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There are significant differences in their molecular conformations and their crystal packing. Within the group of compounds, three different types of carboxylic acid intermolecular interactions are exhibited, all involving O\u2013H\u00b7\u00b7\u00b7O hydrogen bonds. These three types are (i) symmetric R<jats:sup>2<\/jats:sup>\n                  <jats:sub>2<\/jats:sub>(8) dimers formed from pairs of O\u2013H\u00b7\u00b7\u00b7O hydrogen bonds in compounds <jats:bold>1\u20135<\/jats:bold>, (ii) infinite 1D homo-assemblies of carboxylic groups (homo-AA,A catemers), and (iii), a 3-D array, in which there are no direct carboxylic acid\u2013carboxylic acid interactions, generated from O\u2013H\u00b7\u00b7\u00b7O interactions of each carboxylic acid group with the hydroxyl and carbonyl groups of other molecules in <jats:bold>7<\/jats:bold>. Each of the carboxylic acid groups in the catemer exhibit anti arrangements with all the carboxylic acid oxygen atoms lying in a plane. Disorder is exhibited in the carboxylic acid groups in <jats:bold>2<\/jats:bold> and <jats:bold>6<\/jats:bold>. With the variety of oxygen substituents present in <jats:bold>1\u20137<\/jats:bold>, a large number of O\u2013H\u00b7\u00b7\u00b7O and C\u2013H\u00b7\u00b7\u00b7O hydrogen bonds are exhibited, resulting in all cases in three dimension assemblies. In <jats:bold>1\u20135<\/jats:bold>, interlayer contacts between the carboxylic acid R<jats:sup>2<\/jats:sup>\n                  <jats:sub>2<\/jats:sub>(8) dimers in rows, with differing sets of weaker C\u2013H\u00b7\u00b7\u00b7O and\/or C\u2013H\u00b7\u00b7\u00b7\u03c0 interactions, result in the formation of two-molecular wide columns and\/or infinite sheets. While column and sheet sub structures can also be designated in compound <jats:bold>6<\/jats:bold>, on linking the carboxylic acid groups with other substituents via C\u2013H\u00b7\u00b7\u00b7O, C\u2013H\u00b7\u00b7\u00b7\u03c0 and C=O\u00b7\u00b7\u00b7\u03c0 interactions, these differ from those in <jats:bold>1\u20135<\/jats:bold> due to the different arrangements of the CO<jats:sub>2<\/jats:sub>H groups.<\/jats:p>","DOI":"10.1515\/zkri-2017-2144","type":"journal-article","created":{"date-parts":[[2018,5,4]],"date-time":"2018-05-04T00:26:42Z","timestamp":1525393602000},"page":"761-780","source":"Crossref","is-referenced-by-count":1,"title":["Crystal structures and Hirshfeld surface analyses of seven 7-aryl-4,7-dioxoheptanoic acids: differing carboxylic acid interactions leading to dimers, chains and three-dimensional arrays"],"prefix":"10.1515","volume":"233","author":[{"given":"Ligia R.","family":"Gomes","sequence":"first","affiliation":[{"name":"FP-ENAS-Faculdade de Ci\u00eancias de Sa\u00fade, Escola Superior de Sa\u00fade da UFP, Universidade Fernando Pessoa , Rua Carlos da Maia, 296 , P-4200-150 Porto , Portugal"},{"name":"REQUIMTE, Departamento de Qu\u00edmica e Bioqu\u00edmica, Faculdade de Ci\u00eancias da Universidade do Porto, Rua do Campo Alegre, 687 , P-4169-007 Porto , Portugal"}]},{"given":"John N.","family":"Low","sequence":"additional","affiliation":[{"name":"Department of Chemistry , University of Aberdeen, Meston Walk, Old Aberdeen , AB24 3UE , Scotland , UK"}]},{"given":"Alan B.","family":"Turner","sequence":"additional","affiliation":[{"name":"Department of Chemistry , University of Aberdeen, Meston Walk, Old Aberdeen , AB24 3UE , Scotland , UK"}]},{"given":"Graeme J.R.","family":"Watson","sequence":"additional","affiliation":[{"name":"Department of Chemistry , University of Aberdeen, Meston Walk, Old Aberdeen , AB24 3UE , Scotland , UK"}]},{"given":"Thomas C.","family":"Baddeley","sequence":"additional","affiliation":[{"name":"Department of Chemistry , University of Aberdeen, Meston Walk, Old Aberdeen , AB24 3UE , Scotland , UK"}]},{"given":"James L.","family":"Wardell","sequence":"additional","affiliation":[{"name":"Department of Chemistry , University of Aberdeen, Meston Walk, Old Aberdeen , AB24 3UE , Scotland , UK"},{"name":"Instituto de Tecnologia em F\u00e1rmacos e Farmanguinhos , Funda\u00e7\u00e3o Oswaldo Cruz , 21041-250 Rio de Janeiro, RJ , Brazil"}]}],"member":"374","published-online":{"date-parts":[[2018,5,3]]},"reference":[{"key":"2021062122180889635_j_zkri-2017-2144_ref_001_w2aab3b7c16b1b6b1ab2b1b1Aa","doi-asserted-by":"crossref","unstructured":"E. 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