{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,10]],"date-time":"2026-06-10T02:38:38Z","timestamp":1781059118920,"version":"3.54.1"},"reference-count":0,"publisher":"Slovenian Chemical Society","issue":"2","content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["ACSi"],"abstract":"<jats:p>A new Schiff base compound N,N\u2019-bis(4-bromo-2-hydroxybenzylidene)ethylenediamine (H2L) was prepared by reaction of 4-bromosalicylaldehyde with ethane-1,2-diamine in methanol. Reaction of H2L with copper acetate and zinc acetate in methanol, respectively, afforded two mononuclear complexes [CuL] (1) and [ZnL(OH2)] (2). Reaction of H2L with cobalt nitrate in the presence of ammonium thiocyanate in a mixture of methanol and dimethylformamide (DMF) afforded a mononuclear cobalt(III) complex [CoL(NCS)(OH2)]\u00b7DMF (3). The free Schiff base and the complexes were characterized by elemental analysis and infrared spectroscopy, as well as single crystal X-ray determination. 1H NMR analysis was also performed for H2L. The urease inhibitory assay reveals that the copper(II) complex has the most effective activity, with IC50 (half maximal inhibitory concentration) value of 0.17 \u00b1 0.08 \u03bcmol L\u20131.<\/jats:p>","DOI":"10.17344\/acsi.2025.9224","type":"journal-article","created":{"date-parts":[[2025,6,11]],"date-time":"2025-06-11T08:18:41Z","timestamp":1749629921000},"page":"321-328","source":"Crossref","is-referenced-by-count":2,"title":["N,N\u2019-Bis(4-Bromo-2-hydroxybenzylidene)ethylenediamine and Its Copper(II), Zinc(II) and Cobalt(III) Complexes: Synthesis, Crystal Structures and Urease Inhibition"],"prefix":"10.17344","volume":"72","author":[{"given":"Rundong","family":"Lu","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinkai","family":"Lei","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiacheng","family":"Liu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chi","family":"Liu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Liuxiu","family":"Chen","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wu","family":"Chen","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"7072","published-online":{"date-parts":[[2025,6,20]]},"container-title":["Acta Chimica Slovenica"],"original-title":[],"deposited":{"date-parts":[[2025,6,11]],"date-time":"2025-06-11T08:18:43Z","timestamp":1749629923000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.matheo.si\/index.php\/ACSi\/article\/view\/9224"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,6,20]]},"references-count":0,"journal-issue":{"issue":"2","published-online":{"date-parts":[[2025,6,20]]}},"URL":"https:\/\/doi.org\/10.17344\/acsi.2025.9224","relation":{},"ISSN":["1580-3155"],"issn-type":[{"value":"1580-3155","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,6,20]]}}}