title":"Transformed akhtenskite MnO2 from Mn3O4 as cathode for a rechargeable aqueous zinc ion battery","volume":"6","author":"L Wang","year":"2018","journal-title":"ACS sustainable chemistry & engineering"},{"issue":"9","key":"pone.0305611.ref068","doi-asserted-by":"crossref","first-page":"10376","DOI":"10.1021\/acsnano.9b04165","article-title":"Ultrafast zinc-ion diffusion ability observed in 6.0-nanometer spinel nanodots","volume":"13","author":"L. Jiang","year":"2019","journal-title":"ACS nano"},{"key":"pone.0305611.ref069","doi-asserted-by":"crossref","first-page":"422","DOI":"10.1016\/j.electacta.2017.01.163","article-title":"Manganese sesquioxide as cathode material for multivalent zinc ion battery with high capacity and long cycle life","volume":"229","author":"B. Jiang","year":"2017","journal-title":"Electrochimica Acta"},{"key":"pone.0305611.ref070","doi-asserted-by":"crossref","first-page":"504","DOI":"10.1016\/j.jcis.2023.11.129","article-title":"Butterfly-tie like MnCO3@ Mn3O4 heterostructure enhanced the electrochemical performances of aqueous zinc ion batteries","volume":"656","author":"T Li","year":"2024","journal-title":"Journal of Colloid and Interface Science"},{"key":"pone.0305611.ref071","doi-asserted-by":"crossref","first-page":"112292","DOI":"10.1016\/j.materresbull.2023.112292","article-title":"Facile synthesis of Mn2O3\/Mn3O4 composites with superior zinc ion storage performance","volume":"165","author":"J Yao","year":"2023","journal-title":"Materials Research Bulletin"},{"key":"pone.0305611.ref072","doi-asserted-by":"crossref","first-page":"156259","DOI":"10.1016\/j.apsusc.2022.156259","article-title":"Enhanced cycling stability achieved by the nitrogen doped carbon coating layer for electrodeposited Mn3O4 in aqueous zinc ion batteries","volume":"614","author":"Z Zhou","year":"2023","journal-title":"Applied Surface Science"},{"issue":"4","key":"pone.0305611.ref073","doi-asserted-by":"crossref","first-page":"040519","DOI":"10.1149\/1945-7111\/ac638d","article-title":"Construction of novel hierarchical honeycomb-like Mn3O4 MnO2 core-shell architecture with high voltage for advanced aqueous zinc-ion batteries","volume":"169","author":"L Gong","year":"2022","journal-title":"Journal of The Electrochemical Society"},{"issue":"39","key":"pone.0305611.ref074","doi-asserted-by":"crossref","first-page":"12894","DOI":"10.1021\/jacs.6b05958","article-title":"Cation-deficient spinel ZnMn2O4 cathode in Zn (CF3SO3) 2 electrolyte for rechargeable aqueous Zn-ion battery.","volume":"138","author":"N Zhang","year":"2016","journal-title":"Journal of the American Chemical Society"},{"key":"pone.0305611.ref075","doi-asserted-by":"crossref","first-page":"514","DOI":"10.1007\/s10118-020-2353-6","article-title":"Preparation of polyaniline-coated composite aerogel of MnO2 and reduced graphene oxide for high-performance Zinc-ion battery","volume":"38","author":"J Mao","year":"2020","journal-title":"Chinese Journal of Polymer Science"},{"key":"pone.0305611.ref076","doi-asserted-by":"crossref","first-page":"136155","DOI":"10.1016\/j.electacta.2020.136155","article-title":"Electrospun core-shell Mn3O4\/carbon fibers as high-performance cathode materials for aqueous zinc-ion batteries","volume":"344","author":"J Long","year":"2020","journal-title":"Electrochimica Acta"},{"key":"pone.0305611.ref077","doi-asserted-by":"crossref","first-page":"158316","DOI":"10.1016\/j.jallcom.2020.158316","article-title":"Assembly of Mn3O4 nanoparticles at low temperature on graphene with enhanced electrochemical property for zinc-ion battery","volume":"864","author":"Z Huang","year":"2021","journal-title":"Journal of Alloys and Compounds"},{"key":"pone.0305611.ref078","doi-asserted-by":"crossref","first-page":"134867","DOI":"10.1016\/j.electacta.2019.134867","article-title":"A case study of \u03b2-and \u03b4-MnO2 with different crystallographic forms on ion-storage in rechargeable aqueous zinc ion battery","volume":"324","author":"C Guo","year":"2019","journal-title":"Electrochimica Acta"},{"issue":"1","key":"pone.0305611.ref079","doi-asserted-by":"crossref","first-page":"6066","DOI":"10.1038\/srep06066","article-title":"Electrochemically-induced reversible transition from the tunneled to layered polymorphs of manganese dioxide.","volume":"4","author":"B Lee","year":"2014","journal-title":"Scientific reports."},{"key":"pone.0305611.ref080","doi-asserted-by":"crossref","first-page":"138","DOI":"10.1016\/j.electacta.2013.08.136","article-title":"Todorokite-type MnO2 as a zinc-ion intercalating material","volume":"112","author":"J Lee","year":"2013","journal-title":"Electrochimica Acta"},{"issue":"4","key":"pone.0305611.ref081","doi-asserted-by":"crossref","first-page":"3140","DOI":"10.1021\/acsnano.7b09003","article-title":"Waterproof and tailorable elastic rechargeable yarn zinc ion batteries by a cross-linked polyacrylamide electrolyte.","volume":"12","author":"H Li","year":"2018","journal-title":"ACS nano."},{"issue":"29","key":"pone.0305611.ref082","doi-asserted-by":"crossref","first-page":"9775","DOI":"10.1021\/jacs.7b04471","article-title":"Zn\/MnO2 battery chemistry with H+ and Zn2+ coinsertion","volume":"139","author":"W Sun","year":"2017","journal-title":"Journal of the American Chemical Society"},{"issue":"12","key":"pone.0305611.ref083","doi-asserted-by":"crossref","first-page":"1487","DOI":"10.1016\/j.jpcs.2011.11.038","article-title":"Preparation and characterization of manganese dioxides with nano-sized tunnel structures for zinc ion storage","volume":"73","author":"C Wei","year":"2012","journal-title":"Journal of Physics and Chemistry of Solids"},{"key":"pone.0305611.ref084","doi-asserted-by":"crossref","first-page":"422","DOI":"10.1016\/j.electacta.2017.01.163","article-title":"Manganese sesquioxide as cathode material for multivalent zinc ion battery with high capacity and long cycle life","volume":"229","author":"B Jiang","year":"2017","journal-title":"Electrochimica Acta"}],"container-title":["PLOS ONE"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/dx.plos.org\/10.1371\/journal.pone.0305611","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,6,17]],"date-time":"2024-06-17T18:12:39Z","timestamp":1718647959000},"score":1,"resource":{"primary":{"URL":"https:\/\/dx.plos.org\/10.1371\/journal.pone.0305611"}},"subtitle":[],"editor":[{"given":"Gomaa A. M.","family":"Ali","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"editor"}]}],"short-title":[],"issued":{"date-parts":[[2024,6,17]]},"references-count":84,"journal-issue":{"issue":"6","published-online":{"date-parts":[[2024,6,17]]}},"URL":"https:\/\/doi.org\/10.1371\/journal.pone.0305611","relation":{},"ISSN":["1932-6203"],"issn-type":[{"value":"1932-6203","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,6,17]]}}}