{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2024,12,14]],"date-time":"2024-12-14T05:24:45Z","timestamp":1734153885044,"version":"3.30.2"},"reference-count":0,"publisher":"Slovenian Chemical Society","issue":"4","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["ACSi"],"abstract":"<jats:p>A novel organic-inorganic hybrid cadmium complex [Cd(MCA)2(Phen)(H2O)] (MCA = anion of 3-hydroxyquinoline-4-carboxylic acid; Phen = 1,10-phenanthroline) was synthesized by solvothermal method and characterized by single crystal X-ray diffraction. The complex exhibits a two-dimensional structure through hydrogen bonding and \u03c0\u00b7\u00b7\u00b7\u03c0 packing interactions. Solid state photoluminescence specter shows that the complex displays an emission in the red region of the light spectrum that time-dependent density functional theory calculations reveal can be attributed to ligand-to-ligand charge transfer. Solid diffuse reflection specter shows that the energy band gap of the complex is 2.32 eV.<\/jats:p>","DOI":"10.17344\/acsi.2024.9004","type":"journal-article","created":{"date-parts":[[2024,12,13]],"date-time":"2024-12-13T15:03:02Z","timestamp":1734102182000},"page":"595-602","source":"Crossref","is-referenced-by-count":0,"title":["Preparation, Characterization and Theoretical Calculation of a Cadmium Complex of 3-hydroxy-2-methylquinolin-4- carboxylate and 1,10-phenanthroline"],"prefix":"10.17344","volume":"71","author":[{"given":"Ting-Qun","family":"Qiu","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Zhi-Tao","family":"Lu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Zi-Jian","family":"He","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Zheng-Ping","family":"Xie","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jin","family":"Guo","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xiu-Guang","family":"Yi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"7072","published-online":{"date-parts":[[2024,12,20]]},"container-title":["Acta Chimica Slovenica"],"original-title":[],"deposited":{"date-parts":[[2024,12,13]],"date-time":"2024-12-13T15:03:06Z","timestamp":1734102186000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.matheo.si\/index.php\/ACSi\/article\/view\/9004"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,12,20]]},"references-count":0,"journal-issue":{"issue":"4","published-online":{"date-parts":[[2024,12,20]]}},"URL":"https:\/\/doi.org\/10.17344\/acsi.2024.9004","relation":{},"ISSN":["1580-3155"],"issn-type":[{"value":"1580-3155","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,12,20]]}}}