{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,10]],"date-time":"2026-03-10T03:31:10Z","timestamp":1773113470309,"version":"3.50.1"},"reference-count":33,"publisher":"Walter de Gruyter GmbH","issue":"3-4","funder":[{"DOI":"10.13039\/501100003593","name":"National Council for Scientific and Technological Development","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100003593","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100002322","name":"Coordination for the Improvement of Higher Education Personnel","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100002322","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/501100001807","name":"Funda\u00e7\u00e3o de Amparo \u00e0 Pesquisa do Estado de S\u00e3o Paulo","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100001807","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2021,3,26]]},"abstract":"<jats:title>Abstract<\/jats:title>\n               <jats:p>The fall armyworm, <jats:italic>Spodoptera frugiperda<\/jats:italic>, is a polyphagous pest that causes important damage in different regions of America and mainly affects corn crops in both tropical and subtropical areas. Currently, control relies on both transgenic plants and\/or chemical pesticides. In this work, we describe insecticidal activity against the fall armyworm from a series of Mannich bases (<jats:bold>1\u201310<\/jats:bold>), derived from 2-hydroxy-1,4-naphthoquinone (lawsone), substituted benzaldehydes, and two primary amines, and their Cu<jats:sup>2+<\/jats:sup> complexes (<jats:bold>11\u201320<\/jats:bold>). The [Cu(L)<jats:sub>2<\/jats:sub>] complexes were more effective in larval mortality compared to the free Mannich bases. Among the tested compounds, complex <jats:bold>11<\/jats:bold> showed the highest toxicity, with 70.00% larval mortality.<\/jats:p>","DOI":"10.1515\/znc-2020-0115","type":"journal-article","created":{"date-parts":[[2020,11,3]],"date-time":"2020-11-03T14:49:02Z","timestamp":1604414942000},"page":"111-115","source":"Crossref","is-referenced-by-count":4,"title":["Potential insecticidal activity of aminonaphthoquinone Mannich bases derived from lawsone and their copper (II) complex derivatives"],"prefix":"10.1515","volume":"76","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8562-3589","authenticated-orcid":false,"given":"Andr\u00e9ia P.","family":"Matos","sequence":"first","affiliation":[{"name":"Department of Chemistry , Natural Products Laboratory, Federal University of S\u00e3o Carlos (UFSCar) , 13565-905 , S\u00e3o Carlos , SP , Brazil"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Andr\u00e9 L. F.","family":"Sarria","sequence":"additional","affiliation":[{"name":"Department of Chemistry , Natural Products Laboratory, Federal University of S\u00e3o Carlos (UFSCar) , 13565-905 , S\u00e3o Carlos , SP , Brazil"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ana C.","family":"Volante","sequence":"additional","affiliation":[{"name":"Department of Chemistry , Natural Products Laboratory, Federal University of S\u00e3o Carlos (UFSCar) , 13565-905 , S\u00e3o Carlos , SP , Brazil"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ant\u00f4nio R.","family":"Bernardo","sequence":"additional","affiliation":[{"name":"Department of Chemistry , Natural Products Laboratory, Federal University of S\u00e3o Carlos (UFSCar) , 13565-905 , S\u00e3o Carlos , SP , Brazil"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Gracielle O. S.","family":"Cunha","sequence":"additional","affiliation":[{"name":"Federal Institute of Education, Science and Technology of Goias, Campus Anapolis , Avenida Pedro Ludovico, 75131-457 , Anapolis , GO , Brazil"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jo\u00e3o B.","family":"Fernandes","sequence":"additional","affiliation":[{"name":"Department of Chemistry , Natural Products Laboratory, Federal University of S\u00e3o Carlos (UFSCar) , 13565-905 , S\u00e3o Carlos , SP , Brazil"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Paulo C.","family":"Vieira","sequence":"additional","affiliation":[{"name":"Department of Chemistry , Natural Products Laboratory, Federal University of S\u00e3o Carlos (UFSCar) , 13565-905 , S\u00e3o Carlos , SP , Brazil"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Maria F\u00e1tima das G. 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