{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2022,7,22]],"date-time":"2022-07-22T00:08:34Z","timestamp":1658448514584},"reference-count":49,"publisher":"Walter de Gruyter GmbH","issue":"7","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2015,7,1]]},"abstract":"<jats:title>Abstract<\/jats:title>\n               <jats:p>Solvothermal reaction of aluminum(III) nitrate nonahydrate with 3-aminopyrazine-2-carboxylic acid (HL) gave rise to a bis(\u03bc<jats:sub>2<\/jats:sub>-hydroxo)-tetrakis(3-aminopyrazine-2-carboxylato)-dialuminium(III) complex [Al(L)<jats:sub>2<\/jats:sub>(OH)]<jats:sub>2<\/jats:sub> (<jats:bold>1<\/jats:bold>) (L = 3-aminopyrazine-2-carboxylate). Crystal structure analysis reveals that each hexacoordinated Al(III) centre adopts a distorted octahedral geometry occupied by two O<jats:sub>carboxylate<\/jats:sub>, two N<jats:sub>pyrazine<\/jats:sub> and two O<jats:sub>hydroxo<\/jats:sub> atoms. The L<jats:sup>\u2013<\/jats:sup> ligand binds the metal cation by means of one pyrazine N-atom and carboxylate O-atoms <jats:italic>via<\/jats:italic> chelating fashion. Two hydroxo groups bridge between two aluminum(III) centres, assisting to construct a dinuclear structure. In the crystal lattice of <jats:bold>1<\/jats:bold> two symmetry non-equivalent dinuclear complexes are present. A 3D supramolecular associate in the crystal lattice of <jats:bold>1<\/jats:bold> has been stabilized by a number of non-covalent H-bonding interactions. Topology of the hydrogen bonded network has been also analyzed.<\/jats:p>","DOI":"10.1515\/zkri-2015-0002","type":"journal-article","created":{"date-parts":[[2015,4,14]],"date-time":"2015-04-14T17:01:04Z","timestamp":1429030864000},"page":"459-465","source":"Crossref","is-referenced-by-count":1,"title":["Synthesis, molecular and supramolecular structure of a new dinuclear aluminium(III) complex derived from 3-aminopyrazine- 2-carboxylic acid"],"prefix":"10.1515","volume":"230","author":[{"given":"Susanta","family":"Hazra","sequence":"first","affiliation":[]},{"given":"Anirban","family":"Karmakar","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural, Instituto Superior T\u00e9cnico, Universidade de Lisboa, Av. Rovisco Pais, 1049\u2013001, Lisbon, Portugal"}]}],"member":"374","published-online":{"date-parts":[[2015,4,14]]},"reference":[{"key":"2022033121312509529_j_zkri-2015-0002_ref_001_w2aab2b8c88b1b7b1ab2b1b1Aa","doi-asserted-by":"crossref","unstructured":"Z.-Z. Wen, X.-L. Wen, S.-L. Cai, S.-R. Zheng, J. Fan, W.-G. Zhang, The construction of Cu(I)\/Cu(II) coordination polymers based on pyrazine\u2013carboxylate: Structural diversity tuned by in situ hydrolysis reaction. CrystEngComm. 2013, 15, 5359.","DOI":"10.1039\/c3ce26817a"},{"key":"2022033121312509529_j_zkri-2015-0002_ref_002_w2aab2b8c88b1b7b1ab2b1b2Aa","unstructured":"J. Cepeda, G. Beobide, O. Castillo, A. Luque, S. P\u00e9rez-Y\u00e1\u00f1ez, P. Rom\u00e1n, Supramolecular architectures and magnetic properties of coordination polymers based on pyrazinedicarboxylato ligands showing embedded water clusters. Cryst. 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