{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2024,6,5]],"date-time":"2024-06-05T10:21:53Z","timestamp":1717582913449},"reference-count":0,"publisher":"Walter de Gruyter GmbH","issue":"7-8","license":[{"start":{"date-parts":[[2001,8,1]],"date-time":"2001-08-01T00:00:00Z","timestamp":996624000000},"content-version":"unspecified","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc-nd\/3.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2001,8,1]]},"abstract":"<jats:p>Catalytic activity of catalase (CAT, EC 1.11.1.6), immobilized on carbon black NORIT and soot PM-100, with respect to decomposition of dibenzoyl peroxide (BPO) in non-aque-ous media (acetonitrile and tetrachloromethane), was investigated with a quantitative UV-spectrophotometrical approach. Progress of the above reaction was controlled by selected kinetic parameters: the apparent Michaelis constant (K<jats:sub>m<\/jats:sub>\n                  <jats:sup>app<\/jats:sup>), the specific rate constant (K<jats:sub>sp<\/jats:sub>), the activation energy (E<jats:sub>a<\/jats:sub>), the maximum reaction rate (V<jats:sub>max<\/jats:sub>), and the Arrhenius\u2019 pre-exponential factor (Z<jats:sub>0<\/jats:sub>). Conclusions on the tentative mechanism of the catalytic process observed were drawn from the calculated values of the Gibbs energy of activation (\u0394G*), the enthalpy of activation (\u0394H*), and entropy of activation (\u0394S*)<\/jats:p>","DOI":"10.1515\/znc-2001-7-813","type":"journal-article","created":{"date-parts":[[2015,2,4]],"date-time":"2015-02-04T12:57:19Z","timestamp":1423054639000},"page":"553-558","source":"Crossref","is-referenced-by-count":2,"title":["Enzyme-Catalyzed Decomposition of Dibenzoyl Peroxide in Organic Solvents"],"prefix":"10.1515","volume":"56","author":[{"given":"Elena","family":"Horozova","sequence":"first","affiliation":[{"name":"Department of Physical Chemistry, University of Plovdiv, 24 Tsar Assen St., Plovdiv - 4000, Bulgaria."}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Nina","family":"Dimcheva","sequence":"additional","affiliation":[{"name":"Department of Physical Chemistry, University of Plovdiv, 24 Tsar Assen St., Plovdiv - 4000, Bulgaria."}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Zinaida","family":"Jordanova","sequence":"additional","affiliation":[{"name":"Department of Physical Chemistry, University of Plovdiv, 24 Tsar Assen St., Plovdiv - 4000, Bulgaria."}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"374","published-online":{"date-parts":[[2014,6,2]]},"container-title":["Zeitschrift f\u00fcr Naturforschung C"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.degruyter.com\/view\/journals\/znc\/56\/7-8\/article-p553.xml","content-type":"text\/html","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.degruyter.com\/document\/doi\/10.1515\/znc-2001-7-813\/xml","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/www.degruyter.com\/document\/doi\/10.1515\/znc-2001-7-813\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2022,8,23]],"date-time":"2022-08-23T05:32:27Z","timestamp":1661232747000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.degruyter.com\/document\/doi\/10.1515\/znc-2001-7-813\/html"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2001,8,1]]},"references-count":0,"journal-issue":{"issue":"7-8","published-online":{"date-parts":[[2014,6,2]]},"published-print":{"date-parts":[[2001,8,1]]}},"alternative-id":["10.1515\/znc-2001-7-813"],"URL":"https:\/\/doi.org\/10.1515\/znc-2001-7-813","relation":{},"ISSN":["1865-7125","0939-5075"],"issn-type":[{"value":"1865-7125","type":"electronic"},{"value":"0939-5075","type":"print"}],"subject":[],"published":{"date-parts":[[2001,8,1]]}}}